Abstract: Persistent infrared (IR) phosphors are disclosed. In an embodiment a phosphor has the general formula: M1(m?k)Ga(2n?x?y?z)M2pO(rm+3n+2p:xSb3+,yM3,zD,kM4, wherein M1 is chosen from magnesium, calcium, barium, strontium, zinc, scandium, yttrium, lanthanum, gadolinium, lutetium, or bismuth, or combinations thereof; M2 is chosen from silicon, germanium, tin, titanium, zirconium, or combinations thereof; M3 is chosen from magnesium, aluminum, indium, scandium, or combinations thereof; M4 is chosen from praseodymium, neodymium, samarium, europium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, or combinations thereof; D is chosen from chromium, iron, nickel, manganese, or cobalt, or combinations thereof; and wherein 1?m?4; 1?n?3; 0?p?5; 0.0002?x?2n; 0?y?2n; 0.0001?z?0.1; 0?k?0.1; and r is selected from 1, 1.5, 2, 2.5, and 3.

Abstract: Persistent infrared (IR) phosphors are disclosed. In an embodiment a phosphor has the general formula: M1(m?k)Ga(2n?x?y?z)M2pO(rm+3n+2p):xSb3+,yM3,zD,kM4, wherein M1 is chosen from magnesium, calcium, barium, strontium, zinc, scandium, yttrium, lanthanum, gadolinium, lutetium, or bismuth, or combinations thereof; M2 is chosen from silicon, germanium, tin, titanium, zirconium, or combinations thereof; M3 is chosen from magnesium, aluminum, indium, scandium, or combinations thereof; M4 is chosen from praseodymium, neodymium, samarium, europium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, or combinations thereof; D is chosen from chromium, iron, nickel, manganese, or cobalt, or combinations thereof; and wherein 1?m?4; 1?n?3; 0?p?5; 0.0002?x?2n; 0?y?2n; 0.0001?z?0.1; 0?k?0.1; and r is selected from 1, 1.5, 2, 2.5, and 3.

Abstract: Disclosed are smoothing phosphors for AC LED lighting that are capable of prolonging the light emission time of an AC LED (or array of AC LEDs) during a ½ cycle response to a phase change of the alternating current to substantially reduce flicker. The smoothing phosphor of the present teachings comprises a matrix represented by the formula: M(l-k-r-v)X(m-p)Al2(n-0.5x-0.5y)O3(n-0.5x-0.5y): Mn(x+p)O(x+p), SiyO2y, Euk, Rr, Liv wherein M is at least one of La2O3, Ce2O3, Gd2O3, Lu2O3, Ba2OF2, Sr2OF2, Ca2OF2, Ba2OCl2, Sr2OCl2, Ca2OCl2, BaO, SrO, CaO, or ZnO; provided that when M comprises BaO, SrO, CaO, or ZnO, M does not comprise La2O3, Ce2O3, Gd2O3, Lu2O3, Ba2OF2, Sr2OF2, Ca2OF2, Ba2OCl2, Sr2OCl2, or Ca2OCl2; X is at least one of MgO or ZnO; R is at least one of Sm, Pr, Tb, Dy, Er, or Ho; m=0 to 2; n=4 to 11; x=0.005 to 1; y=0.005 to 1; p=0 to 1; k=0 to 0.2; r=0 to 0.2; and v=0 to 0.2.

Abstract: Disclosed are smoothing phosphors for AC LED lighting that are capable of prolonging the light emission time of an AC LED (or array of AC LEDs) during a ½ cycle response to a, phase change of the alternating current to substantially reduce flicker. The smoothing phoshor of the present teachings comprises a matrix represented by the formula: (1?k?r?v)M·(m?p)X·(n?0.5x?0.5y)Al2O3:(x+p)MnO, ySiO2, kEu, rR, vLi, wherein M is at least one of La2O3, Ce2O3, Gd2O3, Lu2O3, Ba2OF2, Sr2OF2, Ca2OF2, Ba2OCl2, Sr2OCl2, Ca2OCl, BaO, SrO, CaO, or ZnO; provided that when M comprises BaO, SrO, CaO, or ZnO, M does not comprise La2O3, Ce2O3, Gd2O3, Lu2O3, Ba2OF2, Sr2OF2, Ca2OF2, Ba2OCl2, Sr2OCl2, or Ca2OCl2; X is at least one of MgO or ZnO; R is at least one of Sm, Pr, Tb, Dy, Er, or Ho; m=0 to 2; n=4 to 11; x=0.005 to 1; y=0.005 to 1; p=0 to 1; k=0 to 0.2; r=0 to 0.2; and v=0 to 0.2.

Abstract: Disclosed are smoothing phosphors for AC LED lighting that are capable of prolonging the light emission time of an AC LED (or array of AC LEDs) during a ½ cycle response to a phase change of the alternating current to substantially reduce flicker. The smoothing phosphor of the present teachings comprises a matrix represented by the formula: M(1?k?r?v)X(m?p)Al2(n?0.5x?0.5y)O2(n?0.5x?0.5y):Mn(n+p)O(x+p), SiyO2y, Euk, Rr, Liv wherein M is at least one of La2O3, Ce2O3, Gd2O3, Lu2O3, Ba2OF2, Sr2OF2, Ca2OF2, Ba2OCl2, Sr2OCl2, Ca2OCl2, BaO, SrO, CaO, or ZnO; provided that when M comprises BaO, SrO, CaO, or ZnO, M does not comprise La2O3, Ce2O3, Gd2O3, Lu2O3, Ba2OF2, Sr2OF2, Ca2OF2, Ba2OCl2, Sr2OCl2, or Ca2OCl2; X is at least one of MgO or ZnO; R is at least one of Sm, Pr, Tb, Dy, Er, or Ho; m=0 to 2; n=4 to 11; x=0.005 to 1; y=0.005 to 1; p=0 to 1; k=0 to 0.2; r=0 to 0.2; and v=0 to 0.2.

Abstract: Phosphorescent compositions including silicate of alkaline earth materials which are modified by at least one halide are provided. The phosphorescent compositions may include 3d ions. A variety of embodiments may be realized. The appearance of some embodiments may be glassy (i.e., vitreous).

Abstract: Compositions, methods of making compositions, materials including compositions, crayons including compositions, paint including compositions, ink including compositions, waxes including compositions, polymers including compositions, vesicles including the compositions, methods of making each, and the like are disclosed.

Abstract: Photoluminescent phosphors wherein some of the oxygen anions in the phosphor matrix have been replaced by halides or nitride. In addition, photoluminescent phosphors wherein some of the oxygen anions in the phosphor matrix have been replaced by halides or nitride and a charge compensator has been included. The phosphors are based on green emitting and blue-green emitting aluminates.

Abstract: Compositions, methods of making compositions, materials including compositions, crayons including compositions, paint including compositions, ink including compositions, waxes including compositions, polymers including compositions, vesicles including the compositions, methods of making each, and the like are disclosed.

Abstract: Phosphorescent compositions including silicate of alkaline earth materials which are modified by at least one halide are provided. The phosphorescent compositions may include 3d ions. A variety of embodiments may be realized. The appearance of some embodiments may be glassy (i.e., vitreous).

Abstract: Compositions, methods of making compositions, materials including compositions, crayons including compositions, paint including compositions, ink including compositions, waxes including compositions, polymers including compositions, vesicles including the compositions, methods of making each, and the like are disclosed.

Abstract: Photoluminescent phosphors wherein some of the oxygen anions in the phosphor matrix have been replaced by halides or nitride. In addition, photoluminescent phosphors wherein some of the oxygen anions in the phosphor matrix have been replaced by halides or nitride and a charge compensator has been included. The phosphors are based on green emitting and blue-green emitting aluminates.

Abstract: Embodiments of the present disclosure include Gd3+—Nd3+ infrared phosphor compositions, methods of making Gd3+—Nd3+ infrared phosphor compositions, and the like.

Abstract: The invention provides long-persistent phosphors, methods for their manufacture and phosphorescent articles. The invention also provides a method for generating a long-persistent phosphorescence at a selected color. The phosphors of the invention may be alkaline earth aluminates, alkaline earth silicates, and alkaline earth aluminosilicates. The phosphors include those activated by cerium. The phosphors also include those in which persistent energy transfer occurs from a donor ion to an acceptor ion, producing persistent emission largely characteristic of the acceptor ion.

Abstract: The invention provides long-persistent phosphors, methods for their manufacture and phosphorescent articles. The invention also provides a method for generating a long-persistent phosphorescence at a selected color. The phosphors of the invention may be alkaline earth aluminates, alkaline earth silicates, and alkaline earth aluminosilicates. The phosphors include those activated by cerium. The phosphors also include those in which persistent energy transfer occurs from a donor ion to an acceptor ion, producing persistent emission largely characteristic of the acceptor ion.

Abstract: This invention relates to phosphors including long-persistence green phosphors. Phosphors of the invention are represented by the general formula: MkAl2O4:2xEu2+,2yR3+ wherein k−1-2x-2y, x is a number ranging from about 0.0001 to about 0.05, y is a number ranging from about x to about 3x, M is an alkaline earth metal, and R3+ is one or more trivalent metal ions. Phosphors of this invention include powders, ceramics, single crystals and single crystal fibers. A method of manufacturing improved phosphors and a method of manufacturing single crystal phosphors are also provided.

Abstract: This invention relates to phosphors including long-persistence blue phosphors. Phosphors of the invention are represented by the general formula:MO . mAl.sub.2 O.sub.3 :Eu.sup.2+,R.sup.3+wherein m is a number ranging from about 1.6 to about 2.2, M is Sr or a combination of Sr with Ca and Ba or both, R.sup.3+ is a trivalent metal ion or trivalent Bi or a mixture of these trivalent ions, Eu.sup.2+ is present at a level up to about 5 mol % of M, and R.sup.3+ is present at a level up to about 5 mol % of M. Phosphors of this invention include powders, ceramics, single crystals and single crystal fibers. A method of manufacturing improved phosphors and a method of manufacturing single crystal phosphors are also provided.