Abstract: Disclosed herein is an erosion and corrosion resistant coating comprising a metallic binder, a plurality of hard particles, and a plurality of sacrificial particles. Also disclosed is a method of improving erosion and corrosion resistance of a metal component comprising disposing on a surface of the metal component the foregoing erosion and corrosion resistant coating comprising, and a metal component comprising a metal component surface and the foregoing erosion and corrosion resistant coating comprising a first surface and a second surface opposite the first surface, wherein the first surface is disposed on the metal component surface.

Abstract: A coating system and a method of applying the coating system on an article. The coating system includes a sacrificial coating on a surface of the article and an erosion-resistant coating on the sacrificial coating, wherein the erosion-resistant coating comprises a layer of a polymeric material. The sacrificial coating is more anodic than the surface or the erosion-resistant coating.

Abstract: A treatment process, an oxide-forming treatment composition, and a treated component are disclosed. The treatment process includes applying an oxide-forming treatment composition to a ceramic coating and heating the oxide-forming treatment composition to form an oxide within the ceramic coating. The oxide-forming treatment composition includes a solute and a corrosion inhibitor. The oxide-forming treatment composition is super-saturated with the corrosion inhibitor. The treated component includes a ceramic coating and one or both of a corrosion inhibitor and an oxide formed by an oxide-forming treatment composition having the corrosion inhibitor. The corrosion inhibitor and the oxide-forming treatment composition are within the ceramic coating.

Abstract: A vanadium resistant coating system resistant to high temperature vanadium attack. The system comprises a high temperature superalloy substrate. A bond coat overlies the superalloy substrate. The bond coat may be applied in multiple layers. A ceramic coating overlies the bond coat. The ceramic coating further comprises a zirconium oxide stabilized by at least one cation selected from the group consisting of Yb3+, Lu3+, Sc3+ and Ce4+, in the amounts of about 5-10 weight percent. An overcoat may overlie the ceramic coating. The overcoat may be a sacrificial layer of YSZ infiltrated with cations having an atomic radius larger than Y3+. Alternatively, the overcoat may comprise zirconium oxide stabilized by Ce4+.

Abstract: A vanadium resistant coating system resistant to high temperature vanadium attack. The system comprises a high temperature superalloy substrate. A bond coat overlies the superalloy substrate. The bond coat may be applied in multiple layers. A ceramic coating overlies the bond coat. The ceramic coating further comprises a zirconium oxide stabilized by at least one cation selected from the group consisting of Yb3+, Lu3+, Sc3+ and Ce4+, in the amounts of about 5-10 weight percent. An overcoat may overlie the ceramic coating. The overcoat may be a sacrificial layer of YSZ infiltrated with cations having an atomic radius larger than Y3+. Alternatively, the overcoat may comprise zirconium oxide stabilized by Ce4+.

Abstract: An article comprises a first outer layer; a second intermediate layer; and a substrate; wherein the second intermediate layer contacts the first outer layer at a first interface and the substrate at a second interface. The first outer layer comprises Al2O3—TiO2 and the second intermediate layer comprises a functionally graded material. The functionally graded material comprises a composition proximate the first interface being substantially free of Al2O3—TiO2 and at the second interface having Al2O3—TiO2 in amounts substantially equal to the first outer layer.

Abstract: A sacrificial and erosion-resistant turbine compressor airfoil includes a turbine compressor airfoil having a modified airfoil surface. The airfoil surface has an airfoil coating that includes a sacrificial coating comprising a layer of Al, Cr, Zn, an Ni—Al alloy, an Al—Si alloy, an Al-based alloy, a Cr-based alloy or a Zn-based alloy, an Al polymer composite, or a combination thereof, or a layer of a conductive undercoat and an overcoat of an inorganic matrix binder having a plurality of ceramic particles and conductive particles embedded therein disposed on the undercoat. The airfoil coating also includes an sacrificial coating, wherein one of the sacrificial coating or the erosion-resistant coating is disposed on the airfoil surface and the other of the corrosion-resistant coating or the erosion-resistant coating is disposed on the respective one, and wherein the sacrificial coating is more anodic than the airfoil surface or the erosion-resistant coating.

Abstract: A corrosion inhibitor composition for a fuel, comprising a plurality of nanoparticles formed of an inorganic composition having an average longest dimension of 1 nanometer to 100 nanometers, wherein the inorganic active composition is insoluble in the fuel and is adapted to react with a corrosion causing contaminant.

Abstract: Disclosed herein is an erosion and corrosion resistant coating comprising a metallic binder, a plurality of hard particles, and a plurality of sacrificial particles. Also disclosed is a method of improving erosion and corrosion resistance of a metal component comprising disposing on a surface of the metal component the foregoing erosion and corrosion resistant coating comprising, and a metal component comprising a metal component surface and the foregoing erosion and corrosion resistant coating comprising a first surface and a second surface opposite the first surface, wherein the first surface is disposed on the metal component surface.

Abstract: In one embodiment, a coated turbine article comprising a uniform enhanced coating on at least a portion of the turbine article, wherein the enhanced coating comprises a coating material and a structural enhancer, wherein the structural enhancer is selected from the group consisting of oxide, carbide, nitride, intermetallic material, and combinations comprising at least one of the foregoing, wherein the structural enhancer has an average particle size, as measured along a major axis, of about 0.01 ?m to about 100 ?m.

Abstract: A coating system and process capable of providing erosion and corrosion-resistance to a component, particularly a steel compressor blade of an industrial gas turbine. The coating system includes a metallic sacrificial undercoat on a surface of the component substrate, and a ceramic topcoat deposited by thermal spray on the undercoat. The undercoat contains a metal or metal alloy that is more active in the galvanic series than iron, and electrically contacts the surface of the substrate. The ceramic topcoat consists essentially of a ceramic material chosen from the group consisting of mixtures of alumina and titania, mixtures of chromia and silica, mixtures of chromia and titania, mixtures of chromia, silica, and titania, and mixtures of zirconia, titania, and yttria.

Abstract: A method of forming a composite powder coating comprises depositing multiple layers of a powder coating composition onto a substrate, wherein adjacent layers are formed of a different powder coating composition; and curing the multiple layers of the powder coating composition in a single thermal curing step. The layers can be used to protect power generation equipment from aqueous corrosion, particle erosion, slurry erosion, fretting, and foulig.

Abstract: A corrosion inhibitor composition for a fuel, comprising a plurality of nanoparticles formed of an inorganic composition having an average longest dimension of 1 nanometer to 100 nanometers, wherein the inorganic active composition is insoluble in the fuel and is adapted to react with a corrosion causing contaminant.

Abstract: The article comprising an antifouling surface is provided. The surface comprises a material having a nominal liquid wettability sufficient to generate, with reference to an oil, a nominal contact angle of at least about 30 degrees; and a texture comprising a plurality of features disposed on the surface. The features have a size, shape, and orientation selected such that the surface has an effective wettability sufficient to generate, with reference to an oil, an effective contact angle greater than the nominal contact angle. The features comprise a height dimension (h), a width dimension (a), a spacing dimension (b) such that, ratio b/a is less than about 4, and ratio h/a is less than about 10. In one embodiment, a turbine component comprising an antifouling surface is provided.

Abstract: The addition of a magnesium compound to an ash bearing fuel results in a reduction in the formation of deposits in the turbine and extending the interval between turbine washes when burning the ash bearing fuel in a turbine compared to burning the ash bearing fuel in a turbine without the addition of a magnesium compound. The additive is desirably effective with ash bearing fuel having less than 0.5 ppm vanadium by weight, less than 1 ppm sodium and potassium combined by weight, and greater than about 25 ppm ash by weight or greater than 2 ppm calcium by weight. The additive is blended with the ash bearing fuel to give a mass ratio of magnesium to ash of between about 0.5 to 1 and about 3 to 1, and desirably about 1 to 1 on a mass basis after mixing.

Abstract: A system for continuously removing alkali metal contaminants from liquid fuel supplied to a combustor of a gas turbine comprising a source of fuel; means for supplying the fuel to the gas turbine; a prefilter downstream of the source and upstream of the gas turbine for removing solid particulates from the liquid fuel; and a coalescer located downstream of the prefilter and upstream of the gas turbine for separating water containing alkali metals from the liquid fuel.

Abstract: A system for continuously removing alkali metal contaminants from liquid fuel supplied to a combustor of a gas turbine comprising a source of fuel; means for supplying the fuel to the gas turbine; a prefilter downstream of the source and upstream of the gas turbine for removing solid particulates from the liquid fuel; and a coalescer located downstream of the prefilter and upstream of the gas turbine for separating water containing alkali metals from the liquid fuel.

Abstract: A fluid analyte measurement system includes an extraction unit having a fluid flow path in intimate contact with an extraction solution flow path. The fluid flow path includes a fluid entry port and a fluid exit port and the extraction solution flow path includes an extraction solution flow entry port and an extraction solution flow exit port. The extraction unit extracts analytes from a fluid flow introduced within the fluid flow path through exposure of the fluid flow to an extraction solution introduced within the extraction solution flow path. A sample head vessel is coupled to the extraction solution flow exit port and at least one probe is coupled to the sample head vessel to generate signals indicative of the characteristics of the fluid flow analytes within the extraction solution flow. For example, this measurement system can be used to determine Na+ level within fuel oil. Circuitry is coupled to the probe(s), which circuitry is configured to measure the signals generated by the probe(s).