Abstract: A method of forming an LMNO cathode with electrolytic manganese dioxide includes dissolving metallic manganese in acid to create a dissolved manganese solution, disposing the solution within an electrolytic cell including an electrolytic cell anode and an electrolytic cell cathode, and applying a current between the cell anode and the cell cathode to the solution. Applying the current forms an MnO2 deposit upon the cell anode. The method further includes harvesting the deposit, creating a manganese precursor by neutralizing the deposit and grinding the deposit to form an MnO2 powder, and mixing the manganese precursor with a nickel precursor and a lithium precursor to create a mixture. The method further includes calcining the mixture to create an LMNO powder and coating a current collector with the LMNO powder to thereby form the LMNO cathode. The method may include testing the cathode electrode in an electrochemical pouch format cell.

Abstract: The concepts described herein provide a hybrid metal/polymer current collector for a battery cell electrode that includes a collector body joined to a tab portion and encased in an electrically conductive overlay, and an associated method of manufacture. The tab portion is fabricated from a homogeneous electrically conductive material, the collector body is fabricated from a polymer, and the collector body is joined to the tab portion at a junction.

Abstract: The present disclosure relates to over-lithiated positive electroactive materials for use within an electrochemical cell. For example, the electrochemical cell includes a positive electrode that includes an over-lithiated positive electroactive material that includes one of LixMn2O4 (where 1.05?x?1.30) and LiMn(2?x)NixO4 (where 0?x?0.5). The electrochemical cell can include a negative electrode that includes a silicon-containing negative electroactive material having a Columbic Efficiency greater than or equal to about 80% and less than or equal to about 90%.

Abstract: An electrolyte solution for a lithium metal battery is provided. The electrolyte solution includes lithium bis(fluorosulfonyl)imide dissolved in a fluorinated ether solvent. The electrolyte solution further includes a first additive including fluoroethylene carbonate and a second additive including lithium difluorophosphate. In one embodiment, the fluorinated ether solvent includes fluorinated 1,4 dimethoxy butane.

Abstract: The present disclosure relates to over-lithiated positive electroactive materials for use within an electrochemical cell. For example, the electrochemical cell includes a positive electrode that includes an over-lithiated positive electroactive material that includes one of LixMn2O4 (where 1.05?x?1.30) and LiMn(2?x)NixO4 (where 0?x?0.5). The electrochemical cell can include a negative electrode that includes a silicon-containing negative electroactive material having a Columbic Efficiency greater than or equal to about 80% and less than or equal to about 90%.

Abstract: A lithium ion battery is provided that includes a positive electrode, a negative electrode, and a separator disposed between the positive electrode and the negative electrode. One or more of the separator, positive electrode, and negative electrode includes a transition metal compound capable of catalyzing any gaseous reactants formed in the lithium ion battery to form a liquid. The transition metal compound may include ruthenium (Ru). In certain variations, the lithium ion battery includes an electrolyte that is a conductive medium for lithium ions to move between the positive electrode and the negative electrode. The electrolyte comprises a transition metal compound capable of catalyzing a reaction of any gaseous reactants to form a liquid.

Abstract: A lithium ion batteries and electric vehicles including lithium ion batteries are provided. An exemplary lithium ion battery includes a cathode including a cathode active material comprising at least 50 wt. %, based on a total weight of the cathode active material, of LiFexMn(1-x)PO4, wherein X is from 0.01 to 0.5.

Abstract: A lithium ion battery is provided that includes a positive electrode, a negative electrode, and a separator disposed between the positive electrode and the negative electrode. One or more of the separator, positive electrode, and negative electrode includes a transition metal compound capable of catalyzing any gaseous reactants formed in the lithium ion battery to form a liquid. The transition metal compound may include ruthenium (Ru). In certain variations, the lithium ion battery includes an electrolyte that is a conductive medium for lithium ions to move between the positive electrode and the negative electrode. The electrolyte comprises a transition metal compound capable of catalyzing a reaction of any gaseous reactants to form a liquid.

Abstract: An electrochemical cell comprises an electrolyte capable of facilitating ion transfer between an anode and a cathode. A method for identifying and/or characterizing a soft short in an electrochemical cell comprises cooling the electrochemical cell to an observation temperature at which inter-electrolyte ion migration is substantially inhibited, observing the open circuit voltage (OCV) of the electrochemical cell at the observation temperature for a period of time, and determining the presence of a soft short in the electrochemical cell if the OCV reaches a minimum threshold voltage prior to the expiration of the period of time. The method can optionally further include generating an impedance spectrum for the cell via potentiostatic electrochemical impedance spectroscopy (PETS) at or below the observation temperature, and defining the cell leakage resistance as the maximum impedance limit of the impedance spectrum. The observation temperature can comprise the glass transition temperature of the electrolyte.

Abstract: An electrochemical cell comprises an electrolyte capable of facilitating ion transfer between an anode and a cathode. A method for identifying and/or characterizing a soft short in an electrochemical cell comprises cooling the electrochemical cell to an observation temperature at which inter-electrolyte ion migration is substantially inhibited, observing the open circuit voltage (OCV) of the electrochemical cell at the observation temperature for a period of time, and determining the presence of a soft short in the electrochemical cell if the OCV reaches a minimum threshold voltage prior to the expiration of the period of time. The method can optionally further include generating an impedance spectrum for the cell via potentiostatic electrochemical impedance spectroscopy (PETS) at or below the observation temperature, and defining the cell leakage resistance as the maximum impedance limit of the impedance spectrum. The observation temperature can comprise the glass transition temperature of the electrolyte.

Abstract: System and methods for determining performance degradation of a battery system are presented. In certain embodiments, the disclosed systems and methods may involve testing, monitoring, and/or modeling of battery system cyclic performance degradation at a single battery system operating temperature. The disclosed systems and methods may offer certain efficiencies over conventional techniques for determining cyclic degradation of a battery system. Such efficiencies may allow the disclosed systems and methods to be implemented in connection with real-time battery state estimation methods.

Abstract: System and methods for determining performance degradation of a battery system are presented. In certain embodiments, the disclosed systems and methods may involve testing, monitoring, and/or modeling of battery system cyclic performance degradation at a single battery system operating temperature. The disclosed systems and methods may offer certain efficiencies over conventional techniques for determining cyclic degradation of a battery system. Such efficiencies may allow the disclosed systems and methods to be implemented in connection with real-time battery state estimation methods.

Abstract: Disclosed herein is a process of reducing water content within a lithium battery comprising contacting at least one component of the lithium battery having an initial amount of water, with a halogen substituted silicon compound capable of reaction with water, at a concentration, temperature, pressure, and for a period of time sufficient to reduce the initial amount of water. Also disclosed is a process of removing water from a lithium battery cell, comprising disposing within the lithium battery cell having an initial amount of water, a halogen substituted silicon compound capable of reaction with water, at a concentration sufficient to reduce the initial amount of water within the cell. Also disclosed is a lithium battery made from the disclosed processes.