Patent number: 6326066
Abstract: 1,4-disubstituted 2,6-difluorobenzene compound of formula I
wherein
R is an alkyl or alkenyl radical,
A1 and A2 are independently
(a) a trans-1,4-cyclohexylene radical in which a CH2 group may be replaced by -O- and/or -S,
(b) a 1,4-phenylene radical in which a CH group may be replaced by N,
(c) 1,4-cyclohexenylene, 1,4-bicyclo(2,2,2)octylene, piperidine-1,4-diyl, naphthalene-2,6-diyl, decahydronaphthalene-2,6-diyl or 1,2,3,4-tetrahydronaphthalene-2,6-diyl,
Z1 and Z2 are —CO—O—, —O—CO—, —CH2O—,—OCH2—, —CH2CH2—, —CH═CH—,—C≡C—or a single bond
m and n are 0, 1, 2 or 3,
(m+n) is 1, 2 or 3,
X is R or F, Cl, CF3, —OCF3, or —OCHF2, —OCF5, —CN or —NCS
with the provisos that at least one of the radicals A1 and A2 present in the molecule is
and at least one of Z1 or Z2 is —COO—,
are suitable as components of liquid-
Type:
Grant
Filed:
February 28, 2000
Date of Patent:
December 4, 2001
Assignee:
Merck Patent Gesellschaft mit Reschankter Haftung
Inventors:
Eike Poetsch, Volker Meyer, Volker Reiffenrath, Andreas Wachtler, Ulrich Finkenzeller, Hans Adolf Kurmeier, Reinhard Hittich, Bernhard Rieger, David Coates, Simon Greenfield, Robert William Clemitson
Patent number: 6200654
Abstract: 1,4-disubstituted 2,6-difluorobenzene compound of formula I
wherein
R is an alkyl or alkenyl radical,
A1 and A2, in each case independently of one another, are
(a) a trans-1,4-cyclohexylene radical in which a CH2 group may be replaced by —O— and/or —S,
(b) a 1,4-phenylene radical in which a CH group may be replaced by N,
(c) 1,4-cyclohexenylene, 1,4-bicyclo(2,2,2)octylene, piperidine-1,4-diyl, naphthalene-2,6-diyl, decahydronaphthalene-2,6-diyl or 1,2,3,4-tetrahydronaphthalene-2,6-diyl,
Z1 and Z2 are —CO—O—, —O—CO—, —CH2—O—, —OCH2—, —CH2CH2—, —CH═CH—, —C≡C— or a single bond
m and n are 0, 1, 2 or 3,
(m+n) is 1, 2 or 3,
X is R or F, Cl, CF3, —OCF3, or —OCHF2, —OCF5, —CN or —NCS
with the proviso that at least one of the radicals A1 and A2 present in the molecule is
are suitable as components of liquid-c
Type:
Grant
Filed:
August 25, 1997
Date of Patent:
March 13, 2001
Assignee:
Merck Patent Gesellschaft mit beschrankter Haftung
Inventors:
Eike Poetsch, Volker Meyer, Volker Reiffenrath, Andreas Wachtler, Ulrich Finkenzeller, Hans Adolf Kurmeier, Reinhard Hittich, Bernhard Rieger, David Coates, Simon Greenfield, Robert William Clemitson
Patent number: 5496499
Abstract: Biphenylylethanes of the formula I ##STR1## in which one of the radicals R.sup.1 and R.sup.2 is X and the other radical R.sup.1 or R.sup.2 is R--Y-- whereX is H, halogen, --CF.sub.3, --OCHF.sub.2, --OCF.sub.3, --CN, --NCS or --NO.sub.2,R is alkyl, fluoroalkyl, alkenyl or oxaalkyl andY is O, S, --CO--O--, --O--CO--, --O--CO--O--, a single bond or--in the case where m=1--alternatively trans-1,4-cyclohexylene or ##STR2## m is 1 or 2, Ph is in each case identical or different radicals selected from the group comprising 1,4-phenylene, 2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene and 3,5-difluoro-1,4-phenylene,L.sup.3 and L.sup.4 are each H, or one of these radicals is alternatively F,L.sup.1, L.sup.2and L.sup.5 are each H or F, with the proviso that in the case where X=CN or R.sup.1 =--NCS, Y is trans-1,4-cyclohexylene or ##STR3## and/or m=2 and/or one of the radicals L.sup.1, L.sup.2 and L.sup.
Type:
Grant
Filed:
January 12, 1994
Date of Patent:
March 5, 1996
Assignee:
Merck Patent Gesellschaft mit beschrankter Haftung
Inventors:
Eike Poetsch, Volker Meyer, Klaus P. Stahl, Volker Reiffenrath, Ulrich Finkenzeller, Ekkehard Bartmann, Reinhard Hittich, David Coates, Simon Greenfield, Graham Smith, Hans A. Kurmeier, Dieter Dorsch