Patents by Inventor Virginio Arrigoni

Virginio Arrigoni has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 7754637
    Abstract: The present invention relates to a catalytic composition which comprises a beta zeolite, a metal of group VIII, a metal of group VI B and optionally one or more oxides as carrier. The catalytic system of the present invention can be used for the hydrotreating of hydrocarbon mixtures and more specifically in the upgrading of hydrocarbon mixtures having boiling ranges within the range of 35° to 250° C., containing sulfur impurities, i.e. in hydrodesulfuration with contemporaneous skeleton isomerization and a reduced hydrogenation degree of olefins contained in said hydrocarbon mixtures, the whole process being carried out in a single step.
    Type: Grant
    Filed: December 6, 2006
    Date of Patent: July 13, 2010
    Assignees: AGIP Petroli S.p.A., Enitecnologie S.p.A.
    Inventors: Laura Zanibelli, Marco Ferrari, Virginio Arrigoni
  • Publication number: 20070084756
    Abstract: The present invention relates to a catalytic composition which comprises a beta zeolite, a metal of group VIII, a metal of group VI B and optionally one or more oxides as carrier. The catalytic system of the present invention can be used for the hydrotreating of hydrocarbon mixtures and more specifically in the upgrading of hydrocarbon mixtures having boiling ranges within the range of 35° to 250° C., containing sulfur impurities, i.e. in hydrodesulfuration with contemporaneous skeleton isomerization and a reduced hydrogenation degree of olefins contained in said hydrocarbon mixtures, the whole process being carried out in a single step.
    Type: Application
    Filed: December 6, 2006
    Publication date: April 19, 2007
    Applicants: AGIP PETROLI S.p.A., ENITECNOLOGIE S.p.A.
    Inventors: Laura ZANIBELLI, Marco FERRARI, Virginio ARRIGONI
  • Patent number: 7196029
    Abstract: The present invention relates to the use of a catalytic system comprising a metal of group VIII, a metal of group VI, a metal oxide as carrier and suitable quantities of a component selected from a zeolite of the FER type, phosphorous, and a mixture thereof, in upgrading of hydrocarbons boiling in the naphtha range containing sulfur impurities, namely in hydrodesulfurization with contemporaneous skeleton isomerization of olefins contained in said hydrocarbons and/or with reduction of olefins hydrogenation, carried out in a single step.
    Type: Grant
    Filed: April 7, 2004
    Date of Patent: March 27, 2007
    Assignees: Enitechnologie S.p.A., Repsol Petroleo S.A., Elf Antar France S.A., AGIP Petroli S.p.A.
    Inventors: Laura Zanibelli, Virginio Arrigoni, Fernando Albertos, Evangelina Atanes, Thierry Cholley, Febronio Panarello
  • Patent number: 7160439
    Abstract: A process is described for the upgrading of hydrocarbon mixtures which boil within the naphtha range containing sulfur impurities, i.e. a hydrodesulfuration process with contemporaneous skeleton isomerization and reduced hydrogenation degree of the olefins contained in said hydrocarbon mixtures, the whole process being carried out in a single step. The process is carried out in the presence of a catalytic system comprising a metal of group VI B, a metal of group VIII and a carrier of acid nature consisting of a mesoporous silico-alumina.
    Type: Grant
    Filed: February 13, 2004
    Date of Patent: January 9, 2007
    Assignees: AgipPetroli S.p.A., EniTecnologie S.p.A.
    Inventors: Laura Maria Zanibelli, Virginio Arrigoni, Marco Ferrari, Donatella Berti
  • Patent number: 7157397
    Abstract: A process is described for the synthesis of mesitylene, characterized in that mesitylene is obtained starting exclusively from pseudocumene, without the use of any other chemical compound, operating in continuous, at a temperature ranging from 225 to 400° C., at a pressure ranging from 1 to 50 bar, at a weight space velocity ranging from 0.1 to 10 hours?1, and in the presence of a catalyst containing a zeolite selected from ZSM-5 zeolite having a crystal lattice based on silicon oxide and aluminum oxide, and ZSM-5 zeolite modified by the partial or total substitution of Si with a tetravalent element such as Ti or Ge and/or the partial or total substitution of Al with other trivalent elements, such as Fe, Ga or B.
    Type: Grant
    Filed: February 26, 2004
    Date of Patent: January 2, 2007
    Assignees: Polimeri Europa S.p.A., Enitecnologie S.p.A.
    Inventors: Leonardo Dalloro, Alberto Cesana, Robert{dot over (o)} Buzzoni, Franco Rivetti, Giovanni Antonio Fois, Caterina Rizzo, Virginio Arrigoni
  • Patent number: 7156980
    Abstract: The present invention relates to a catalytic composition which comprises a beta zeolite, a metal of group VIII, a metal of group VI B and optionally one or more oxides as carrier. The catalytic system of the present invention can be used for the hydrotreating of hydrocarbon mixtures and more specifically in the upgrading of hydrocarbon mixtures having boiling ranges within the range of 35° to 250° C., containing sulfur impurities, i.e. in hydrodesulfuration with contemporaneous skeleton isomerization and a reduced hydrogenation degree of olefins contained in said hydrocarbon mixtures, the whole process being carried out in a single step.
    Type: Grant
    Filed: July 15, 2004
    Date of Patent: January 2, 2007
    Assignees: Agip Petroli S.p.A., Enitechnologie S.p.A.
    Inventors: Laura Zanibelli, Marco Ferrari, Virginio Arrigoni
  • Patent number: 6949687
    Abstract: A process is described for the contemporaneous preparation of mesitylene and durene, characterized in that mesitylene and durene are obtained exclusively starting from pseudo-cumene without the use of any further chemical compound, operating in continuous, at a temperature ranging from 210 to 400° C., at a pressure ranging from 1 to 50 bar, with a weight space velocity ranging from 0.1 to 20 hours?1 and in the presence of a catalyst based on crystalline metal-silicates in acid form. After the recovery of mesitylene and durene from the reaction raw product, some of the remaining components of the raw product itself are recycled and fed to the reactor together with the pseudo-cumene.
    Type: Grant
    Filed: December 17, 2003
    Date of Patent: September 27, 2005
    Assignees: Polimeri Europa S.p.A., Enitecnologie S.p.A.
    Inventors: Leonardo Dalloro, Alberto Cesana, Roberto Buzzoni, Franco Rivetti, Caterina Rizzo, Virginio Arrigoni, Carlo Perego
  • Patent number: 6908880
    Abstract: A process is described for the upgrading of hydrocarbon mixtures which boil within the naphtha range containing sulfur impurities, i.e. a hydrodesulfuration process with contemporaneous skeleton isomerization and reduced hydrogenation degree of the olefins contained in said hydrocarbon mixtures, the whole process being carried out in a single step. The process is carried out in the presence of a catalytic system comprising a metal of group VIB, a metal of group VIII and a carrier of acid nature consisting of a mesoporous silico-alumina.
    Type: Grant
    Filed: May 21, 2002
    Date of Patent: June 21, 2005
    Assignees: AgipPetroli S.p.A., EniTechnologie S.p.A.
    Inventors: Laura Maria Zanibelli, Virginio Arrigoni, Marco Ferrari, Donatella Berti
  • Publication number: 20040248726
    Abstract: The present invention relates to a catalytic composition which comprises a beta zeolite, a metal of group VIII, a metal of group VI B and optionally one or more oxides as carrier. The catalytic system of the present invention can be used for the hydrotreating of hydrocarbon mixtures and more specifically in the upgrading of hydrocarbon mixtures having boiling ranges within the range of 35° to 250° C., containing sulfur impurities, i.e. in hydrodesulfuration with contemporaneous skeleton isomerization and a reduced hydrogenation degree of olefins contained in said hydrocarbon mixtures, the whole process being carried out in a single step.
    Type: Application
    Filed: July 15, 2004
    Publication date: December 9, 2004
    Applicants: AGIP PETROLI S.p.A., ENITECNOLOGIE S.p.A.
    Inventors: Laura Zanibelli, Marco Ferrari, Virginio Arrigoni
  • Publication number: 20040222132
    Abstract: A process is described for the upgrading of hydrocarbon mixtures which boil within the naphtha range containing sulfur impurities, i.e. a hydrodesulfuration process with contemporaneous skeleton isomerization and reduced hydrogenation degree of the olefins contained in said hydrocarbon mixtures, the whole process being carried out in a single step. The process is carried out in the presence of a catalytic system comprising a metal of group VI B, a metal of group VIII and a carrier of acid nature consisting of a mesoporous silico-alumina.
    Type: Application
    Filed: February 13, 2004
    Publication date: November 11, 2004
    Applicant: ENITECHNOLOGIE S.p.A.
    Inventors: Laura Maria Zanibelli, Virginio Arrigoni, Marco Ferrari, Donatella Berti
  • Publication number: 20040225170
    Abstract: A process is described for the synthesis of mesitylene, characterized in that mesitylene is obtained starting exclusively from pseudocumene, without the use of any other chemical compound, operating in continuous, at a temperature ranging from 225 to 400° C., at a pressure ranging from 1 to 50 bar, at a weight space velocity ranging from 0.1 to 10 hours−1, and in the presence of a catalyst containing a zeolite selected from ZSM-5 zeolite having a crystal lattice based on silicon oxide and aluminum oxide, and ZSM-5 zeolite modified by the partial or total substitution of Si with a tetravalent element such as Ti or Ge and/or the partial or total substitution of Al with other trivalent elements, such as Fe, Ga or B.
    Type: Application
    Filed: February 26, 2004
    Publication date: November 11, 2004
    Applicants: POLIMERI EUROPA S.p.A., ENITECNOLOGIE S.p.A.
    Inventors: Leonardo Dalloro, Alberto Cesana, Roberto Buzzoni, Franco Rivetti, Giovanni Antonio Fois, Caterina Rizzo, Virginio Arrigoni
  • Patent number: 6803337
    Abstract: The present invention relates to a catalytic composition which comprises a beta zeolite, a metal of group VIII, a metal of group VIB and optionally one or more oxides as carrier. The catalytic system of the present invention can be used for the hydrotreating of hydrocarbon mixtures and more specifically in the upgrading of hydrocarbon mixtures having boiling ranges within the range of 35° to 250° C., containing sulfur impurities, i.e. in hydrodesulfuration with contemporaneous skeleton isomerization and a reduced hydrogenation degree of olefins contained in said hydrocarbon mixtures, the whole process being carried out in a single step.
    Type: Grant
    Filed: March 10, 2000
    Date of Patent: October 12, 2004
    Assignees: Agip Petroli S.p.A., Enitecnologie S.p.A.
    Inventors: Laura Zanibelli, Marco Ferrari, Virginio Arrigoni
  • Publication number: 20040192540
    Abstract: The present invention relates to the use of a catalytic system comprising a metal of group VIII, a metal of group VI, a metal oxide as carrier and suitable quantities of a component selected from a zeolite of the FER type, phosphorous, and a mixture thereof, in upgrading of hydrocarbons boiling in the naphtha range containing sulfur impurities, namely in hydrodesulfurization with contemporaneous skeleton isomerization of olefins contained in said hydrocarbons and/or with reduction of olefins hydrogenation, carried out in a single step.
    Type: Application
    Filed: April 7, 2004
    Publication date: September 30, 2004
    Applicants: ENITECHNOLOGIE S.p.A., REPSOL PETROLEO S.A., Elf Antar France, AGIP PETROLI S.p.A.
    Inventors: Laura Zanibelli, Virginio Arrigoni, Fernando Albertos, Evangelina Atanes, Thierry Cholley, Febronio Panarello
  • Publication number: 20040127762
    Abstract: A process is described for the contemporaneous preparation of mesitylene and durene, characterized in that mesitylene and durene are obtained exclusively starting from pseudo-cumene without the use of any further chemical compound, operating in continuous, at a temperature ranging from 210 to 400° C., at a pressure ranging from 1 to 50 bar, with a weight space velocity ranging from 0.1 to 20 hours−1 and in the presence of a catalyst based on crystalline metal-silicates in acid form. After the recovery of mesitylene and durene from the reaction raw product, some of the remaining components of the raw product itself are recycled and fed to the reactor together with the pseudo-cumene.
    Type: Application
    Filed: December 17, 2003
    Publication date: July 1, 2004
    Applicants: POLIMERI EUROPA S.p.A., ENITECNOLOGIE S.p.A.
    Inventors: Leonardo Dalloro, Alberto Cesana, Roberto Buzzoni, Franco Rivetti, Caterina Rizzo, Virginio Arrigoni, Carlo Perego
  • Patent number: 6746598
    Abstract: The present invention relates to the use of a catalytic system comprising a metal of group VIII, a metal of group VI, a metal oxide as carrier and suitable quantities of a component selected from a zeolite of the FER type, phosphorous, and a mixture thereof, in upgrading of hydrocarbons boiling in the naphtha range containing sulfur impurities, namely in hydrodesulfurization with contemporaneous skeleton isomerization of olefins contained in said hydrocarbons and/or with reduction of olefins hydrogenation, carried out in a single step.
    Type: Grant
    Filed: April 6, 2001
    Date of Patent: June 8, 2004
    Assignees: Enitecnologie S.p.A., Repsol Petroleo S.A., Elf Antar France S.A., AGIP Petroli S.p.A.
    Inventors: Laura Zanibelli, Virginio Arrigoni, Fernando Albertos, Evangelina Atanes, Thierry Cholley, Febronio Panarello
  • Publication number: 20030038059
    Abstract: A process is described for the upgrading of hydrocarbon mixtures which boil within the naphtha range containing sulfur impurities, i.e. a hydrodesulfuration process with contemporaneous skeleton isomerization and reduced hydrogenation degree of the olefins contained in said hydrocarbon mixtures, the whole process being carried out in a single step. The process is carried out in the presence of a catalytic system comprising a metal of group VI B, a metal of group VIII and a carrier of acid nature consisting of a mesoporous silico-alumina.
    Type: Application
    Filed: May 21, 2002
    Publication date: February 27, 2003
    Applicant: AGIPPETROLI S.p.A.
    Inventors: Laura Maria Zanibelli, Virginio Arrigoni, Marco Ferrari, Donatella Berti
  • Patent number: 5650547
    Abstract: This invention provides a process for the selective production of cumene comprising reacting benzene with propylene in the presence of a type-Y zeolite modified by treatment with a phosphorous compound. This invention also provides a process for the transalkylation of a polyalkylated benzene which comprises reacting the polyalkylated benzene in the presence of benzene and a type-Y zeolite modified by treatment with a phosphorous compound.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: July 22, 1997
    Assignee: Ministero Dell `Universita` E Della Ricerca Scientifica E Technologica
    Inventors: Fabrizio Cavani, Gianni Girotti, Virginio Arrigoni, Giuseppe Terzoni
  • Patent number: 5149896
    Abstract: A process for oligomerizing propylene is described, consisting of reacting said olefin in the presence of an X-ray amorphous alumina-silica gel catalyst with a silica/alumina molar ratio of between 30/1 and 500/1, a surface area of between 500 and 1000 m.sup.2 /g, a total pore volume of between 0.3 and 0.6 ml/g, an average pore diameter of the order of 10 .ANG. or less, and free or substantially free of pores with a diameter greater than 30 .ANG..
    Type: Grant
    Filed: June 14, 1991
    Date of Patent: September 22, 1992
    Assignee: Eniricerche S.p.A.
    Inventors: Giuseppe Bellussi, Fabrizio Cavani, Virginio Arrigoni, Roberto Ghezzi
  • Patent number: 4992608
    Abstract: Cumene is prepared by alkylation of benzene with propylene, or by transalkylation of diisopropylbenzenes in the presence of benzene, on a silica and alumina gel catalyst which is amorphous to X-rays and has an SiO.sub.2 /Al.sub.2 O.sub.3 ratio of between 50/1 and 300/1, a surface area of between 500 and 1000 m.sup.2 /g, an overall pore volume of between 0.3 and 0.6 ml/g and mean pore diameter of the order of 10 .ANG., and which is free or substantially free of pores having a diameter exceeding 30 .ANG..
    Type: Grant
    Filed: April 24, 1989
    Date of Patent: February 12, 1991
    Assignees: Enichem Synthesis SpA, Eniricerche SpA
    Inventors: Fabrizio Cavani, Virginio Arrigoni