Abstract: n the manufacture of sodium carbonate having increased CO2 uptakes the carbonation reaction to form sodium bicarbonate is enhanced by the addition of particular amounts of a cationic quaternary amine, selected from the family of dialkylethoxylated quaternary salts, benzylalkyl quaternary salts, or a combination of quaternary salts from these families, to treat the 25-30% by weight sodium carbonate liquor prior to filtration. The manufactured product yields a modified sodium carbonate liquor product that, when crystallized and converted to any anhydrous product, is more readily carbonated with CO2 in the production of sodium bicarbonate. The cationic additive reacts with organic materials in the sodium carbonate liquor to form solid polymeric by-products. Thus the treatment with a cationic compound is made prior to filtering the liquor. After filtering to remove the polymeric by-products and other solid materials, the liquor is evaporated or crystallized to produce a purified and modified sodium carbonate.

Abstract: n the manufacture of sodium carbonate having increased CO2 uptakes the carbonation reaction to form sodium bicarbonate is enhanced by the addition of particular amounts of a cationic quaternary amine, selected from the family of dialkylethoxylated quaternary salts, benzylalkyl quaternary salts, or a combination of quaternary salts from these families, to treat the 25-30% by weight sodium carbonate liquor prior to filtration. The manufactured product yields a modified sodium carbonate liquor product that, when crystallized and converted to any anhydrous product, is more readily carbonated with CO2 in the production of sodium bicarbonate. The cationic additive reacts with organic materials in the sodium carbonate liquor to form solid polymeric by-products. Thus the treatment with a cationic compound is made prior to filtering the liquor. After filtering to remove the polymeric by-products and other solid materials, the liquor is evaporated or crystallized to produce a purified and modified sodium carbonate.

Abstract: An improved method of purifying sodium carbonate from a natural source whereby a dissolved sodium carbonate product is treated with a cationic compound, such as a quaternary amine, to react with carbon-containing contaminants and filtering the product. The filtered modified sodium carbonate solution is then crystallized and dried. The modified sodium carbonate has a greater reactivity or uptake of carbon dioxide for the manufacture of sodium bicarbonate than conventional sodium carbonates.

Abstract: An improved method of purifying sodium carbonate from a natural source whereby a dissolved sodium carbonate product is treated with a cationic compound, such as a quaternary amine, to react with carbon-containing contaminants and filtering the product. The filtered modified sodium carbonate solution is then crystallized and dried. The modified sodium carbonate has a greater reactivity or uptake of carbon dioxide for the manufacture of sodium bicarbonate than conventional sodium carbonates.