Abstract: The present invention discloses an electrocatalytic Fenton oxidation-electrochemical oxidation coupling process and apparatus for efficient treatment of chemical wastewater, and belongs to the field of sewage treatment. The process includes an electrocatalytic Fenton oxidation step, an electrochemical oxidation step, and a pH adjustment step. A spacing between a cathode and an anode in the electrocatalytic Fenton oxidation step is controlled, so that oxygen produced at the anode reacts at the cathode to produce H2O2. The treatment requirements can be met without external aeration or external addition of H2O2, and meanwhile, the efficiency of COD removal by electro-Fenton oxidation is effectively improved. Further, by connecting a pH adjusting tank with the electrocatalytic Fenton oxidation-electrochemical oxidation coupling apparatus in series, a coupling treatment process with near-zero production of iron sludge is realized.

Abstract: A gas diffusion electrode includes a carbon fiber tube, a support layer, and a catalyst layer. The carbon fiber tube is straight and functions as a substrate. The support layer includes a carbon black-polytetrafluoroethylene (PTFE) coating, and is disposed on the substrate. The catalyst layer includes carbon black, anhydrous ethanol, and PTFE, and is disposed on the support layer. The gas diffusion electrode has a diameter of 3-20 mm and a length of 50-500 mm.

Abstract: A water-processing electrochemical reactor that comprises a cylindrical inner anode (73), an outer tubular cathode (74), an intermediate chamber between the anode (73) and the cathode (74) and being crossed by the water, an outer shell (77) surrounding the cathode (74), a water inlet (71) and a water outlet (78), and a gas inlet (80) and gas outlet (79) connected to the outer shell (77) and to the gas chamber. The cathode surrounds the inner anode (73) and is porous to gas. A gas chamber is defined between the cathode (74) and the outer shell (77). The gas chamber contains a gas comprising oxygen and is at an overpressure that forces the gas through the porous cathode (74).

Abstract: An electrode includes a microporous titanium substrate coated with a catalytic layer, and the catalytic layer includes magnetic SnO2—Sb particles. The magnetic SnO2—Sb particles are attached to the microporous titanium substrate through an external magnetic field. The microporous titanium substrate includes a plurality of membrane pores having a pore size of 5-50 ?m that is smaller than a particle size of the magnetic SnO2—Sb particles.

Abstract: The present invention relates to the technical field of electrocatalytic electrode preparation, and discloses a lead dioxide-carbon nanotube adsorptive electrochemical submicroelectrode, a preparation method, and use thereof. The electrochemical submicroelectrode according to the present invention comprises multiple layers of orderly arranged spherical lead dioxide submicroholes communicating with each other, where the carbon nanotubes are partially or completely inserted (in the form of twigs) in the lead dioxide hole and in the wall of the hole. The combined effect of adsorption and catalysis inside the submicroreactor effectively solves the problems of low catalytic efficiency and diffusion control associated with the conventional flat lead dioxide electrode, thus greatly improving the electrochemical catalytic performance of the electrode.

Abstract: Disclosed is a device for selective oxidation of macromolecular organic pollutants using free radicals produced in a heterogeneous Fenton reaction. The device includes a heterogeneous Fenton reaction unit and an electrochemical cell. The heterogeneous Fenton reaction unit includes a reactor and an anion exchange membrane. The anion exchange membrane is disposed in the reactor and separates the reactor into a first chamber and a second chamber. The first chamber is filled with a catalyst and the wastewater to be treated; and the second chamber is filled with a dielectric material. The electrochemical cell is configured to supply an electric field to the reactor, so that organic acids generated by a heterogeneous Fenton reaction move from the first chamber into the second chamber.

Abstract: A base material includes a base layer. The base layer includes a structured surface. The base layer includes a transition metal and a transition metal oxide, and a sum of the transition metal and a transition metal oxide accounts for at least 90 wt. % of the base layer. The transition metal oxide is concentratedly distributed on the structured surface. The base material is flexible in at least one direction, and has a bending angle of not less than 90° when being bent.

Abstract: The present invention discloses an electrocatalytic Fenton oxidation-electrochemical oxidation coupling process and apparatus for efficient treatment of chemical wastewater, and belongs to the field of sewage treatment. The process includes an electrocatalytic Fenton oxidation step, an electrochemical oxidation step, and a pH adjustment step. A spacing between a cathode and an anode in the electrocatalytic Fenton oxidation step is controlled, so that oxygen produced at the anode reacts at the cathode to produce H2O2. The treatment requirements can be met without external aeration or external addition of H2O2, and meanwhile, the efficiency of COD removal by electro-Fenton oxidation is effectively improved.

Abstract: The present invention provides an ultrafiltration membrane comprising a sulfone polymer membrane matrix with pores and an organic polymer sealing layer, wherein the pores are filled with nanoadsorbents. The present invention further provides a method for preparing the ultrafiltration membrane, which includes the following steps: (1) synthesizing nanoadsorbents; (2) preparing the sulfone polymer membrane matrix by immersion-precipitation phase inversion; and (3) immobilizing nanoadsorbents in the pores of the sulfone polymer membrane matrix by reverse filling, then sealing the pores with organic polymers to form a multifunctional ultrafiltration membrane. In the present invention, colloidal gold, polyethylene glycol molecules and Pb(II) ions (and so forth) are utilized as models of viruses, macromolecular organic pollutants, and small molecular pollutants, respectively.

Abstract: The present invention provides an ultrafiltration membrane comprising a sulfone polymer membrane matrix with pores and an organic polymer sealing layer, wherein the pores are filled with nanoadsorbents. The present invention further provides a method for preparing the ultrafiltration membrane, which includes the following steps: (1) synthesizing nanoadsorbents; (2) preparing the sulfone polymer membrane matrix by immersion-precipitation phase inversion; and (3) immobilizing nanoadsorbents in the pores of the sulfone polymer membrane matrix by reverse filling, then sealing the pores with organic polymers to form a multifunctional ultrafiltration membrane. In the present invention, colloidal gold, polyethylene glycol molecules and Pb(II) ions (and so forth) are utilized as models of viruses, macromolecular organic pollutants, and small molecular pollutants, respectively.