Abstract: The present invention relates to a curable composition, which comprises: (A) at least one unreactive blocked diisocyanate; (B) at least one unreactive blocked diamine; (C) at least one reactive component; and (D) at least one photo-initiator, wherein component (B) is formed by blocking diamine with a ligand; to a process of forming a 3D-printed object from the same and a 3D-printed object prepared therefrom.

Abstract: This disclosure relates to thermoplastic polyurethane (TPU) powders derived from expanded TPU and/or molding part thereof, wherein the average particle size D50 of the powders is no more than 1 mm, to a 3D molding formed from the same and to a process of forming the 3D molding. The TPU powders of the present invention can be used to prepare 3D products with low density, high rebound resilience and good mechanical properties, and the TPU powders of the present invention can be derived from a wide range of sources, and the TPU powders and 3D products of the present invention can be easily reused.

Abstract: This disclosure relates to thermoplastic elastomer (TPE) powders, wherein the average particle size D50 of the TPE powders is in the range from 10 ?m to 1 mm and at least one of average sphericity A and average sphericity B of TPE powders is no more than 0.6; to a process of preparing the TPE powders and to a method of preparing the 3D molding. The powders and the method according to the present invention allow to prepare a 3D molding with low density, high rebound resilience and good mechanical properties, especially a 3D molding comprising multiple areas having different properties.

Abstract: The present invention relates to a curable composition for 3D-printing, which comprises: (A) at least one reactive component: (B) at least one physical volatile agent; and (C) at least one photoinitiator, a process of forming a 3D-printed object from the same and a 3D-printed object prepared therefrom. The 3D-printed object formed from the composition has reduced density, stable dimension size, and uniform porous structure.

Abstract: The present disclosure relates to a thermoplastic pulverulent composition comprising (a) at least one silica particle treated with alkoxysilane; and (b) at least one thermoplastic polymer. The present disclosure also relates to a 3D-printed object formed from the thermoplastic pulverulent composition and a process of forming the 3D-printed object. The thermoplastic pulverulent composition shows good powder flowability and the printed object obtained from said thermoplastic pulverulent composition surprisingly shows high elongation at break, high impact strength, good toughness and low surface roughness.

Abstract: This disclosure relates to a radiation-curable liquid composition, comprising following components: (A) at least one radiation-curable reactive component; (B) at least one photoinitiator; and (C) at least one expandable microsphere and/or lightweight filler, relates to a 3D-printed object formed from the radiation-curable liquid composition as well as a process of forming the 3D-printed object. The 3D-printed object formed from the composition shows excellent energy return property and good mechanical property as well as low density and foam structure.

Abstract: The present disclosure relates to a pulverulent composition comprising (a) at least one phosphate flame retardant synergist selected from hydrogen phosphate salt, dihydrogen phosphate salt, hydrate thereof and mixture thereof; (b) at least one flame retardant; and (c) at least one thermoplastic polymer. The present disclosure also relates to a 3D-printed object formed from the pulverulent composition and a process of forming 3D-printed object. The pulverulent composition shows good printability and the 3D-printed objects obtained from the thermoplastic powders not only have excellent flame-retardant performance but also have good mechanical properties.

Abstract: The invention relates to a photo-curable liquid resin composition for 3D printing, its preparation process and use, and also to a method of forming a 3D-printed object by using the composition. By using the inventive composition for 3D printing, the improvement of the flexibility and elasticity of the cured composition can be achieved.