Abstract: Disclosed is a process for the preparation of di-n-butyl terephthalate by the esterification of terephthalic acid with n-butanol in the presence of a strong acid while employing a fractionating column.

Abstract: Mixtures of terephthalate diesters having lowered freezing points and methods of making the terephthalic acid diesters. The method includes contacting a first alcohol, a second different alcohol and dimethyl terephthalate in the presence of a catalyst to thereby form the terephthalate diesters.

Abstract: Disclosed is a process for the preparation of di-(2-ethylhexyl) terephthalate by the esterification of terephthalic acid with 2-ethylhexanol at elevated temperature and pressure while the water of reaction is removed from the reaction mixture.

Abstract: In a process for preparing an olefinic hydrocarbon mixture comprising at least 5% by weight of mono-olefin oligomers of the empirical formula: CnH2n where n is greater than or equal to 6, a feedstock comprising n-butene and propylene in a molar ratio of about 1:0.01 to about 1:0.49 is contacted under oligomerization conditions with surface deactivated ZSM-23. The resultant mono-olefin oligomers comprise at least 20 percent by weight of olefins having at least 12 carbon atoms, wherein said olefins having at least 12 carbon atoms have an average of from about 0.8 to about 2.0 C1–C3 alkyl branches per carbon chain.

Abstract: A tire buffer for buffing a tire casing as part of a retread operation can include a rasp pedestal having a rasp head and a texturing device. A moving assembly can be connected to the rasp pedestal for selectively moving the rasp pedestal along a pair of perpendicular axes. The rasp pedestal can rotate about a vertical axis. A tire hub assembly can be included for rotating the tire casing. The tire buffer can be operated at an operator station by interfacing with a control unit. The tire buffer can automatically buff a tire casing to achieve a predetermined tire casing profile and impart a texture thereto. The tire buffer includes a tire location mechanism and a tire measurement mechanism mounted to the rasp pedestal.

Abstract: Hydraulic engine valve actuation methods for internal combustion engines having improved energy efficiency. In hydraulic engine valve operating systems using spring returns for valve closure, the spring force is a minimum when the valve is closed and a maximum at the maximum lift. The present invention takes advantage of this difference by using a valve opening hydraulic force which is greater than the spring force when the valve is closed and less than the spring force when the valve is open at its maximum lift. The valve actuator is controlled to allow the valve, when opening, to overshoot the equilibrium condition. During the overshoot, the hydraulic actuator backfills with actuating fluid at it normal actuating pressure. When the valve velocity decays to zero or near zero, the flow of hydraulic fluid to (and from) the valve actuator may be cut off, capturing the valve substantially at the overshoot position.

Abstract: A tire buffer for buffing a tire casing as part of a retread operation can include a rasp pedestal having a rasp head and a texturing device. A moving assembly can be connected to the rasp pedestal for selectively moving the rasp pedestal along a pair of perpendicular axes. The rasp pedestal can rotate about a vertical axis. A tire hub assembly can be included for rotating the tire casing. The tire buffer can be operated at an operator station by interfacing with a control unit. The tire buffer can automatically buff a tire casing to achieve a predetermined tire casing profile and impart a texture thereto. The tire buffer includes a tire location mechanism and a tire measurement mechanism mounted to the rasp pedestal.

Abstract: A tire buffer for buffing a tire casing as part of a retread operation can include a rasp pedestal having a rasp head and a texturing device. A moving assembly can be connected to the rasp pedestal for selectively moving the rasp pedestal along a pair of perpendicular axes. The rasp pedestal can rotate about a vertical axis. A tire hub assembly can be included for rotating the tire casing. The tire buffer can be operated at an operator station by interfacing with a control unit. The tire buffer can automatically buff a tire casing to achieve a predetermined tire casing profile and impart a texture thereto. The tire buffer includes a tire location mechanism and a tire measurement mechanism mounted to the rasp pedestal.

Abstract: A tire buffer for buffing a tire casing as part of a retread operation can include a rasp pedestal having a rasp head and a texturing device. A moving assembly can be connected to the rasp pedestal for selectively moving the rasp pedestal along a pair of perpendicular axes. The rasp pedestal can rotate about a vertical axis. A tire hub assembly can be included for rotating the tire casing. The tire buffer can be operated at an operator station by interfacing with a control unit. The tire buffer can automatically buff a tire casing to achieve a predetermined tire casing profile and impart a texture thereto. The tire buffer includes a tire location mechanism and a tire measurement mechanism mounted to the rasp pedestal.

Abstract: Hydraulic engine valve actuation systems and methods for internal combustion engines. The systems utilize a proportional valve to regulate the flow of a working fluid to and from a hydraulic actuator controlling the engine valve position. The position of the proportional valve is controlled by one or more high speed valves to control various engine valve parameters, including engine valve takeoff and landing velocities. Returning all valves to a known starting position between engine valve events avoids accumulation of errors in proportional valve positioning. Embodiments using spool valves for the high speed valves and the proportional valve, and spring return and hydraulic return for the engine valve, are disclosed. A specially shaped spool in the proportional valve provides enhanced control over the engine valve operation. Various further alternate embodiments are disclosed.

Abstract: Hydraulic engine valve actuation methods for internal combustion engines having improved energy efficiency. In hydraulic engine valve operating systems using spring returns for valve closure, the spring force is a minimum when the valve is closed and a maximum at the maximum lift. The present invention takes advantage of this difference by using a valve opening hydraulic force which is greater than the spring force when the valve is closed and less than the spring force when the valve is open at its maximum lift. The valve actuator is controlled to allow the valve, when opening, to overshoot the equilibrium condition. During the overshoot, the hydraulic actuator backfills with actuating fluid at it normal actuating pressure. When the valve velocity decays to zero or near zero, the flow of hydraulic fluid to (and from) the valve actuator may be cut off, capturing the valve substantially at the overshoot position.

Abstract: Disclosed is a continuous process for the production of tertiary butyl esters by the reaction of a ketene and tertiary butyl alcohol containing a finite concentration of water. The process may be carried out in an absorber reactor with continuous recovery and purification of products by distillation. This process provides high-purity tertiary butyl acetate without the production of unwanted by-products found in many strong acid catalyzed processes.

Abstract: There are disclosed refrigeration working fluid compositions comprising tetrafluoroethane refrigerants and certain polyol esters of C7-C10 branched alkanoic acids or mixtures of such branched acids with linear C7-C10 monoalkanoic acids. The polyols are mono-, di- or technical grade pentaerythritol or trimethylolpropane; the esters exhibit suitable viscosity ranges and miscibility with refrigerants over a broad compositional range. The acids have a defined average effective carbon chain length and a certain degree of methyl branching for polyols other than trimethylolpropane.

Abstract: Hydraulic engine valve actuation systems and methods for internal combustion engines. The systems utilize a proportional valve to regulate the flow of a working fluid to and from a hydraulic actuator controlling the engine valve position. The position of the proportional valve is controlled by one or more high speed valves to control various engine valve parameters, including engine valve takeoff and landing velocities. Returning all valves to a known starting position between engine valve events avoids accumulation of errors in proportional valve positioning. Embodiments using spool valves for the high speed valves and the proportional valve, and spring return and hydraulic return for the engine valve, are disclosed. A specially shaped spool in the proportional valve provides enhanced control over the engine valve operation. Various further alternate embodiments are disclosed.

Abstract: Disclosed is a continuous process for the production of tertiary butyl esters by the reaction of a ketene and tertiary butyl alcohol containing a finite concentration of water. The process may be carried out in an absorber reactor with continuous recovery and purification of products by distillation. This process provides high-purity tertiary butyl acetate without the production of unwanted by-products found in many strong acid catalyzed processes.

Abstract: Hydraulic engine valve actuation systems and methods for internal combustion engines. The systems utilize a proportional valve to regulate the flow of a working fluid to and from a hydraulic actuator controlling the engine valve position. The position of the proportional valve is controlled by high speed valves to control various engine valve parameters, including engine valve takeoff and landing velocities. Returning all valves to a known starting position between engine valve events avoids accumulation of errors in proportional valve positioning. Embodiments using spool valves for the high speed valves and the proportional valve, and spring return and hydraulic return for the engine valve, are disclosed. A specially shaped spool in the proportional valve provides enhanced control over the engine valve operation. Various further alternate embodiments are disclosed.

Abstract: A cable pulling device for installing a second cable (14) along side an existing first cable (12). The cable puller (10) consists of a body (20) with a motor (22) mounted to the body (20). The motor (22) has an output shaft (24) attached to a drive wheel (26). The drive wheel (26) turns against the first cable (12) to propel the cable puller (10) along the first cable (12). The cable puller (10) also includes a motor controller (28) operably coupled to the motor (22) to control the motion of the motor (22). A cable clamp (30) is attached to the body (20) to secure a second cable (14) as it is pulled into position along side the first cable (12).

Abstract: A synthetic ester composition exhibiting low odor, and high thermal and oxidative stability which comprises the reaction product of: (a) a polyol which comprises at least dipentaerythritol, e.g., technical grade pentaerythritol and mixtures of technical grade pentaerythritol or dipentaerythritol and monopentaerythritol; and (b) a mixture of monocarboxylic acids comprising at least one linear acid selected from the group consisting of between C5-C10 acids and at least one branched acid selected from the group consisting of C7-C9 acids, wherein the amount of C5 and C6 acids is between about 20 to 45 weight %, based upon the total amount of said mixture of monocarboxylic acids, and wherein said synthetic ester composition has a viscosity of at least 4 cSt at 99° C., a viscosity of less than about 8,000 cSt at 40° C., and a pour point of at least as low as −54° C.

Abstract: A lubricating oil comprising an add mixture of the following components: (A) a complex alcohol ester basestock which comprises the reaction product of an add mixture of the following: (1) a polyhydroxyl compound represented by the general formula:R(OH).sub.nwherein R is any aliphatic or cyclo-aliphatic hydrocarbyl group and n is at least 2, provided that the hydrocarbyl group contains from about 2 to 20 carbon atoms; (2) a polybasic acid or an anhydride of a polybasic acid, provided that the ratio of equivalents of the polybasic acid to equivalents of alcohol from the polyhydroxyl compound is in the range between about 1.6:1 to 2:1; and (3) a monohydric alcohol, provided that the ratio of equivalents of the monohydric alcohol to equivalents of the polybasic acid is in the range between about 0.84:1 to 1.2:1; wherein the complex alcohol ester exhibits a viscosity in the range between about 100-700 cSt at 40.degree. C. and having a polybasic acid ester concentration of less than or equal to 70 wt.

Abstract: A polyol ester distillate fuel additive exhibits improved lubricity and friction and wear performance. The ester has between about 1% and about 35% unconverted hydroxyl groups and is characterized as having a hydroxyl number from about 5 to about 180.