Abstract: Disclosed herein is a process that includes: (a) providing a powder blend comprising (1) one or more hydrogenated titanium powders containing around 0.2 to around 3.4 weight % of hydrogen, and (2) one or more master alloys, comprising Al, V, or a combination thereof, (b) consolidating the powder blend by compacting the powder blend to provide a green compact, (c) heating the green compact to a temperature ranging from around 400° C. to around 900° C.

Abstract: The present invention relates to design and manufacture of multilayer sintered membranes made from metals and inorganic compounds (ceramics, silicate, clay, zeolites, phosphates, etc.). The membranes are designated for separation of water. They comprise at least one layer having nanopores commensurable with the size of water molecules. The membranes comprise: (a) supporting metallic layer having pore size 1-500 microns, (b) metallic interlayer having pore size <2 micron, (c) sublayer with local regular protrusions of the interlayer into the supporting layer to increase service life of the membrane, and (d) one nanoporous ceramic or metallic top layer having pore size in the range of 1-15 angstroms. The invented design and method allow the manufacture of cost-effective multilayer membranes containing nanoporous layer with controlled pore sizes in each layer and optimal morphology of pores that provides selective transport of molecules during filtration and separation of liquids.

Abstract: Disclosed herein is a process that includes: (a) providing a powder blend comprising (1) one or more hydrogenated titanium powders containing around 0.2 to around 3.4 weight % of hydrogen, and (2) one or more master alloys, comprising Al, V, or a combination thereof, (b) consolidating the powder blend by compacting the powder blend to provide a green compact, (c) heating the green compact to a temperature ranging from around 400° C. to around 900° C.

Abstract: The invention relates to energy-saving manufacturing of purified hydrogenated titanium powders or alloying titanium hydride powders, by metallo-thermic reduction of titanium chlorides, including their hydrogenation, vacuum separation of titanium hydride sponge block from magnesium and magnesium chlorides, followed by crushing, grinding, and sintering of said block without need for any hydro-metallurgical treatment of the produced powders. Methods disclosed contain embodiments of processes for manufacturing high purity high-purity powders and their use in manufacturing near-net shape titanium and titanium-alloy articles by sintering titanium hydride and alloyed titanium hydride powders produced from combined hydrogen-magnesium reduction of titanium chlorides, halides and hydrides of other metals.

Abstract: A process including: (a) forming a powder blend by mixing titanium powders, (b) consolidating the powder blend by compacting to provide a green compact, (c) heating the green compact thereby releasing absorbed water from the titanium powder, (d) forming ?-phase titanium and releasing atomic hydrogen from the hydrogenated titanium by heating the green compact in an atmosphere of hydrogen emitted by the hydrogenated titanium, (e) reducing surface oxides on particles of the titanium powder with atomic hydrogen released by heating of the green compact, (f) diffusion-controlled chemical homogenizing of the green compact and densification of the green compact by heating followed by holding resulting in complete or partial dehydrogenation to form a cleaned and refined compact, (g) heating the cleaned and refined green compact in vacuum thereby sintering titanium to form a sintered dense compact, and (h) cooling the sintered dense compact to form a sintered near-net shaped article.

Abstract: The present invention relates to design and manufacture of multilayer sintered membranes made from metals and inorganic compounds (ceramics, silicate, clay, zeolites, phosphates, etc.). The membranes are designated for separation of water. They comprise at least one layer having nanopores commensurable with the size of water molecules. The membranes comprise: (a) supporting metallic layer having pore size 1-500 microns, (b) metallic interlayer having pore size <2 micron, (c) sublayer with local regular protrusions of the interlayer into the supporting layer to increase service life of the membrane, and (d) one nanoporous ceramic or metallic top layer having pore size in the range of 1-15 angstroms. The invented design and method allow the manufacture of cost-effective multilayer membranes containing nanoporous layer with controlled pore sizes in each layer and optimal morphology of pores that provides selective transport of molecules during filtration and separation of liquids.

Abstract: The invention is suitable for the manufacture of flat or shaped titanium matrix composite articles having improved mechanical properties such as lightweight plates and sheets for aircraft and automotive applications, heat-sinking lightweight electronic substrates, bulletproof structures for vests, partition walls and doors, as well as for sporting goods such as helmets, golf clubs, sole plates, crown plates, etc. A fully-dense discontinuously-reinforced titanium matrix composite (TMMC) material comprises (a) a matrix of titanium or titanium alloy as a major component, (b) ceramic and/or intermetallic hard particles dispersed in the matrix in the amount of ?50 vol. %, and (c) complex carbide- and/or silicide particles at least partially soluble in the matrix at the sintering or forging temperatures such as Ti4Cr3C6, Ti3SiC2, Cr3C2, Ti3AlC2, Ti2AlC, Al4C3, Al4SiC4, Al4Si2C5, Al8SiC7, V2C, (Ti,V)C, VCr2C2, and V2Cr4C3 dispersed in the matrix in the amount of ?20 vol. %.

Abstract: The invention relates to energy-saving manufacturing of purified hydrogenated titanium powders or alloying titanium hydride powders, by metallo-thermic reduction of titanium chlorides, including their hydrogenation, vacuum separation of titanium hydride sponge block from magnesium and magnesium chlorides, followed by crushing, grinding, and sintering of said block without need for hydrometallurgical treatment of the produced powders. Methods disclosed contain embodiments of processes for manufacturing high-purity powders and their use in manufacturing near-net shape titanium and titanium-alloy articles by sintering titanium hydride and alloyed titanium hydride powders produced from combined hydrogen-magnesium reduction of titanium chlorides, halides and hydrides of other metals.

Abstract: A process including: (a) forming a powder blend by mixing titanium powders, (b) consolidating the powder blend by compacting to provide a green compact, (c) heating the green compact thereby releasing absorbed water from the titanium powder, (d) forming ?-phase titanium and releasing atomic hydrogen from the hydrogenated titanium by heating the green compact in an atmosphere of hydrogen emitted by the hydrogenated titanium, (e) reducing surface oxides on particles of the titanium powder with atomic hydrogen released by heating of the green compact, (f) diffusion-controlled chemical homogenizing of the green compact and densification of the green compact by heating followed by holding resulting in complete or partial dehydrogenation to form a cleaned and refined compact, (g) heating the cleaned and refined green compact in vacuum thereby sintering titanium to form a sintered dense compact, and (h) cooling the sintered dense compact to form a sintered near-net shaped article.

Abstract: The cost-effective hydrogenated, purified titanium powder is manufactured by the semi-continuous process including: (a) magnesium-thermic reduction of titanium chlorides at 830-880° C. in the hydrogen atmosphere characterized by the formation of a hollow porous block of the reaction mass having an open cavity in the center of the block, (b) full thermal-vacuum separation of the hollow block from excessive Mg and MgCl2 at 850-980° C. and residual pressure of 26-266 Pa using a multi-step cycle including: (i) purging hydrogen at 800-950° C. into the reactor at the pressure 10 kPa to 24.

Abstract: The invention relates to manufacture of titanium articles from sintered powders. The cost-effective initial powder: 10-50 wt % of titanium powder having ?500 microns in particle size manufactured from underseparated titanium sponge comprising ?2 wt % of chlorine and ?2 wt % of magnesium; 10-90 wt % of a mixture of two hydrogenated powders A and B containing different amount of hydrogen; 0-90 wt % of standard grade refined titanium powder, and/or 5-50 wt % of alloying metal powders. The method includes: mixing powders, compacting the blend to density at least 60% of the theoretical density, crushing titanium hydride powders into fine fragments at pressure of 400-960 MPa, chemical cleaning and refining titanium powders by heating to 300-900° C. and holding for ?30 minutes, heating in vacuum at 1000-1350° C., holding for ?30 minutes, and cooling.

Abstract: The cost-effective hydrogenated, purified titanium powder is manufactured by the semi-continuous process including: (a) magnesium-thermic reduction of titanium chlorides at 830-880° C. in the hydrogen atmosphere characterized by the formation of a hollow porous block of the reaction mass having an open cavity in the center of the block, (b) full thermal-vacuum separation of the hollow block from excessive Mg and MgCl2 at 850-980° C. and residual pressure of 26-266 Pa using a multi-step cycle including: (i) purging hydrogen at 800-950° C. into the reactor at the pressure 10 kPa to 24.

Abstract: The invention is suitable for the manufacture of flat or shaped titanium matrix composite articles having improved mechanical properties such as lightweight plates and sheets for aircraft and automotive applications, etc. The method for manufacturing TMCC is comprised of the following steps: (a) preparing a basic powdered blend containing matrix alloy or titanium powders, dispersing ceramic and/or intermetallic powders, and powders of said complex carbide- and/or silicide particles, (b) preparing the Al—V master alloy containing ?5 wt. % of iron, (c) preparing the Al—V—Fe master alloy fine powder having a particle size of ?20 ?m, (d) mixing the basic powdered blend with the master alloy powder to obtain a chemical composition of TMCC, (e) compacting the powder mixture at room temperature, (f) sintering at the temperature which provides at least partial dissolution of dispersed powders, (g) forging at 1500-2300° F., and (h) cooling.

Abstract: The invention relates to the cost-effective manufacture of near-net shape titanium articles from sintered powders containing titanium and all required alloying elements. The cost-effective initial powder composition for subsequent room temperature consolidation and sintering contains: (a) 10-50 wt. % of underseparated titanium powder with ?500 ?m in particle size manufactured from underseparated titanium sponge comprising up to 2 wt. % of chlorine and up to 2 wt. % of magnesium. The underseparated titanium powder costs significantly less than that for fully separated powder of completely reduced sponge; (b) 10-90 wt. % of hydrogenated titanium powder, whereby this powder is a mixture of two hydrogenated powders A and B containing different amount of hydrogen: powder A contains amount of hydrogen in the range of 0.2-1 wt. % and powder B contains amount of hydrogen in the range of 2-3.9 wt. %.

Abstract: The method is suitable for the manufacture of flat or shaped titanium aluminide articles and layered metal matrix composites such as lightweight plates and sheets for aircraft and automotive applications, thin cross-section vanes and blades, composite electrodes, heat-sinking lightweight electronic substrates, bulletproof structures for vests, partition walls and doors, as well as for sporting goods such as helmets, golf clubs, sole plates, crown plates, etc.

Abstract: The invention relates to manufacturing the flat or shaped titanium matrix composite articles having improved mechanical properties such as lightweight plates, sheets for aircraft and automotive applications, heat-sinking lightweight electronic substrates, armor plates, etc. High-strength discontinuously-reinforced titanium metal matrix composite (TMMC) comprises (a) titanium matrix or titanium alloy as a major component, (b) ceramic and/or ?50 vol. % intermetallic hard particles dispersed in matrix, (c) complex carbide- and/or boride particles at least partially soluble in matrix at sintering or forging temperatures such as ?50 vol. % AlV2C, AlTi2Si3, AlTi6Si3, VB2, TiVSi2, TiVB4, Ti2AlC, AlCr2C, TiAlV2, V2C, VSi2, Ta3B4, NbTiB4, Al3U2C3 dispersed in matrix. Method for manufacturing these TMMC materials is disclosed. Sintered TMMC density exceeds 98% and closed discontinuous porosity allows performing hot deformation in air without encapsulating.

Abstract: The invention relates to manufacturing of fully dense strips, plates, sheets, and foils from titanium alloys, titanium metal matrix composites, titanium aluminides, and flat multilayer composites of said materials by direct powder rolling of blended powders followed by sintering. The resulting titanium alloy flat products have properties that meet or exceed the conventional ingot metallurgy alloys and are suitable for aerospace, automotive, sporting goods, and other applications. The process includes: (a) providing C.P.

Abstract: (a) The metal matrix composite is suitable for the manufacture of flat or shaped titanium aluminide, zirconium aluminide, or niobium aluminide articles and layered metal composites having improved mechanical properties such as lightweight plates and sheets for aircraft and automotive applications, thin cross-section vanes and airfoils, heat-sinking lightweight electronic substrates, bulletproof structures for vests, partition walls and doors, as well as sporting goods such as helmets, golf clubs, sole plates, crown plates, etc. The composite material consists of a metal (e.g., Ti, Zr, or Nb-based alloy) matrix at least partially intercalated with a three-dimensional skeletal metal aluminide structure, whereby ductility of the matrix metal is higher than that of the metal aluminide skeleton. The method for manufacturing includes the following steps: (a) providing an aluminum skeleton structure having open porosity of 50-95 vol.

Abstract: (a) The metal matrix composite is suitable for the manufacture of flat or shaped titanium aluminide, zirconium aluminide, or niobium aluminide articles and layered metal composites having improved mechanical properties such as lightweight plates and sheets for aircraft and automotive applications, thin cross-section vanes and airfoils, heat-sinking lightweight electronic substrates, bulletproof structures for vests, partition walls and doors, as well as sporting goods such as helmets, golf clubs, sole plates, crown plates, etc. The composite material consists of a metal (e.g., Ti, Zr, or Nb-based alloy) matrix at least partially intercalated with a three-dimensional skeletal metal aluminide structure, whereby ductility of the matrix metal is higher than that of the metal aluminide skeleton. The method for manufacturing includes the following steps: (a) providing an aluminum skeleton structure having open porosity of 50-95 vol.

Abstract: The method is suitable for the manufacture of flat or shaped titanium aluminide articles and layered metal matrix composites such as lightweight plates and sheets for aircraft and automotive applications, thin cross-section vanes and blades, composite electrodes, heat-sinking lightweight electronic substrates, bulletproof structures for vests, partition walls and doors, as well as for sporting goods such as helmets, golf clubs, sole plates, crown plates, etc.