Patents by Inventor Wataro Koike

Wataro Koike has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4342859
    Abstract: Bis(aminophenylthioalkyl)terephthalate having the formula ##STR1## wherein R represents a C.sub.1 -C.sub.3 alkyl group. The compounds are useful as hardeners for a polyurethane elastomer.
    Type: Grant
    Filed: May 27, 1980
    Date of Patent: August 3, 1982
    Assignee: Ihara Chemical Industry Co., Ltd.
    Inventors: Takao Harada, Hideaki Ohashi, Wataro Koike, Chihiro Yazawa, Kazuko Nanjo
  • Patent number: 4327204
    Abstract: A polyurethane elastomer is produced by mixing a hardener composition containing a polyamine, a long chain polyol having an average molecular weight of 300 to 4,000 and a catalyst with an isocyanate composition comprises a prepolymer having terminal isocyanate group and an average molecular weight of 500 to 5,000 and an organic diisocyanate monomer with or without a triisocyanate monomer and a ratio of isocyanate groups of said prepolymer to amino groups of said polyamine is in a range of 0.6:1 to 1.5:1 and a ratio of a total of isocyanate groups in said isocyanate composition to a sum of amino groups of said polyamine and hydroxyl group of said long chain polyol is in a range of 0.8:1 to 1.4:1.
    Type: Grant
    Filed: March 18, 1980
    Date of Patent: April 27, 1982
    Assignee: Ihara Chemical Industry Co., Ltd.
    Inventors: Yoshijiro Oyaizu, Wataro Koike, Chihiro Yazawa
  • Patent number: 4267317
    Abstract: A phenoxyalkene derivative having the formula ##STR1## wherein R represents a hydrogen atom, ##STR2## and Y and Z are the same or different and respectively represent a hydrogen atom, trifluoromethyl group, a halogen atom, a lower alkyl group, nitro group or cyano group; R.sub.1 represents a hydrogen atom or a lower alkyl group and R.sub.2 represents carboxyl, hydroxymethyl, allyloxycarbonyl, a lower alkoxycarbonyl, a lower haloalkoxycarbonyl, a S-lower alkylthiocarbonyl, carbamoyl, a N-lower alkylcarbamoyl or a N-phenylcarbamoyl group is produced by reacting a phenol compound having the formula ##STR3## with a dihalogen compound having the formula ##STR4## wherein R, R.sub.1 and R.sub.2 are defined above and X.sub.1 represents a halogen atom and X.sub.2 and X.sub.
    Type: Grant
    Filed: October 12, 1979
    Date of Patent: May 12, 1981
    Assignee: Ihara Chemical Industry Co., Ltd.
    Inventors: Wataro Koike, Tadashi Sasuga, Chihiro Yazawa
  • Patent number: 4254262
    Abstract: A phenoxycarboxylic acid derivative having the formula ##STR1## wherein R represents ##STR2## and X.sub.1 represents a hydrogen atom, a halogen atom, a lower alkyl group, trifluoromethyl group, nitro group or cyano group and X.sub.2 represents a hydrogen atom, a halogen atom, a lower alkyl group, nitro group or cyano group, R' represents ##STR3## and R.sub.1 and R.sub.2 are the same and different and respectively represent hydrogen atom or a lower alkyl group, is produced by reacting a phenol compound having the formula ##STR4## with a halogen compound havingX--R'wherein X represents a halogen atom in the presence of a base. The reaction is carried out in the presence of a quarternary ammonium salt or a quaternary phosphonium salt in a nonpolar solvent.
    Type: Grant
    Filed: October 12, 1979
    Date of Patent: March 3, 1981
    Assignee: Ihara Chemical Industry Co., Ltd.
    Inventors: Wataro Koike, Tadashi Sasuga, Chihiro Yazawa
  • Patent number: 4246425
    Abstract: 4-Chloro-3,5-diaminophenyl acetates having the formula ##STR1## wherein R represents an alkyl group are useful as curing agent for polyurethane elastomer and intermediates for pharmaceutical and agrochemical compounds and are produced by simultaneously nitrating hydrolyzing 4-chlorobenzylcyanide and esterifying the resulting 4-chloro-3,5-dinitrophenyl acetic acid and then reducing the resulting ester.
    Type: Grant
    Filed: March 8, 1979
    Date of Patent: January 20, 1981
    Assignee: Ihara Chemical Industry Co., Limited
    Inventors: Wataro Koike, Masami Takayama, Hideaki Ohashi, Chihiro Yazawa
  • Patent number: 4246392
    Abstract: A method for the preparation of polyurethane elastomers in which polyethyleneglycol-bis(4-aminobenzoate) is used as the curing agent to be admixed with the polyurethane formulations. This curing agent imparts considerably extended pot life to the ready-prepared polyurethane composition to be cured by heating into an elastomer having improved properties.
    Type: Grant
    Filed: October 11, 1978
    Date of Patent: January 20, 1981
    Assignee: Ihara Chemical Industry Co., Ltd.
    Inventors: Wataro Koike, Masami Takayama, Hideaki Ohashi, Chihiro Yazawa
  • Patent number: 4211723
    Abstract: Chlorosulfonylbenzoylchloride having the formula ##STR1## wherein X is hydrogen, halogen or nitro is prepared by reacting phosgene with an aromatic sulfocarboxylic acid having the formula ##STR2## or an alkali metal salt or alkaline earth metal salt thereof in the presence of dimethylformamide.
    Type: Grant
    Filed: June 20, 1978
    Date of Patent: July 8, 1980
    Assignee: Ihara Chemical Industry Co., Ltd.
    Inventors: Wataro Koike, Takahiro Kimoto, Sadayoshi Matsui
  • Patent number: 4195037
    Abstract: 4-Alkoxy-3,5-diamino-.alpha.,.alpha.,.alpha.-trifluoromethylbenzene having the formula ##STR1## wherein R represents an alkyl group.
    Type: Grant
    Filed: October 4, 1978
    Date of Patent: March 25, 1980
    Assignee: Ihara Chemical Industry Co., Ltd.
    Inventors: Takao Harada, Nobuhide Wada, Hideaki Ohashi, Wataro Koike, Chihiro Yazawa
  • Patent number: 4097426
    Abstract: A curing agent for polyurethane which has a melting point at most 110.degree. C and comprises a mixture of at least two compounds of the general formula: ##STR1## Wherein n is zero or a positive integer. This curing agent has a low solidifying point and good solubility in solvents and thus is excellent in workability. This curing agent is used for the production of polyurethane highly stabilized in quality.
    Type: Grant
    Filed: October 26, 1976
    Date of Patent: June 27, 1978
    Assignee: Ihara Chemical Kogyo Kabushiki Kaisha
    Inventors: Wataro Koike, Masami Takayama, Hideaki Ohashi, Sadayoshi Matsui
  • Patent number: 4076721
    Abstract: An o-sulfobenzimide having the formula: ##STR1## is prepared by reacting phosgene with a methylbenzoate-o-sulfonate having the formula: ##STR2## WHEREIN M represents potassium or calcium, n is 1 when M is K and n is 2 when M is Ca, in an inert organic solvent in the presence of dimethylformamide; and then reacting ammonia with the reaction product.
    Type: Grant
    Filed: April 15, 1976
    Date of Patent: February 28, 1978
    Assignee: Ihara Chemical Industry Co., Ltd.
    Inventors: Wataro Koike, Takahiro Kimoto, Sadayoshi Matsui
  • Patent number: 4057555
    Abstract: 1,2-Benzoisothiazole-3-on-1, 1-dioxide having the formula ##STR1## wherein X represents hydrogen, halogen, nitro, lower alkyl or lower alkoxy and Y represents hydrogen, halogen, lower alkyl, or lower alkoxy is prepared by reacting phosgene with an o-sulfobenzoic acid compound having the formula: ##STR2## or an alkali metal salt or alkaline earth metal salt thereof in the presence of dimethylformamide, thereby producing a mixture of a dichlorotolylsultone and a chlorosulfonylbenzoylchloride; (b) reacting the reaction products of step (a) with an alcohol of the formula ROH wherein R represents a lower alkyl group; and then (c) reacting the product of step (b) with ammonia.
    Type: Grant
    Filed: April 15, 1976
    Date of Patent: November 8, 1977
    Assignee: Ihara Chemical Industry Co., Ltd.
    Inventors: Wataro Koike, Takahiro Kimoto, Sadayoshi Matsui