Abstract: Aspects of the present disclosure relate to Schiff base oligomers and uses thereof In at least one aspect, an oligomer is represented by Formula (IV) wherein each instance of R9 is independently selected from the group consisting of alkyl, cycloalkyl, aryl, heteroaryl, and ether. Each instance of R28 and R29 of Formula (IV) is independently selected from the group consisting of hydrogen, alkyl, cycloalkyl, and aryl. Each instance of R33 of Formula (IV) is independently selected from the group consisting of alkyl, cycloalkyl, aryl, heterocyclyl, and a bond. Each instance of R41 of Formula (IV) is independently —NH— or a bond and each instance of R40 is independently —NH— or —NH—NH—. Each instance of R42 of Formula (IV) is independently —NH— or a bond and each instance of R43 is independently —NH— or —NH—NH—.

Abstract: Aspects described herein generally relate to a sol-gel that is the reaction product of an organosilane, a metal alkoxide, an acid, and a thio-lanthanide salt having a solubility of about 1 gram or greater per gram of sol-gel at 23° C. The thio-lanthanide salt includes a cation and a thio-ligand. The cation can be lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, scandium, yttrium, cobalt, calcium, strontium, barium, and zirconium. In another aspect, a component, such as a vehicle component, includes a metal substrate and a sol-gel disposed on the metal substrate. Methods can include forming a sol-gel by mixing a metal alkoxide and an acid to form a first mixture; mixing with the first mixture an organosilane to form a second mixture; and mixing with the second mixture a lanthanide salt to form a third mixture.

Abstract: Aspects of the present disclosure relate to Schiff base oligomers and uses thereof. In at least one aspect, an oligomer is represented by Formula (I) wherein each instance of R4, R5, R6, R7, R8, R10, R11, R12, R13, and R14 is independently selected from the group consisting of hydrogen, alkyl, cycloalkyl, alkoxyl, aryloxyl, ether, and heterocyclyl. Each instance of R9 of Formula (I) is independently selected from the group consisting of alkyl, cycloalkyl, aryl, heterocyclyl, and ether. Each instance of R28 and R29 of Formula (I) is independently selected from the group consisting of hydrogen, alkyl, and aryl. Each instance of R33 of Formula (I) is independently selected from the group consisting of alkyl, cycloalkyl, aryl, heterocyclyl, and a bond. Each instance of R41 of Formula (I) is independently —NH— or a bond and each instance of R40 is independently —NH— or —NH—NH—.

Abstract: The present disclosure relates to substrates and methods of producing substrates thereof. The substrates have a metal substrate and a sol-gel coating disposed on the metal substrate. The sol-gel coating includes about 3 wt % to about 15 wt % by volume of an organic corrosion inhibitor to the sol-gel. The sol-gel includes surfactant and a reaction product of an epoxy-containing organosilane, a metal alkoxide, and an acid.

Abstract: The present disclosure relates to a systems and methods for a coated substrate having a metal substrate and a sol-gel coating disposed on the metal substrate. The sol-gel includes a corrosion inhibitor, a surfactant and a reaction product of an epoxy-containing organosilane, a metal alkoxide, and an acid. The coated substrate includes an organic primer coating having an organic primer having a plurality of metal particles.

Abstract: A system for measuring corrosion includes a first electrode configured to be connected to a first structure and a second electrode configured to be connected to a second structure. The first and second structures are galvanically-coupled together, and the first and second structures are made of different materials. A chamber is configured to run through one or more cycles while the first electrode, the first structure, the second electrode, and the second structure are positioned inside the chamber. A measurement device is configured to receive data from the first and second electrodes and to measure one or more parameters based at least partially upon the data. A level of corrosion on the first structure, the second structure, or both is configured to be determined based at least partially upon the one or more parameters.

Abstract: A method for repairing a damaged portion of a steel member that includes at least one of a coating and a plating. The method includes applying to the damaged portion of the steel member a coating composition to produce a repair coating. The coating composition includes nickel, chromium, and carbon.

Abstract: Aspects described herein generally relate to a sol-gel that is the reaction product of an organosilane, a metal alkoxide, an acid, and a thio-lanthanide salt having a solubility of about 1 gram or greater per gram of sol-gel at 23° C. The thio-lanthanide salt includes a cation and a thio-ligand. The cation can be lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, scandium, yttrium, cobalt, calcium, strontium, barium, and zirconium. In another aspect, a component, such as a vehicle component, includes a metal substrate and a sol-gel disposed on the metal substrate. Methods can include forming a sol-gel by mixing a metal alkoxide and an acid to form a first mixture; mixing with the first mixture an organosilane to form a second mixture; and mixing with the second mixture a lanthanide salt to form a third mixture.

Abstract: Aspects of the present disclosure relate to Schiff base oligomers and uses thereof. In at least one aspect, an oligomer is represented by Formula (IV) wherein each instance of R9 is independently selected from the group consisting of alkyl, cycloalkyl, aryl, heteroaryl, and ether. Each instance of R28 and R29 of Formula (IV) is independently selected from the group consisting of hydrogen, alkyl, cycloalkyl, and aryl. Each instance of R33 of Formula (IV) is independently selected from the group consisting of alkyl, cycloalkyl, aryl, heterocyclyl, and a bond. Each instance of R41 of Formula (IV) is independently —NH— or a bond and each instance of R40 is independently —NH— or —NH—NH—. Each instance of R42 of Formula (IV) is independently —NH— or a bond and each instance of R43 is independently —NH— or —NH—NH—.

Abstract: Aspects of the present disclosure relate to Schiff base oligomers and uses thereof. In at least one aspect, an oligomer is represented by Formula (I) wherein each instance of R4, R5, R6, R7, R8, R10, R11, R12, R13, and R14 is independently selected from the group consisting of hydrogen, alkyl, cycloalkyl, alkoxyl, aryloxyl, ether, and heterocyclyl. Each instance of R9 of Formula (I) is independently selected from the group consisting of alkyl, cycloalkyl, aryl, heterocyclyl, and ether. Each instance of R28 and R29 of Formula (I) is independently selected from the group consisting of hydrogen, alkyl, and aryl. Each instance of R33 of Formula (I) is independently selected from the group consisting of alkyl, cycloalkyl, aryl, heterocyclyl, and a bond. Each instance of R41 of Formula (I) is independently —NH— or a bond and each instance of R40 is independently —NH— or —NH—NH—.

Abstract: The present disclosure provides a coated iron particle, or reaction product of a coating and the iron particle, comprising an iron particle and a ceramic coating disposed on the iron particle. Aspects of the present disclosure provide a coated iron particle, or reaction product of a coating and the iron particle, including an iron particle having a diameter of from about 0.5 micron to about 100 microns; and a ceramic coating disposed on the iron particle. Aspects of the present disclosure further provide compositions comprising a coated iron particle and a polymer or adhesion promoter. Aspects of the present disclosure further provide components, such as components, such as vehicle components, having a surface and a composition of the present disclosure disposed on the surface.

Abstract: The present disclosure provides a coated iron particle, or reaction product of a coating and the iron particle, comprising an iron particle and a ceramic coating disposed on the iron particle. Aspects of the present disclosure provide a coated iron particle, or reaction product of a coating and the iron particle, including an iron particle having a diameter of from about 0.5 micron to about 100 microns; and a ceramic coating disposed on the iron particle. Aspects of the present disclosure further provide compositions comprising a coated iron particle and a polymer or adhesion promoter. Aspects of the present disclosure further provide components, such as components, such as vehicle components, having a surface and a composition of the present disclosure disposed on the surface.

Abstract: A corrosion inhibition composition includes a carrier and a Schiff base in admixture with the carrier. The carrier includes at least one of water, a hydrocarbon solvent, and a binder.

Abstract: A method for repairing a damaged portion of a steel member that includes at least one of a coating and a plating. The method includes applying to the damaged portion of the steel member a coating composition to produce a repair coating. The coating composition includes nickel, chromium, and carbon.

Abstract: Compositions are described for protecting a metal surface against corrosion. The composition includes a corrosion-inhibiting particle. The corrosion inhibiting particle may be usable in an epoxy resin-based coating or an olefin resin-based coating. The particle may include a core and a protectant. The core may include a water soluble corrosion inhibitor. The protectant may be disposed on at least a portion of a surface of the core and may be covalently or ionically bonded to a thiol group of the corrosion inhibitor. The protectant may be configured to reduce reaction between the core and the epoxy resin or the olefin resin. Methods of making the compositions are also disclosed.

Abstract: Compositions are described for protecting a metal surface against corrosion. The composition includes a corrosion-inhibiting particle. The corrosion inhibiting particle may be usable in an epoxy resin-based coating or an olefin resin-based coating. The particle may include a core and a protectant. The core may include a water soluble corrosion inhibitor. The protectant may be disposed on at least a portion of a surface of the core and may be covalently or ionically bonded to a thiol group of the corrosion inhibitor. The protectant may be configured to reduce reaction between the core and the epoxy resin or the olefin resin. Methods of making the compositions are also disclosed.

Abstract: Compositions are described for protecting a metal surface against corrosion. The composition includes a corrosion-inhibiting particle. The corrosion inhibiting particle may be usable in an epoxy resin-based coating or an olefin resin-based coating. The particle may include a core and a protectant. The core may include a water soluble corrosion inhibitor. The protectant may be disposed on at least a portion of a surface of the core and may be covalently or ionically bonded to a thiol group of the corrosion inhibitor. The protectant may be configured to reduce reaction between the core and the epoxy resin or the olefin resin. Methods of making the compositions are also disclosed.

Abstract: A system for measuring corrosion includes a first electrode configured to be connected to a first structure and a second electrode configured to be connected to a second structure. The first and second structures are galvanically-coupled together, and the first and second structures are made of different materials. A chamber is configured to run through one or more cycles while the first electrode, the first structure, the second electrode, and the second structure are positioned inside the chamber. A measurement device is configured to receive data from the first and second electrodes and to measure one or more parameters based at least partially upon the data. A level of corrosion on the first structure, the second structure, or both is configured to be determined based at least partially upon the one or more parameters.

Abstract: Aspects of the present disclosure relate to Schiff base oligomers and uses thereof. In at least one aspect, an oligomer is represented by Formula (IV) wherein each instance of R9 is independently selected from the group consisting of alkyl, cycloalkyl, aryl, heteroaryl, and ether. Each instance of R28 and R29 of Formula (IV) is independently selected from the group consisting of hydrogen, alkyl, cycloalkyl, and aryl. Each instance of R33 of Formula (IV) is independently selected from the group consisting of alkyl, cycloalkyl, aryl, heterocyclyl, and a bond. Each instance of R41 of Formula (IV) is independently —NH— or a bond and each instance of R40 is independently —NH— or —NH—NH—. Each instance of R42 of Formula (IV) is independently —NH— or a bond and each instance of R43 is independently —NH— or —NH—NH—.

Abstract: Aspects of the present disclosure relate to Schiff base oligomers and uses thereof. In at least one aspect, an oligomer is represented by Formula (I) wherein each instance of R4, R5, R6, R7, R8, R10, R11, R12, R13, and R14 is independently selected from the group consisting of hydrogen, alkyl, cycloalkyl, alkoxyl, aryloxyl, ether, and heterocyclyl. Each instance of R9 of Formula (I) is independently selected from the group consisting of alkyl, cycloalkyl, aryl, heterocyclyl, and ether. Each instance of R28 and R29 of Formula (I) is independently selected from the group consisting of hydrogen, alkyl, and aryl. Each instance of R33 of Formula (I) is independently selected from the group consisting of alkyl, cycloalkyl, aryl, heterocyclyl, and a bond. Each instance of R41 of Formula (I) is independently —NH— or a bond and each instance of R40 is independently —NH— or —NH—NH—.