Abstract: A method and system for purification of helium and CO2 from a stream containing at least Helium, CO2, nitrogen or methane uses a combination of cryogenic, membrane and adsorption technologies.

Abstract: Processes for producing hydrogen from a source gas comprising natural gas are described. A process comprises catalytic reaction of a source gas to produce a product stream. The product stream may then be subjected to a number of conversion and/or purification steps to produce a hydrogen product. The hydrogen product may be recycled to the catalytic reactor or a gas turbine as a source of fuel and/or heat to the catalytic reaction.

Abstract: A thermally integrated separation method, including exchanging heat indirectly between an inlet stream and a liquid carbon dioxide/NGL containing stream in a heat exchanger, thereby producing a cold inlet stream and a vaporized carbon dioxide/NGL containing stream, introducing the cold inlet stream into a cryogenic separation unit, thereby producing the liquid carbon dioxide/NGL containing stream and a methane-rich stream, introducing the methane-rich stream into a membrane separation unit, thereby producing a methane rich product stream, and a permeate stream, and introducing the vaporized carbon dioxide/NGL containing stream into a carbon dioxide/NGL separation unit, thereby producing a carbon dioxide rich product stream and a NGL rich product stream. Wherein, at least a portion of the liquid carbon dioxide/NGL containing stream bypasses the heat exchanger and is introduced into the carbon dioxide/NGL separation unit in liquid phase.

Abstract: A method of efficient cold recovery from a liquid hydrogen stream includes warming a cold liquid hydrogen stream by indirect heat exchange with a cold feed air stream in an ASU sub-cooler, thereby producing a warmed liquid hydrogen stream. Wherein at least a portion of the cool inlet air stream is introduced into a cold booster, thereby producing the compressed cool feed air stream. Wherein at least a first portion of the further cooled feed air stream is introduced into an expander, thereby producing an expanded feed air stream. Wherein a second portion of the further cooled feed air stream is further cooled, thereby producing the cold feed air stream. And, wherein the liquid oxygen stream has a first molar mass flow rate, and the cold liquid hydrogen stream has a second molar flow rate that is between 1.5 and 2.5 times the first molar mass flow rate.

Abstract: A method for liquefying ammonia can include the steps of: providing a pressurized carbon dioxide stream from a power generating facility; expanding the pressurized carbon dioxide stream to a lower pressure that is sufficient to produce a dual phase carbon dioxide fluid; introducing the dual phase carbon dioxide fluid to a gas-liquid separator; withdrawing a liquid stream from the gas-liquid separator; and liquefying an ammonia gas stream in an ammonia liquefier by indirect contact with the liquid stream from the gas-liquid separator, thereby forming a liquid ammonia stream and a gaseous carbon dioxide stream.

Abstract: A method and system for purification of helium and CO2 from a stream containing at least Helium, CO2, nitrogen or methane uses a combination of cryogenic, membrane and adsorption technologies.

Abstract: A method for increasing the reliability and availability of a cryogenic fluid reliquefaction system is provided. It may comprise at least N sub-coolers comprising a motor and a compressor and at least one variable speed. It may comprise N?1 variable speed systems to be shared between the motors and compressors if N equals 2, or N?2 variable speed systems to be shared between the motors and compressors if N is greater than 2. It may comprise two different liquid cryogenic fluid users are provided liquid cryogenic fluid, utilizing two different main cryogenic tanks, with a common sub-cooler and recirculation loop, wherein the pressure in the two different main cryogenic tanks are controlled with pressure controllers acting on two different subcooled liquid cryogenic fluid valves. And or, it may comprise at least one liquid cryogenic fluid user is provided refrigeration from two or more sub-cooling systems in a lead-lag arrangement.

Abstract: A method for increasing the reliability and availability of a cryogenic fluid reliquefaction system is provided. Wherein the liquid cryogenic fluid is supplied to a cryogenic liquid user in the absence of a pump by elevating the storage height of the main cryogenic storage tank relative to the liquid cryogenic liquid user to a minimum predetermined height. Wherein the temperature of the liquid cryogenic fluid downstream of the sub-cooler is at least 1 degree Celsius above the freezing point of the cryogenic fluid at the internal pressure. The method also includes controlling the internal pressure of the main cryogenic tank by adjusting the recirculation flow to the, and maintaining the cold supply to the liquid cryogenic fluid user when the sub-cooling line is reduced or stopped by venting the vaporized cryogenic fluid.

Abstract: A method for liquefying ammonia can include the steps of: providing a pressurized carbon dioxide stream from a power generating facility; expanding the pressurized carbon dioxide stream to a lower pressure that is sufficient to produce a dual phase carbon dioxide fluid; introducing the dual phase carbon dioxide fluid to a gas-liquid separator; withdrawing a liquid stream from the gas-liquid separator; and liquefying an ammonia gas stream in an ammonia liquefier by indirect contact with the liquid stream from the gas-liquid separator, thereby forming a liquid ammonia stream and a gaseous carbon dioxide stream.

Abstract: A method for temperature-controlled delivery of the gaseous product at temperatures at or below ambient in the event of an air separation unit failure. In one embodiment, a first portion of a stored cryogenic liquid product is sent to the back-up vaporizer and heated to ambient conditions, and a second portion of stored cryogenic liquid product, which is at the cryogenic storage temperature, bypasses the back-up vaporizer using a bypass line controlled by a bypass valve and is mixed with the vaporized gas. This mixed stream will then preferably go through a static mixer in order to get to an homogenous temperature that is below the ambient temperature. A temperature control loop can be used to adjust the opening of the by-pass valve in order to reach the desired product temperature.

Abstract: A method of separating hydrocarbons containing three or more carbon atoms from an off-gas stream is provided. This method includes separating a light ends stream from a fractionator, thereby producing a stream rich in hydrocarbons containing three or more carbon atoms, and a stream lean in hydrocarbons containing three or more carbon atoms, separating the stream lean in hydrocarbons containing three or more carbon atoms in a membrane unit, thereby producing a permeate stream enriched in hydrocarbons containing three or more carbon atoms and a retentate stream, and separating the stream rich in hydrocarbons containing three or more carbon atoms in one or more separation columns, thereby producing one or more streams selected from the group consisting of a propylene stream, a propane stream, a butane stream, a light cat naptha stream, and a heavy cat naptha stream.

Abstract: A method of temperature balancing for thermal integration of an air separation unit (ASU) with an oxycombustion power generation system, including compressing air through a plurality of compression stages, and routing a first stage compressed air stream through a first heat exchanger in heat exchange communication with a subsequent stage compressed air stream to lower the first stage compressed air stream temperature and increase the temperature of a subsequent stage compressed air stream.