Abstract: A hard tissue repair adhesive composition and a hard tissue repair kit comprising same. The adhesive composition comprises a polymerizable monomer (A), polymer powder (B), a polymerization initiator (C), and a filler (D). The polymerization initiator (C) comprises 100 parts by weight of alkoxydialkylboron having a purity of 97% or more and 0.2-5 parts by weight of an alcohol having a boiling point of 60° C. to 180° C. The polymerization initiator (C) does not generate smoke or coking or present ignition quality even when in contact with paper, porous fibers or the like in air, is easy to be taken in a small amount, and can provide a polymerizable composition with high polymerization activity, thereby providing an adhesive composition suitable for hard tissue repair. (A), (B), (C), (D) and all other components comprised according to requirements of the adhesive composition for hard tissue repair can be separately or mixedly stored in three or more members to form a repair kit.

Abstract: An adhesive composition for hard tissue repair, comprising a polymerizable monomer (A), a polymer powder (B), and a polymerization initiator (C), wherein the polymerization initiator (C) is represented by the following general formula: [CH3(CH2)m-]2B—O(CH2)nCH3, and in the formula, m and n are each independently an integer from 1 to 4, and the relational expression that 2m+n<=10 is satisfied. The polymerization initiator cannot show coking or ignitability even when in contact with paper, a porous fiber, and the like in air, and is high in fluidity and easy to take a small and correct amount, so as to reduce adverse effects on a human body: and high polymerization activity can be given to a polymerizable composition, so that the polymerizable composition is cured within a short time, and the adhesive composition suitable for hard tissue repair is provided.

Abstract: The dental adhesive composition of the present invention comprises a polyfunctional polymerizable monomer which is an ester compound of a polyhydric alcohol of 3 to 6 carbon atoms and plural (meth)acrylic acids and has 1 to 2 hydroxyl groups, a monofunctional (meth)acrylate having no hydroxyl group in its molecule, a polymerizable monomer containing an acid group in its molecule, an organoboron compound as a curing agent and a filler. According to the present invention, a dental adhesive composition remarkably enhanced in the curing rate with rarely affecting adhesion properties of the composition, working time and flexibility of a cured product is provided.

Abstract: A polymerization initiator composition which does not burn or ignite even when it contacts paper or the like in air and can provide high polymerization activity to a polymerizable composition to cure it in a short period of time, and an adhesive composition comprising the same. The above polymerization initiator composition comprises 100 parts by weight of (A) an organic boron compound such as a trialkyl boron, alkoxyalkyl boron, dialkylborane, monocyclo or bicyclo compound having a boron atom as a hetero atom or partially oxidated trialkyl boron, 5 to 40 parts by weight of (B) an aprotic solvent having a boiling point of 50 to 120° C., and 0.2 to 5 parts by weight of (C) an alcohol having a boiling point of 60 to 180° C.

Abstract: An adhesive resin cement composition having excellent adhesion and physical properties without the application of a priming material or an adhesive when it is bonded to the enamel and aesthetic properties. A photocurable dental enamel adhesive composition comprising (A) a radically polymerizable monomer having an acid group and a structure represented by the following formula (1): CH2?CR1—COO—R2—OCO—R3—COOH ??(1) (R1 is H or CH3, and R2 and R3 are each independently a divalent inert group essentially composed of C and H), (B) a monofunctional radically polymerizable monomer having a molecular weight of 220 or less and a boiling point of 60° C./10 mmHg or more, (C) a carboxylic ester group-containing aromatic amine, (D) a photopolymerization initiator and (E) a bifunctional radically polymerizable monomer and optionally (F) a filler.

Abstract: The dental adhesive composition of the present invention comprises a polyfunctional polymerizable monomer which is an ester compound of a polyhydric alcohol of 3 to 6 carbon atoms and plural (meth)acrylic acids and has 1 to 2 hydroxyl groups, a monofunctional (meth)acrylate having no hydroxyl group in its molecule, a polymerizable monomer containing an acid group in its molecule, an organoboron compound as a curing agent and a filler. According to the present invention, a dental adhesive composition remarkably enhanced in the curing rate with rarely affecting adhesion properties of the composition, working time and flexibility of a cured product is provided.

Abstract: The present invention is a polymerization initiator paste composition which comprises (A) an organoboron compound which is liquid at 25° C. and (B) particles having an average particle diameter of 0.001 to 50 ?m and inert to the organoboron compound (A), in an amount of 4 to 400 parts by weight based on 100 parts by weight of the organoboron compound (A), and has a consistency, as measured at 25° C. under a load of 300 g in accordance with a method defined in ISO4823, of 15 to 100 mm. This composition constitutes a dental kit or the like together with a polymerizable monomer separately packaged. According to the present invention, an organoboron compound can be used safely, and because the composition is a paste, it is very easily utilized.

Abstract: A curable dental adhesive composition of the type including polymerizable monomer and polymerization initiator may be easily prepared and applied to a tooth surface by using a tool which includes fibrous or sponge material, adapted to fit within a person's mouth, and carrying at least part of the polymerization initiator. Polymerizable monomer and any remaining polymerization initiator as well as filler and other ingredients may be brought into contact with the tool to form the curable composition just prior to applying the composition to the tooth surface. The tool may be part of a kit which also includes a container for polymerizable monomer and, as necessary, one or more additional containers for remaining polymerization initiator(s), fillers, etc. No separate mixing container is required.

Abstract: An adhesive composition for dental or surgical treatment comprising (A) 2 to 24 parts by weight of an organic boron compound, (B) 0.002 to 0.5 part by weight of a photopolymerization initiator, (C) 75 to 97 parts by weight of a polymerizable monomer mixture comprising 2 to 20% by weight of a monomer containing an acidic group and 80 to 98% by weight of a monomer containing no acidic group, and (D) optionally, 250 parts or less by weight of a filler.

Abstract: A polymerization initiator composition comprising 100 parts by weight of an organic boron compound (A) and 10 to 150 parts by weight of an aprotic solvent (B) having a boiling point of 30 to 150.degree. C.; and a dental or surgical adhesive composition containing the above polymerization initiator composition.

Abstract: A polymerization initiator composition comprising 100 parts by weight of an organic boron compound (A) and 10 to 150 parts by weight of an aprotic solvent (B) having a boiling point of 30.degree. to 150.degree. C.; and a dental or surgical adhesive composition containing the above polymerization initiator composition.

Abstract: A curable composition comprising a polymerizable monomer having an acidic group in its molecule and an initiator. The composition has a viscosity in the range of from 100 to 30,000 cP at 37.5.degree. C. and may have additionally contain other polymerizable monomer and/or a filler. The composition is applied to a tooth surface directly or after applying a primer composition. There is also provided the primer composition which comprises a polymerizable monomer having an acidic group and a solvent.

Abstract: An adhesive composition comprising (A) 98 to 60 parts by weight of a polymerizable monomer mixture containing 2 to 25% by weight of a monomer having acidic group, (B) 2 to 40 parts by weight of a polymer, preferably a polymer which can form a solution or dispersion having the property that the solution or dispersion of 10 parts by weight of the polymer in 90 parts by weight of methyl methacrylate shows a viscosity of 100 cps or less at 25.degree. C., and (C) 0.01 to 35 parts by weight of a polymerization initiator, provided that the total amount of the components (A), (B) and (C) is 100 parts by weight.According to the present invention, there can be provided an adhesive composition which is easy to handle for the restoration treatment of a tooth, so that adhesion dental treatment can be reliably carried out.

Abstract: A primer composition for the treatment of a tooth surface, which comprises a) at least one metal compound selected from the group consisting of an iron compound, a copper compound and a cobalt compound, b) a polymerizable monomer having an acidic group, and c) water or water and an organic solvent miscible with water; and a method of forming an adhesive layer on a tooth surface, which comprises applying this primer composition to the tooth surface and then applying a curable composition containing trialkylborane or partial oxide thereof and a polymerizable monomer. According to the present invention, both the enamel and the dentin of a tooth can be simultaneously surface-treated without acid treatment or washing with water, and adhesion dental treatment can be reliably carried out by a simple operation without causing pains on a patient.

Abstract: A curable composition comprising a polymerizable monomer having an acidic group in its molecule and an initiator. The composition has a viscosity in the range of from 100 to 30,000 cP at 37.5.degree. C. and may have additionally contain other polymerizable monomer and/or a filler. The composition is applied to a tooth surface directly or after applying a primer composition. There is also provided the primer composition which comprises a polymerizable monomer having an acidic group and a solvent.

Abstract: A curable composition comprising a polymerizable monomer having an acidic group in its molecule and an initiator. The composition has a viscosity in the range of from 100 to 30,000 cP at 37.5.degree. C. and may have additionally contain other polymerizable monomer and/or a filler. The composition is applied to a tooth surface directly or after applying a primer composition. There is also provided the primer composition which comprises a polymerizable monomer having an acidic group and a solvent.