Abstract: A continuous process for producing granular calcium hypochlorite particles comprises admixing lime and an aqueous liquid in a mixing zone to form a lime slurry. The lime slurry is fed into a crystallizing zone along with a calcium hypochlorite-containing liquid to produce a slurry of coarse dibasic calcium hypochlorite crystals and to elutriate a fines slurry from the crystallizing zone. The coarse dibasic calcium hypochlorite crystals are separated from a dibasic hypochlorite mother liquor and fed to a chlorinating zone. Reaction of the coarse dibasic calcium hypochlorite crystals with a chlorinating agent is conducted to produce a slurry of hemibasic calcium hypochlorite crystals. The slurry is fed to a separator to separate a hemibasic hypochlorite mother liquor from the hemibasic calcium hypochlorite crystals.

Abstract: A method and apparatus is disclosed for combustion of diverse materials, particularly combustible solids, liquids or gases, such as sewage sludge, refuse, coal, refinery sludge, tar sands, coal shale, coal tailings and spent foundry sand. A rotary combustion apparatus is employed which consists of a cylindrical drum, or other similar regularly shaped chamber, with a substantially horizontal axis of rotation including an ignition zone, a principal combustion zone, a falling temperature zone and a spent solids removal zone. The apparatus further includes solids transport chutes for forward and backward circulation of solids, arranged for the transfer of solids to or from one or more points. Feedstock may also be heated by recycled hot solids. The method and apparatus employs direct solids-to-gas contact established by lifting and cascading combustible solids through a hot gas stream.

Abstract: A method and apparatus is disclosed for combustion of diverse materials, particularly combustible solids, liquids or gases, such as sewage sludge, refuse, coal, refinery sludge, tar sands, coal shale, coal tailings and spent foundry sand. A rotary combustion apparatus is employed which consists of a cylindrical drum, or other similar regularly shaped chamber, with a substantially horizontal axis of rotation including an ignition zone, a principal combustion zone, a falling temperature zone and a spent solids removal zone. The apparatus further includes solids transport chutes for forward and backward circulation of solids, arranged for the transfer of solids to or from one or more points. Feedstock may also be heated by recycled hot solids. The method and apparatus employs direct solids-to-gas contact established by lifting and cascading combustible solids through a hot gas stream.

Abstract: A method and apparatus is disclosed for retorting particulate solid materials, particularly hydrocarbon-containing materials such as oil shale, oil sands, tar sands, coal shale, coal tailings, and the like, for the recovery of a volatile constituent such as oil or gas. A rotary retorting apparatus is employed which consists of a cylindrical drum, or other similar regularly shaped chamber, with a substantially horizontal axis of rotation and having multiple compartments for retorting and combustion and, optionally, spent solids cooling. The apparatus further includes solids transport chutes for forward and backward circulation of solids, arranged for the intercompartmental transfer of solids with the capability of additions at one or more points in each compartment. Employing the method and apparatus, particulate solids feedstock is heated by recycled spent solids material to remove the volatile constituent of the feedstock in the retort section.

Abstract: A continuous process for producing granular calcium hypochlorite particles comprises admixing lime and an aqueous liquid in a mixing zone to form a lime slurry. The lime slurry is fed into a crystallizing zone along with a calcium hypochlorite-containing liquid to produce a slurry of coarse dibasic calcium hypochlorite crystals and to elutriate a fines slurry from the crystallizing zone. The coarse dibasic calcium hypochlorite crystals are separated from a dibasic hypochlorite mother liquor and fed to a chlorinating zone. Reaction of the coarse dibasic calcium hypochlorite crystals with a chlorinating agent is conducted to produce a slurry of hemibasic calcium hypochlorite crystals. The slurry is fed to a separator to separate a hemibasic hypochlorite mother liquor from the hemibasic calcium hypochlorite crystals.

Abstract: A method and apparatus is disclosed for retorting particulate solid materials, particularly hydrocarbon-containing materials such as oil shale, oil sands, tar sands, coal shale, coal tailings, and the like, for the recovery of a volatile constituent such as oil or gas. A rotary retorting apparatus is employed which consists of a cylindrical drum, or other similar regularly shaped chamber, with a substantially horizontal axis of rotation and having multiple compartments for retorting and combustion and, optionally, spent solids cooling. The apparatus further includes solids transport chutes for forward and backward circulation of solids, arranged for the intercompartmental transfer of solids with the capability of additions at one or more points in each compartment. Employing the method and apparatus, particulate solids feedstock is heated by recycled spent solids material to remove the volatile constituent of the feedstock in the retort section.

Abstract: In a rotary apparatus and a process for the production of layered glass batch pellets there is provided a drying process and a dryer for final drying of the pellets prior to their being fed to a melting furnace.

Abstract: In a rotary apparatus for the production of layered glass batch pellets there is provided a dryer for final drying of the pellets prior to their being fed to a melting furnace.

Abstract: Layered glass batch pellets are produced in a continuous process which comprises the steps of:(a) maintaining in the pelletizing zone of a rotary apparatus a moving bed of recycle pellets,(b) feeding sand and particles of a calcium carbonate source into the pelletizing zone,(c) feeding a Na.sub.2 O source comprised of a solution of sodium hydroxide into the pelletizing zone, the recycle pellets being coated with a layer comprised of the solution of sodium hydroxide, the sand and the calcium carbonate source and forming layered pellets,(d) passing the layered pellets into a heated drying zone to form dried layered pellets, the dried layered pellets having a residual moisture content of from about 4 to about 12 percent by weight,(e) passing the dried layered pellets from the drying zone to a cycle zone,(f) recycling a portion of the dried layered pellets to the pelletizing zone as the recycle pellets, and(g) recovering a portion of the dried layered pellets from the recycle zone.

Abstract: Layered glass batch pellets are produced in a continuous process which comprises the steps of:(a) maintaining in the pelletizing zone of a rotary apparatus a moving bed of recycle pellets,(b) feeding sand and particles of a calcium carbonate source into the pelletizing zone,(c) feeding a Na.sub.2 O source comprised of a solution of sodium hydroxide into the pelletizing zone, the recycle pellets being coated with a layer comprised of the solution of sodium hydroxide, the sand and the calcium carbonate source and forming layered pellets,(d) passing the layered pellets into a heated drying zone to form dried layered pellets, the dried layered pellets having a residual moisture content of from about 4 to about 12 percent by weight,(e) passing the dried layered pellets from the drying zone to a recycle zone,(f) recycling a portion of the dried layered pellets to the pelletizing zone as the recycle pellets, and(g) recovering a portion of the dried layered pellets from the recycle zone.

Abstract: In a rotary apparatus and a process for the production of layered glass batch pellets there is provided a drying process and a dryer for final drying of the pellets prior to their being fed to a melting furnace. Relatively cool moist pellets are fed into a static bed-type dryer to form a uniformly distributed pellet bed while a heating and drying gas is directed into the dryer in such a manner that the gas flows countercurrent to the direction of travel of the pellets through the dryer to maintain a temperature differential between the gas and the surface of the solid pellets in the bed throughout the bed's entire height in the range of approximately 5.degree. F. to 120.degree. F. and, ideally, within approximately 50.degree. F.

Abstract: A process for the recovery of calcium chloride hydrates and calcium chlorate compounds comprises:(a) blending an effluent comprised of an aqueous solution of calcium chloride, calcium chlorate, and calcium hypochlorite and having a weight ratio of Ca(ClO.sub.3).sub.2 /CaCl.sub.2 of less than about 0.2 with a second mother liquor comprised of an aqueous solution of calcium chlorate and calcium chloride and having a weight ratio of Ca(ClO.sub.3).sub.2 /CaCl.sub.2 of greater than about 1.0 to form a blended solution;(b) feeding the blended solution to a first crystallizer to form a slurry of calcium chloride hydrate in a first mother liquor;(c) separating the crystals of calcium chloride hydrate from the first mother liquor, the first mother liquor having a weight ratio of Ca(ClO.sub.3).sub.2 /CaCl.sub.2 of at least about 1.

Abstract: Layered glass batch pellets are produced in a continuous process which comprises the steps of:(a) maintaining in the pelletizing zone of a rotary apparatus a moving bed of recycle pellets,(b) feeding sand and particles of a calcium oxide source into the pelletizing zone,(c) feeding a solution of sodium hydroxide into the pelletizing zone, the recycle pellets being coated with a layer comprised of the solution of sodium hydroxide, the sand and the calcium oxide source and forming layered pellets,(d) passing the layered pellets into a heated drying zone exposed to an atmosphere containing carbon dioxide gas,(e) lifting the layered pellets to the upper part of the drying zone and releasing the layered pellets to separately fall through the drying zone,(f) simultaneously absorbing carbon dioxide onto the layered pellets while evaporating and removing water from the falling layered pellets to form dried layered pellets, the dried layered pellets having a residual moisture content of less than 15 percent by weight,

Abstract: Rounded granular calcium hypochlorite comprised of a core of calcium hypochlorite encapsulated with a plurality of rounded layers of calcium hypochlorite, wherein the core of each particle generally has a diameter which ranges from about 200 to about 2,000 microns and the novel coated granules have a diameter ranging from about 400 to about 5,000 microns. Each layer is formed from an aqueous slurry of calcium hypochlorite which contains a high percentage of soluble inorganic salts as well as calcium hypochlorite. These soluble salts impart a high degree of cohesive bonding as each layer is formed and result in rounded granules of higher density and improved dust resistance.

Abstract: A coated, rounded, solid calcium hypochlorite granule is described which is comprised of granular calcium hypochlorite encapsulated with a plurality of layers of an inorganic salt other than calcium hypochlorite. The inorganic salt is admixed with sufficient alkaline material to form a coating which has a pH in dilute aqueous solution at ambient temperature of at least about nine or higher. The inorganic salt is selected from a group consisting of the chloride, chlorate, nitrate, bromide, bromate and sulfate of an alkali metal. The alkaline material is selected from the group consisting of calcium hydroxide, strontium hydroxide, barium hydroxide, magnesium hydroxide and mixtures thereof. The inorganic salt coating comprises from about 4 to about 45 percent by weight of the calcium hypochlorite granule. The coated, rounded, solid granule of this invention is highly stable and resists chemical decomposition and dusting during storage.

Abstract: A process is described in which granular calcium hypochlorite particles are encapsulated with a plurality of layers of an inorganic salt other than calcium hypochlorite. In this process granular calcium hypochlorite particles are placed in a moving bed and a portion of the moving bed is lifted to the upper part of a distributing zone and released to fall downwardly through the distributing zone to the moving bed. An aqueous medium of the inorganic salt is sprayed onto the falling particles at a temperature sufficiently high to simultaneously evaporate and remove water from the aqueous medium and to provide a coating of a plurality of layers of inorganic salt in solid form on each calcium hypochlorite particle.

Abstract: A process is described in which granular calcium hypochlorite particles are encapsulated with at least one layer of a hydrated low melting inorganic salt. In this process granular calcium hypochlorite particles are lifted from a moving bed to the upper part of a distribution zone and the lifted particles are released to fall downwardly through the upper portion to the moving bed. A molten hydrated low melting inorganic salt is sprayed onto the falling particles above the moving bed, and the coated particles are cooled to provide at least one solid outer layer of said low melting hydrated inorganic salt.

Abstract: Granular calcium hypochlorite particles having a core of calcium hypochlorite encapsulated in a plurality of layers of calcium hypochlorite are produced from an aqueous slurry of calcium hypochlorite by spraying a pumpable and sprayable slurry of calcium hypochlorite particles onto suspended particles of solid calcium hypochlorite above a moving bed of said particles. The solid particles coated with the slurry are heated to simultaneously evaporate and remove water from the slurry whereby said particles are coated with a layer of solid calcium hypochlorite.A portion of the moving bed of coated articles is removed from the spraying zone and further processed, if desired. In one embodiment the coated articles, with or without sizing, are dried to produce granular particles having the desired moisture content.

Abstract: A rotary dryer in which the rate of the bed transport is adjustable. The dryer shell is provided with at least one set of flights and a dam ring with the dam ring being spaced downstream of the flights to provide a flight-free area. Adjustable means are provided to transport material from the flight-free area over the dam ring to the downstream side thereof upon rotation of the shell to vary the amount of material retained upstream from the dam ring. In addition, means are provided to convey material from the flight-free area to a point adjacent the upstream end of the flights. Further, a cooling section is also included comprising a plurality of flights. Means for supplying co-current drying gas may be provided at the feed end of the dryer and means for supplying counter-current cooling gas may be provided adjacent the discharge end.

Abstract: A process is described in which granular calcium hypochlorite particles are encapsulated with at least one layer of a hydrated low melting inorgnaic salt. In this process granular calcium hypochlorite particles are lifted from a moving bed to the upper part of a distribution zone and the lifted particles are released to fall downwardly through the upper portion to the moving bed. A molten hydrated low melting inorganic salt is sprayed onto the falling particles above the moving bed, and the coated particles are cooled to provide at least one solid outer layer of said low melting hydrated inorganic salt.