Abstract: The present invention relates to a method for detecting the presence of gas hydrates and/or ice in a medium. The method comprises at least the following steps: measuring at least at one measurement point in said medium two characteristic values of Raman spectra corresponding to two distinct vibration modes of the OH bonds of water, and determining the ratio ? of said two characteristic values, determining the temperature T in said medium at said measurement point of said spectra, comparing ratio ? with a value ?0 corresponding to a predetermined threshold of formation of said crystals for said temperature T, and determining the presence or not of hydrate and/or ice crystals from said comparison.

Abstract: The present invention relates to a method for detecting the presence of gas hydrates and/or ice in a medium. The method comprises at least the following steps: measuring at least at one measurement point in said medium two characteristic values of Raman spectra corresponding to two distinct vibration modes of the OH bonds of water, and determining the ratio ? of said two characteristic values, determining the temperature T in said medium at said measurement point of said spectra, comparing ratio ? with a value T0 corresponding to a predetermined threshold of formation of said crystals for said temperature T, and determining the presence or not of hydrate and/or ice crystals from said comparison.

Abstract: a) The invention relates to an integrated analysis method and device for characterization of a hydrocarbon sample in distillation fractions. The method carries out a simulated distillation so as to separate the sample into a light fraction and at least one heavy fraction, analyzes the light fraction, collects at least one heavy fraction after separation, and analyzes in detail at least one heavy fraction.

Abstract: Method intended for continuous detection and control of hydrate formation at any point of a pipe carrying multiphase petroleum fluids. The method uses a compositional code allowing to simulate the circulation modes and conditions at any point of the pipe, considering that the fluid mixture is substantially continuously at equilibrium, that the composition of the multiphase mixture is variable all along the pipe and that the mass of each constituent of the mixture is globally defined by a mass conservation equation regardless of its phase state. The thermodynamic hydrate formation conditions are detected after a particular stage of grouping the petroleum fluids into pseudo-components so as to isolate the hydrate forming components, with definition for each one of a mass fraction and of a certain number of characteristic physical quantities, and the data relative to these particular fractions are applied to the modules so as to determine at any point the hydrate dissociation temperature (Td).

Abstract: Method intended for continuous detection and control of hydrate formation at any point of a pipe carrying multiphase petroleum fluids. The method uses a compositional code allowing to simulate the circulation modes and conditions at any point of the pipe, considering that the fluid mixture is substantially continuously at equilibrium, that the composition of the multiphase mixture is variable all along the pipe and that the mass of each constituent of the mixture is globally defined by a mass conservation equation regardless of its phase state. The thermodynamic hydrate formation conditions are detected after a particular stage of grouping the petroleum fluids into pseudo-components so as to isolate the hydrate forming components, with definition for each one of a mass fraction and of a certain number of characteristic physical quantities, and the data relative to these particular fractions are applied to the modules so as to determine at any point the hydrate dissociation temperature (Td).