Abstract: A single step, in situ curing method for making gel polymer lithium ion rechargeable cells and batteries is described. This method used a precursor solution consisting of monomers with multiple functionalities such as multiple acryloyl functionalities, a free-radical generating activator, nonaqueous solvents such as ethylene carbonate and propylene carbonate, and a lithium salt such as LiPF6. The electrodes are prepared by slurry-coating a carbonaceous material such as graphite onto an anode current collector and a lithium transition metal oxide such as LiCoO2 onto a cathode current collector, respectively. The electrodes, together with a highly porous separator, are then soaked with the polymer electrolyte precursor solution and sealed in a cell package under vacuum. The whole cell package is heated to in situ cure the polymer electrolyte precursor.

Abstract: A single step, in situ curing method for making gel polymer lithium ion rechargeable cells and batteries is described. This method used a precursor solution consisting of monomers with multiple functionalities such as multiple acryloyl functionalities, a free-radical generating activator, nonaqueous solvents such as ethylene carbonate and propylene carbonate, and a lithium salt such as LiPF6. The electrodes are prepared by slurry-coating a carbonaceous material such as graphite onto an anode current collector and a lithium transition metal oxide such as LiCoO2 onto a cathode current collector, respectively. The electrodes, together with a highly porous separator, are then soaked with the polymer electrolyte precursor solution and sealed in a cell package under vacuum. The whole cell package is heated to in situ cure the polymer electrolyte precursor.

Abstract: A lithium ion battery electrode formed by the pyrolysis of a silane polymer followed by introducing lithium ions. These electrodes can be used to form batteries with large capacities, low irreversible capacity, high density and good safety behavior.

Abstract: A lithium ion battery electrode formed by the pyrolysis of a polycarbosilane followed by introducing lithium ions. These electrodes can be used to form batteries with large capacities, low irreversible capacity, high density and good safety behavior.

Abstract: A lithium ion battery electrode formed by the pyrolysis of a siloxane polymer of the structure(R.sup.1 R.sup.2 R.sup.3 SiO.sub.0.5).sub.w (R.sup.4 R.sup.5 SiO).sub.x (R.sup.6 SiO.sub.1.5).sub.y (SiO.sub.4/2).sub.zfollowed by introducing lithium ions. In this structure, each R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are independently selected from the group consisting of hydrogen and a hydrocarbon, w is in the range of 0 to about 0.8, x is in the range of 0 to about 0.9, y is in the range of 0 to about 0.9, z is in the range of 0 to 1 and w+x+y+z=1.

Abstract: A lithium ion battery electrode formed by the pyrolysis of a silazane polymer followed by introducing lithium ions. These electrodes can be used to form batteries with large capacities, low irreversible capacity, high density and good safety behavior.