Patents by Inventor Warren Thaler

Warren Thaler has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5478463
    Abstract: A method, composition and filter for reducing the presence of sludge or varnish precursors in a lubricating oil circulating within an internal combustion engine. The lubricating oil containing sludge or varnish precursors is contacted with discrete particles of an oil insoluble, oil wettable compound having an antioxidant functional group and/or a dispersant functional group, which are capable of complexing with sludge or varnish precursors. Preferably the compounds comprises a crosslinked amine having ethylene amine functionality. The starting polyethylene amines have a number average molecular weight in the range of about 100 to about 60,000, preferably 200 to 250 and are crosslinked with a silicon oxide, silane, silicate, epoxide, quinone, or phenol-formaldehyde crosslinking agent. The particles are encaged within a one or two stage oil filter together with filtering media such as chemically active filter media, physically active filter media and inactive filter media.
    Type: Grant
    Filed: July 28, 1994
    Date of Patent: December 26, 1995
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Darrell W. Brownawell, Warren A. Thaler, Cruise K. Jones, Jacob Emert, Abhimanyu O. Patil
  • Patent number: 5435821
    Abstract: A vegetation enhancement composite including a vegetation enhancement agent consisting of a first member selected from the group consisting of at least one macronutrient, micronutrient, nitrogen fertilizer including an inhibitor of nitrification activity, slow release fertilizer, and mixtures of such members and a pesticide; and at least one first controlled release film including a sulfonated polymer coating at least a portion of a surface of the vegetation enhancement agent.
    Type: Grant
    Filed: December 31, 1990
    Date of Patent: July 25, 1995
    Assignee: Exxon Research & Engineering Co.
    Inventors: Ilan Duvdevani, Evelyn N. Drake, Warren A. Thaler, Pacifico V. Manalastas
  • Patent number: 5393441
    Abstract: Briefly stated, the present invention comprises novel compounds useful as two-cycle oil additives obtained by reacting an alkyl acrylamide with a compound selected from the group consisting of polyalkylenepolyamines, polyalkylenepolyamines functionalized with polyalkyl acid anhydrides and polyalkylenepolyamines and a polyalkyl acid anhydride.
    Type: Grant
    Filed: November 23, 1993
    Date of Patent: February 28, 1995
    Assignee: Exxon Research and Engineering Company
    Inventors: Warren A. Thaler, Stephen Zushma, Richard H. Schlosberg
  • Patent number: 5256181
    Abstract: A composite comprising a urea substrate and ionically and covalently crosslinked, neutralized, sulfonated EPDM elastomeric coating encapsulating the urea.
    Type: Grant
    Filed: March 28, 1991
    Date of Patent: October 26, 1993
    Assignee: Exxon Research and Engineering Company
    Inventors: Pacifico V. Manalastas, Evelyn N. Drake, Warren A. Thaler, Edward N. Kresge, Chester W. Elspass, Albert J. Geiger, Vijay Swarup
  • Patent number: 5190797
    Abstract: The present invention relates to a process for the encapsulation of a solid substrate with a neutralized sulfonated polymer, which comprises the steps of: (a) forming a solution of a non-conjugated, diene polymer in a solvent selected from the group consisting of aliphatic, aromatic hydrocarbons and mixtures thereof; (b) contacting the solution of the unsaturated polymer with a sulfonating agent at a sufficient temperature and for a sufficient period of time to form a solution of a sulfonated polymer containing free acid; (c) forming a solution of a base selected from the group consisting of alkali metal hydroxides and mixtures thereof in a mixtrue of an aliphatic alcohol and a hydrocarbon, the hydrocarbon being selected from the group consisting of aliphatic and aromatic hydrocarbons and mixtures thereof; (d) adding the solution of base to the solution of sulfonated polymer in an amount sufficient to neutralize the polymer and the free acid, thereby forming a coating solution; (e) contacting the solid substr
    Type: Grant
    Filed: June 24, 1991
    Date of Patent: March 2, 1993
    Assignee: Exxon Research and Engineering Company
    Inventors: Warren A. Thaler, Cruise K. Jones, Evelyn N. Drake, Pacifico V. Manalastas, Edward N. Kresge
  • Patent number: 5188654
    Abstract: A composite comprising a substrate and a polymeric coating adhered to at least one surface of said substrate, said polymer coating having a thickness of about 1 to about 100 micrometers, wherein said polymer coating comprises an ionically and covalently crosslinked neutralized carboxylated polymer having a carboxylate content of about 5 to about 300 meq. per 100 grams of said ionically and covalently crosslinked neutralized carboxylated polymer.
    Type: Grant
    Filed: March 28, 1991
    Date of Patent: February 23, 1993
    Assignee: Exxon Research and Engineering Company
    Inventors: Pacifico V. Manalastas, Evelyn N. Drake, Warren A. Thaler, Edward N. Kresge, Chester W. Elspass, Albert J. Geiger, Vijay Swarup
  • Patent number: 5187011
    Abstract: An encapsulated breaker chemical composition used in an oil or gas stimulation operation which comprises: a breaker chemical; and a pinhole free coating of an ionically and covalently crosslinked neutralized sulfonated elastomeric polymer of about 2 to about 80 microns thick deposited onto the surface of the breaker chemical, wherein said polymer encapsulates the breaker chemical, wherein the polymer is permeable to the breaker chemical and the polymer is non-reactive to the breaker chemical.
    Type: Grant
    Filed: January 9, 1992
    Date of Patent: February 16, 1993
    Assignee: Exxon Research and Engineering Company
    Inventors: Pacifico V. Manalastas, Evelyn N. Drake, Edward N. Kresge, Warren A. Thaler, Lee A. McDougall, John C. Newlove, Vijay Swarup, Albert J. Geiger
  • Patent number: 5164101
    Abstract: Piston deposits resulting from neutralizing combustion acids present in the lubricating oil circulating within the lubrication system of an internal combustion engine are reduced or eliminated by first cntacting the acids with a soluble weak base in the piston ring zone of the engine to form soluble neutral salts containing the weak base and the combustion acids. Thereafter, the neutral salts are contacted with a heterogenous strong base immobilized within the lubrication system but outside of the piston ring zone. The strong base displaces the weak base from the neutral salts, returning the weak base to the oil for recirculation to the piston ring zone for further use. The remaining strong base/combustion adic salts are immobilized as deposits with the strong base rather than on the piston. In a preferred embodiment, trioctadecyl amine is the weak base and magnesium oxide is the strong base.
    Type: Grant
    Filed: March 5, 1991
    Date of Patent: November 17, 1992
    Assignee: Exxon Research and Engineering Co.
    Inventors: Darrell W. Brownawell, Warren A. Thaler, Eric Bannister, Paul K. Ladwig
  • Patent number: 5156758
    Abstract: A terpolymer having the formula: ##STR1## wherein n=0 to 12; x is about 15 to about 75 mole percent; y is about 25 to about 85 mole percent; z is about 0.1 to about 10 mole percent; R.sub.1 and R.sub.3 equal to H, C.sub.1 -C.sub.10 alkyl, alkyl amino, alkylpolyamino, alkyl amino ether, alkyl amino alcohol groups and R.sub.2 is an alkyl group having about 1 to about 8 carbon atoms.
    Type: Grant
    Filed: December 4, 1990
    Date of Patent: October 20, 1992
    Assignee: Exxon Research and Engineering Company
    Inventors: Warren A. Thaler, Joseph Wegensommer, Darrell W. Brownawell, Donald N. Schulz, John B. Gardiner
  • Patent number: 5110486
    Abstract: An encapsulated breaker chemical composition used in an oil or gas stimulation operation which comprises: a breaker chemical; and a pinhole free coating of an ionically and covalently crosslinked neutralized sulfonated elastomeric polyer of about 2 to about 80 microns thick deposited onto the surface of the breaker chemical, wherein said polymer encapsulates the breaker chemical, wherein the polymer is permeable to the breaker chemical and the polymer is non-reactive to the breaker chemical.
    Type: Grant
    Filed: March 28, 1991
    Date of Patent: May 5, 1992
    Assignee: Exxon Research and Engineering Company
    Inventors: Pacifico V. Manalastas, Evelyn N. Drake, Edward N. Kresge, Warren A. Thaler, Lee A. McDougall, John C. Newlove, Vijay Swarup, Albert J. Geiger
  • Patent number: 5093003
    Abstract: A new copolymer composition comprising the soft segment of an aliphatic polyester and the hard segment of a highly halogenated polyurethane containing from 3 to 36 halogen atoms is disclosed. The new halogenated polyurethane copolymer membrane has high thermal stability, and good selectivity and permeability for separation of an aromatic/saturate mixture.
    Type: Grant
    Filed: March 25, 1991
    Date of Patent: March 3, 1992
    Assignee: Exxon Research and Engineering Company
    Inventors: W. S. Winston Ho, Guido Sartori, Warren A. Thaler, Bruce H. Ballinger, David C. Dalrymple, Robert P. Mastondrea
  • Patent number: 5068044
    Abstract: Piston deposits resulting from neutralizing combustion acids present in the lubricating oil circulating within the lubrication system of an internal combustion engine are reduced or eliminated by first contacting the acids with a soluble weak base in the piston ring zone of the engine to form soluble neutral salts containing the weak base and the combustion acids. Thereafter, the neutral salts are contacted with a heterogeneous strong base immobilized within the lubrication system but outside of the piston ring zone. The strong base displaces the weak base from the neutral salts, returning the weak base to the oil for recirculation to the piston ring zone for further use. The remaining strong base/combustion acid salts are immobilized as deposits with the strong base rather than on the piston. In a preferred embodiment, trioctadecyl amine is the weak base and zinc oxide is the strong base. In a particularly preferred embodiment, the strong base is incorporated on a substrate, preferably a cement binder.
    Type: Grant
    Filed: March 5, 1990
    Date of Patent: November 26, 1991
    Assignee: Exxon Research & Engineering Company
    Inventors: Darrell W. Brownawell, Warren A. Thaler, Eric Bannister, Paul K. Ladwig
  • Patent number: 5051296
    Abstract: This invention relates to emulsion type adhesive compositions which include a metal neutralized copolymer of a conjugated diene and an ethoxylated alkylamine salt of a styrene sulfonate, wherein the sulfonated copolymer has about 5 to about 125 meg. of sulfonate groups per 100 grams of the sulfonated copolymer, and about 25 to about 200 parts by weight of a hydrocarbon resin of a petroleum or coal tar distillate, having about 5 to 6 carbon atoms, the hydrocarbon resin being composed of aliphatic dienes and monoolefins per 100 parts by weight of the neutralized sulfonated copolymer.
    Type: Grant
    Filed: September 27, 1990
    Date of Patent: September 24, 1991
    Assignee: Exxon Research and Engineering Company
    Inventors: Pawan K. Agarwal, Warren A. Thaler
  • Patent number: 5051461
    Abstract: This invention relates to emulsion type adhesive compositions which include a metal neutralized copolymer of a conjugated diene and an ethoxylated alkylamine salt of a styrene sulfonate, wherein the sulfonated copolymer has about 5 to about 125 meq. so sulfonate groups per 100 grams of the sulfonated copolymer, and less than about 300 parts by weight of a hydrocarbon resin of a petroleum or coal tar distillate, having about 5 to 6 carbon atoms, the hydrocarbon resin being composed of aliphatic dienes and monoolefins per 100 parts by weight of the neutralized sulfonated copolymer.
    Type: Grant
    Filed: September 27, 1990
    Date of Patent: September 24, 1991
    Assignee: Exxon Research and Engineering Company
    Inventors: Pawan K. Agarwal, Warren A. Thaler
  • Patent number: 5042617
    Abstract: Sludge can be effectively removed from a lubricating oil by contacting the oil with a dispersant functional group immobilized on a substrate. This results in improved engine cleanliness and control of viscosity increases.
    Type: Grant
    Filed: September 7, 1989
    Date of Patent: August 27, 1991
    Assignee: Exxon Research & Engineering Company
    Inventors: Darrell W. Brownawell, Warren Thaler
  • Patent number: 5028685
    Abstract: A new copolymer composition comprising the soft segment of an aliphatic polyester and the hard segment of a highly halogenated polyurethane containing from 3 to 36 halogen atoms is disclosed. The new halogenated polyurethane copolymer membrane has high thermal stability, and good selectivity and permeability for separation of an aromatic/saturate mixture.
    Type: Grant
    Filed: October 16, 1989
    Date of Patent: July 2, 1991
    Assignee: Exxon Research & Engineering Company
    Inventors: W. S. Winston Ho, Guido Sartori, Warren A. Thaler, Bruce H. Ballinger, David C. Dalrymple, Robert P. Mastondrea
  • Patent number: 5023005
    Abstract: A sulfone adduct which comprises the reaction product of: ##STR1## and an unsaturated hydrocarbon polymer wherein X is an alkyl group selected from the group consisting of C.sub.n H.sub.2n +1, wherein n=1 to 18; X is an aryl group selected from the group consisting of C.sub.m H.sub.m-1 wherein m=6 and C.sub.m H.sub.m-2 Z wherein m=6 and Z is selected from the group consisting of OR', R", COOR'", NO.sub.2, Cl, Br, F and I where R', R" and R'" having about 1 to about 18 carbon atoms; wherein said unsaturated hydrocarbon polymer is selected from the group consisting of ethylene propylene terpolymers, ethylene diene copolymers, propylene diene copolymers, polyisoprene, butyl rubber, polybutadiene and styrenebutadiene, and styrene-isoprene random and block copolymers, polypropylenes and polyisobutylenes.
    Type: Grant
    Filed: March 1, 1990
    Date of Patent: June 11, 1991
    Assignee: Exxon Research & Engineering Company
    Inventors: Warren A. Thaler, Stanley J. Brois, Henry K. Hall
  • Patent number: 5006147
    Abstract: An encapsulated water soluble fertilizer which comprises a polymeric film of about 2 to about 100 micrometers coated on a surface of said fertilizer, said polymeric film comprising a sulfonated polymer having about 10 to about 200 meq of sulfonate groups per 100 grams of said sulfonated polymer, said sulfonate groups being neutralized with a polycaprolactone polymer being characterized by the formula ##STR1## wherein R.sub.1 or R.sub.2 is an alkyl, cycloalkyl or aryl group; R.sub.3, R.sub.4 and R.sub.5 are a hydrogen or alkyl, cycloalkyl, or aryl groups; m equals 1 to 20 and n equals 1 to 500.
    Type: Grant
    Filed: July 17, 1989
    Date of Patent: April 9, 1991
    Assignee: Exxon Research and Engineering Company
    Inventors: Warren A. Thaler, Pacifico V. Manalastas, Evelyn N. Drake, Robert D. Lundberg
  • Patent number: 4997906
    Abstract: A crosslinked copolymer composition is derived from an aliphatic polyester, a dianhydride and a diisocyanate. The copolymer membrane has high thermal stability and good aromatic/saturate selectivity and permeability.
    Type: Grant
    Filed: April 3, 1990
    Date of Patent: March 5, 1991
    Assignee: Exxon Research & Engineering Company
    Inventors: Warren A. Thaler, W. S. W. Ho, Guido Sartori
  • Patent number: 4997470
    Abstract: An encapsulated water soluble fertilizer which comprises a polymeric film of about 2 to about 100 micrometers coated on a surface of said fertilizer, said polymeric film comprising a sulfonated polymer having about 10 to about 200 meq of sulfonate groups per 100 grams of said sulfonated polymer, said sulfonate groups being neutralized with a polycaprolactone polymer being characterized by the formula ##STR1## wherein R.sub.1 and R.sub.2 is an alkyl, cycloalkyl or aryl group; R.sub.3, R.sub.4 and R.sub.5 are a hydrogen or alkyl, cycloalkyl, or aryl groups; m equals 1 to 20 and n equals 1 to 500.
    Type: Grant
    Filed: July 17, 1989
    Date of Patent: March 5, 1991
    Assignee: Exxon Research & Engineering Company
    Inventors: Warren A. Thaler, Pacifico V. Manalastas, Evelyn N. Drake, Robert D. Lundberg