Abstract: Described herein are compositions and methods for the storage and release of hydrogen gas using covalent organic frameworks (COFs). Advantageously, the compositions and methods described herein may be used for the facile and rapid release of hydrogen gas at near ambient temperatures. The described COFs allow for photoactivation, where the release of gas is initiated or the rate of release is increased with the COF is exposed to electromagnetic radiation, for example, UV light.

Abstract: Described herein are compositions and methods for the storage and release of hydrogen gas using covalent organic frameworks (COFs). Advantageously, the compositions and methods described herein may be used for the facile and rapid release of hydrogen gas at near ambient temperatures. The described COFs allow for photoactivation, where the release of gas is initiated or the rate of release is increased with the COF is exposed to electromagnetic radiation, for example, UV light.

Abstract: The present disclosure relates to a mixture that includes a mediator having a first redox potential, a non-liquid active material having a second redox potential that is less than the first redox potential, and a cation. In addition, the non-liquid active material has a first condition that includes a first oxidation state, where the cation is intercalated within the non-liquid active material, and the non-liquid active material has a second condition that includes a second oxidation state that is higher than the first oxidation state, where the non-liquid active material is substantially free of the cation. In addition, the mediator has a first condition that includes a third oxidation state and a second condition that includes a fourth oxidation state that is higher than the third oxidation state.

Abstract: The present disclosure relates to a mixture that includes a mediator having a first redox potential, a non-liquid active material having a second redox potential that is less than the first redox potential, and a cation. In addition, the non-liquid active material has a first condition that includes a first oxidation state, where the cation is intercalated within the non-liquid active material, and the non-liquid active material has a second condition that includes a second oxidation state that is higher than the first oxidation state, where the non-liquid active material is substantially free of the cation. In addition, the mediator has a first condition that includes a third oxidation state and a second condition that includes a fourth oxidation state that is higher than the third oxidation state.

Abstract: Hybrid radical energy storage devices, such as batteries or electrochemical devices, and methods of use and making are disclosed. Also described herein are electrodes and electrolytes useful in energy storage devices, for example, radical polymer cathode materials and electrolytes for use in organic radical batteries.

Abstract: Hybrid radical energy storage devices, such as batteries or electrochemical devices, and methods of use and making are disclosed. Also described herein are electrodes and electrolytes useful in energy storage devices, for example, radical polymer cathode materials and electrolytes for use in organic radical batteries.

Abstract: Hybrid radical energy storage devices, such as batteries or electrochemical devices, and methods of use and making are disclosed. Also described herein are electrodes and electrolytes useful in energy storage devices, for example, radical polymer cathode materials and electrolytes for use in organic radical batteries.

Abstract: Hybrid radical energy storage devices, such as batteries or electrochemical devices, and methods of use and making are disclosed. Also described herein are electrodes and electrolytes useful in energy storage devices, for example, radical polymer cathode materials and electrolytes for use in organic radical batteries.