Patents by Inventor Warren Francis Knoff

Warren Francis Knoff has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9790622
    Abstract: The present invention concerns methods for obtaining high-tenacity aramid yarn, wherein the yarn is made of a copolymer obtained from a mixture of monomers comprising 5-(6)-amino-2-(p-aminophenyl)benzimidazole, an aromatic para-diamine, and an aromatic para-diacid; the method comprising: a) spinning said copolymer from an inorganic acid solvent to produce the aramid yarn; b) washing said yarn with a basic aqueous solution for at least 5 seconds; and c) heating said yarn; wherein the yarn is heated in at least two process steps, characterized in that (i) in a first step the yarn is heated at a temperature of 200 to 360° C. at a tension of at least 0.2 cN/dtex, followed by (ii) a second step wherein the yarn is heated at a temperature of 370 to 500° C. at a tension of less than 1 cN/dtex. In some embodiments, the yarn has an effective polymer cation to sulfur content molar ratio of at least 0.3. In some embodiments, the yarn has a hydrolytic strength retention of the yarn is greater than 60%.
    Type: Grant
    Filed: September 30, 2016
    Date of Patent: October 17, 2017
    Assignee: E I DU PONT DE NEMOURS AND COMPANY
    Inventors: Warren Francis Knoff, Christopher William Newton
  • Publication number: 20170016145
    Abstract: The present invention concerns methods for obtaining high-tenacity aramid yarn, wherein the yarn is made of a copolymer obtained from a mixture of monomers comprising 5-(6)-amino-2-(p-aminophenyl)benzimidazole, an aromatic para-diamine, and an aromatic para-diacid; the method comprising: a) spinning said copolymer from an inorganic acid solvent to produce the aramid yarn; b) washing said yarn with a basic aqueous solution for at least 5 seconds; and c) heating said yarn; wherein the yarn is heated in at least two process steps, characterized in that (i) in a first step the yarn is heated at a temperature of 200 to 360° C. at a tension of at least 0.2 cN/dtex, followed by (ii) a second step wherein the yarn is heated at a temperature of 370 to 500° C. at a tension of less than 1 cN/dtex. In some embodiments, the yarn has an effective polymer cation to sulfur content molar ratio of at least 0.3.
    Type: Application
    Filed: September 30, 2016
    Publication date: January 19, 2017
    Inventors: Warren Francis Knoff, CHRISTOPHER WILLIAM NEWTON
  • Patent number: 9481946
    Abstract: The present invention concerns methods for obtaining high-tenacity aramid yarn, wherein the yarn is made of a copolymer obtained from a mixture of monomers comprising 5-(6)-amino-2-(p-aminophenyl)benzimidazole, an aromatic para-diamine, and an aromatic para-diacid. The method comprises: a) spinning said copolymer from an inorganic acid solvent to produce the aramid yarn; b) washing the yarn with a basic aqueous solution for at least 5 seconds; and c) heating the yarn; wherein the yarn is heated in at least two process steps, comprising (i) in a first step the yarn is heated at a temperature of 200 to 360° C. at a tension of at least 0.2 cN/dtex, followed by (ii) a second step wherein the yarn is heated at a temperature of 370 to 500° C. at a tension of less than 1 cN/dtex.
    Type: Grant
    Filed: January 13, 2012
    Date of Patent: November 1, 2016
    Assignee: E I DU PONT DE NEMOURS AND COMPANY
    Inventors: Warren Francis Knoff, Christopher William Newton
  • Patent number: 9434142
    Abstract: A method of making a composite sandwich panel comprises the steps of (i) making a core structure, (ii) making at least one facesheet, (iii) bonding at least one of the at least one facesheets to the core structure, wherein the growth of a carbon nanotube structure is achieved during at least one of steps (i) to (iii).
    Type: Grant
    Filed: January 25, 2013
    Date of Patent: September 6, 2016
    Assignee: E I DU PONT DE NEMOURS AND COMPANY
    Inventors: Mikhail R Levit, Llewellyn Bentley Richardson, III, Warren Francis Knoff, Dariusz Wlodzimierz Kawka
  • Patent number: 9365952
    Abstract: The present invention concerns yarns comprising copolymer derived from the copolymerization of para-phenylenediamine, 5(6)-amino-2-(p-aminophenyl)benzimidazole; and terephthaloyl dichloride wherein the ratio of moles of 5(6)-amino-2-(p-aminophenyl)benzimidazole to the moles of para-phenylenediamine is 30/70 to 85/15. The yarns have a sulfur content greater than 0.1%; and have an effective polymer cation to sulfur content molar ratio of at least 0.3. Additional aspects of the invention concern methods of producing such yarns.
    Type: Grant
    Filed: January 13, 2012
    Date of Patent: June 14, 2016
    Assignee: E I DU PONT DE NEMOURS AND COMPANY
    Inventors: Warren Francis Knoff, Christopher William Newton
  • Publication number: 20150367608
    Abstract: A multilayer laminate comprising in order, a polymeric film layer capable of withstanding a temperature of at least 200 C for at least 10 min, an adhesive layer having an areal weight of from 2 to 40 gsm capable of activation at a temperature of from 75 to 200 degrees C. and an inorganic refractory layer wherein the refractory layer comprises platelets in an amount at least 85% by weight with a dry areal weight of 15 to 50 gsm and has a residual moisture content of no greater than 10 percent by weight.
    Type: Application
    Filed: August 27, 2015
    Publication date: December 24, 2015
    Inventors: LLEWELLYN BENTLEY RICHARDSON, III, WARREN FRANCIS KNOFF, JIAN WANG
  • Publication number: 20150353184
    Abstract: A multilayer laminate for use as a flame barrier in an aircraft comprising (i) a polymeric film layer capable of withstanding a temperature of at least 200 C for at least 10 min, (ii) an adhesive layer having an areal weight of from 2 to 40 gsm capable of activation at a temperature of from 75 to 200 degrees C., (iii) an inorganic refractory layer, and (iv) aramid paper comprising from 50 to 90 weight percent of aramid fibers and from 10 to 50 weight percent of meta-aramid binder wherein the inorganic refractory layer of (iii) comprises platelets in an amount of at least 85% by weight with a dry areal weight of 15 to 50 gsm and a residual moisture content of no greater than 10 percent by weight.
    Type: Application
    Filed: May 6, 2015
    Publication date: December 10, 2015
    Inventors: LLEWELLYN BENTLEY RICHARDSON, III, WARREN FRANCIS KNOFF, JIAN WANG
  • Patent number: 8957183
    Abstract: The present invention concerns yarns comprising copolymer derived from the copolymerization of para-phenylenediamine, 5(6)-amino-2-(p-aminophenyl)benzimidazole; and terephthaloyl dichloride wherein the ratio of moles of 5(6)-amino-2-(p-aminophenyl)benzimidazole to the moles of para-phenylenediamine is 30/70 to 85/15; the yarn having a sulfur content greater than 0.1%; and the hydrolytic strength retention of the yarn is greater than 60%. The invention also concerns processes for making such yarns.
    Type: Grant
    Filed: January 13, 2012
    Date of Patent: February 17, 2015
    Assignee: E I du Pont de Nemours and Company
    Inventors: Warren Francis Knoff, Christopher William Newton
  • Publication number: 20140256204
    Abstract: Carbon nanotubes are coupled and aligned in a non-woven sheet as measured by failure strain by drawing the sheet with a coupling agent such as triphenylmethane and preferable a liquid diluent such as chlorosulfonic acid or sulfuric acid. The formed non-woven sheet has a full width at half maximum as determined by wide angle X-ray diffraction of not greater than 20°.
    Type: Application
    Filed: February 21, 2014
    Publication date: September 11, 2014
    Applicant: E I DU Pont De Nemours And Company
    Inventor: WARREN FRANCIS KNOFF
  • Publication number: 20130196175
    Abstract: A method of making a composite sandwich panel comprises the steps of (i) making a core structure, (ii) making at least one facesheet, (iii) bonding at least one of the at least one facesheets to the core structure, wherein the growth of a carbon nanotube structure is achieved during at least one of steps (i) to (iii).
    Type: Application
    Filed: January 25, 2013
    Publication date: August 1, 2013
    Applicant: E I DU PONT DE NEMOURS AND COMPANY
    Inventors: Mikhail R. LEVIT, Llewellyn Bentley RICHARDSON, III, Warren Francis KNOFF, Dariusz Wlodzimierz KAWKA
  • Publication number: 20130075950
    Abstract: The present invention concerns methods for obtaining high-tenacity aramid yarn, wherein the yarn is made of a copolymer obtained from a mixture of monomers comprising 5-(6)-amino-2-(p-aminophenyl)benzimidazole, an aromatic para-diamine, and an aromatic para-diacid. The method comprises: a) spinning said copolymer from an inorganic acid solvent to produce the aramid yarn; b) washing the yarn with a basic aqueous solution for at least 5 seconds; and c) heating the yarn; wherein the yarn is heated in at least two process steps, comprising (i) in a first step the yarn is heated at a temperature of 200 to 360° C. at a tension of at least 0.2 cN/dtex, followed by (ii) a second step wherein the yarn is heated at a temperature of 370 to 500° C. at a tension of less than 1 cN/dtex.
    Type: Application
    Filed: January 13, 2012
    Publication date: March 28, 2013
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventors: WARREN FRANCIS KNOFF, CHRISTOPHER WILLIAM NEWTON
  • Patent number: 8387748
    Abstract: This invention is directed to a composite laminate comprising in order (a) a flame retardant polymeric moisture barrier (b) an inorganic platelet layer and (c) a flame retardant thermoplastic film layer The invention is also directed to a thermal insulation and acoustic blanket comprising a core of fibrous material or foam surrounded by the above composite laminate wherein the thermoplastic film layer of the composite laminate contacts and encapsulates the core.
    Type: Grant
    Filed: August 28, 2012
    Date of Patent: March 5, 2013
    Assignee: E I du Pont de Nemours and Company
    Inventors: Llewellyn Bentley Richardson, III, Jian Wang, Warren Francis Knoff
  • Publication number: 20130014329
    Abstract: The present invention concerns yarns comprising copolymer derived from the copolymerization of para-phenylenediamine, 5(6)-amino-2-(p-aminophenyl)benzimidazole; and terephthaloyl dichloride wherein the ratio of moles of 5(6)-amino-2-(p-aminophenyl)benzimidazole to the moles of para-phenylenediamine is 30/70 to 85/15. The yarns have a sulfur content greater than 0.1%; and have an effective polymer cation to sulfur content molar ratio of at least 0.3. Additional aspects of the invention concern methods of producing such yarns.
    Type: Application
    Filed: January 13, 2012
    Publication date: January 17, 2013
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventors: WARREN FRANCIS KNOFF, Christopher William Newton
  • Publication number: 20130018148
    Abstract: The present invention concerns yarns comprising copolymer derived from the copolymerization of para-phenylenediamine, 5(6)-amino-2-(p-aminophenyl)benzimidazole; and terephthaloyl dichloride wherein the ratio of moles of 5(6)-amino-2-(p-aminophenyl)benzimidazole to the moles of para-phenylenediamine is 30/70 to 85/15; the yarn having a sulfur content greater than 0.1%; and the hydrolytic strength retention of the yarn is greater than 60%. The invention also concerns processes for making such yarns.
    Type: Application
    Filed: January 13, 2012
    Publication date: January 17, 2013
    Applicant: E. I . DU PONT DE NEMOURS AND COMPANY
    Inventors: WARREN FRANCIS KNOFF, CHRISTOPHER WILLIAM NEWTON
  • Publication number: 20120321868
    Abstract: This invention is directed to a composite laminate comprising in order (a) a flame retardant polymeric moisture barrier (b) an inorganic platelet layer and (c) a flame retardant thermoplastic film layer The invention is also directed to a thermal insulation and acoustic blanket comprising a core of fibrous material or foam surrounded by the above composite laminate wherein the thermoplastic film layer of the composite laminate contacts and encapsulates the core.
    Type: Application
    Filed: August 28, 2012
    Publication date: December 20, 2012
    Applicant: E I Du Pont De Nemours and Company
    Inventors: Llewellyn Bentley Richardson, III, Jian Wang, Warren Francis Knoff
  • Patent number: 8292027
    Abstract: This invention is directed to a composite laminate comprising in order (a) a flame retardant polymeric moisture barrier (b) an inorganic platelet layer and (c) a flame retardant thermoplastic film layer The invention is also directed to a thermal insulation and acoustic blanket comprising a core of fibrous material or foam surrounded by the above composite laminate wherein the thermoplastic film layer of the composite laminate contacts and encapsulates the core.
    Type: Grant
    Filed: April 14, 2010
    Date of Patent: October 23, 2012
    Assignee: E I du Pont de Nemours and Company
    Inventors: Llewellyn Bentley Richardson, III, Warren Francis Knoff, Jian Wang
  • Publication number: 20110094826
    Abstract: This invention is directed to a composite laminate comprising in order (a) a flame retardant polymeric moisture barrier (b) an inorganic platelet layer and (c) a flame retardant thermoplastic film layer The invention is also directed to a thermal insulation and acoustic blanket comprising a core of fibrous material or foam surrounded by the above composite laminate wherein the thermoplastic film layer of the composite laminate contacts and encapsulates the core.
    Type: Application
    Filed: April 14, 2010
    Publication date: April 28, 2011
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventors: Llewellyn Bentley Richardson, III, Warren Francis Knoff, Jian Wang
  • Publication number: 20090158683
    Abstract: A multiple sheet building wrap for wrapping the structural components of a building in order to protect the underlying structural components and optional building sheathing from moisture is provided. The building wrap is particularly useful under facades such as wet applied stucco or engineered stone, demonstrating good drainage of liquid water and moisture vapor permeability. The building wrap is a composite of a water resistive barrier, a three-dimensional mesh layer and a porous intervening layer which acts to filter the stucco as it is applied. An exterior wall construction incorporating such building wrap is also provided.
    Type: Application
    Filed: December 20, 2007
    Publication date: June 25, 2009
    Inventors: Theresa Ann Weston, Barbara Klimowicz O'Rourke, Mieczyslaw (Michel) Stachnik, Warren Francis Knoff, Wazir Nobbee, Kimdolyn Boone
  • Patent number: RE46658
    Abstract: This invention is directed to a composite laminate comprising in order (a) a flame retardant polymeric moisture barrier (b) an inorganic platelet layer and (c) a flame retardant thermoplastic film layer The invention is also directed to a thermal insulation and acoustic blanket comprising a core of fibrous material or foam surrounded by the above composite laminate wherein the thermoplastic film layer of the composite laminate contacts and encapsulates the core.
    Type: Grant
    Filed: October 15, 2014
    Date of Patent: January 2, 2018
    Assignee: E I DU PONT DE NEMOURS AND COMPANY
    Inventors: Llewellyn Bentley Richardson, III, Warren Francis Knoff, Jian Wang
  • Patent number: RE46859
    Abstract: This invention is directed to a composite laminate comprising in order (a) a flame retardant polymeric moisture barrier (b) an inorganic platelet layer and (c) a flame retardant thermoplastic film layer The invention is also directed to a thermal insulation and acoustic blanket comprising a core of fibrous material or foam surrounded by the above composite laminate wherein the thermoplastic film layer of the composite laminate contacts and encapsulates the core.
    Type: Grant
    Filed: October 15, 2014
    Date of Patent: May 22, 2018
    Assignee: E I DU PONT DE NEMOURS AND COMPANY
    Inventors: Llewellyn Bentley Richardson, III, Warren Francis Knoff, Jian Wang