Abstract: A silicon-based anode material, including a silicon-based core; and a shell layer arranged on the silicon-based core, the silicon-based core comprises SiOx and silicon microcrystals dispersed in the SiOx, where 0.9?x?1.3; and a distribution density of the silicon microcrystals gradually decreases along a direction from a surface of the silicon-based core to the center of the silicon-based core, the shell layer includes a carbon layer. The silicon-based anode material has high capacity and low volume expansion effect, and the battery capacity and cycle performance can be improved in the applications in non-aqueous electrolyte secondary batteries. A preparation method for a silicon-based anode material for lithium-ion batteries.

Abstract: A lithium-replenishing additive is provided. The lithium-replenishing additive includes a lithium-rich-material core and a shell layer disposed at the lithium-rich-material core. The lithium-rich-material core is made of a lithium-rich material with an average chemical formula of aNixMyO2 ·bLi2O, where 0.95?x?1, 0.01?y?0.05, 1?z?1.15, 0.8?a?1.1, 0.8?b?1.1, and the M includes one or more of copper (Cu), cobalt (Co), aluminum (Al), titanium (Ti), vanadium (V), zirconium (Zr), or iron (Fe). The shell layer includes a polymer layer. A preparing method of a lithium-replenishing additive and a lithium secondary battery are further provided.