Abstract: A method for producing water-soluble azo dyes by utilizes continuous diazotization reaction and continuous coupling reaction in a pipeline reactor. The diazo component, hydrochloric acid and sodium nitrite are simultaneously fed at the bottom of the pipeline reactor at room temperature, to perform a diazotization reaction in the pipeline and leave the diazotization reaction site in time, followed by performing the coupling reaction with the introduced coupled component. Under stirring of micro stirring blades, the materials at each flow layer are uniformly mixed and reacted, and the reaction materials flow upward under the action of a feed driving force and are discharged from the top of the continuous reactor to produce a water-soluble azo dye.

Abstract: Disclosed are a continuous rolling device and method with interfacial temperature-force controllability for a seamless metal cladding pipe. The device comprises a multi-roller skew rolling mill set, an interfacial temperature-force controlled rolling mill set and a sizing and finishing mill set sequentially distributed along a rolling axis; and the interfacial temperature-force controlled rolling mill set comprises an interface temperature control module and an interface pressure control module sequentially distributed along the rolling axis, the interface pressure control module comprises two racks and a plurality of controlled rolling rollers circumferentially and evenly distributed along the rolling axis, two ends of the controlled rolling roller are respectively mounted on the two racks through corresponding screwdown apparatuses, and the interface pressure control module realizes passive driving through a spiral pushing force or a traction force.

Abstract: A double-inverse opal photonic crystal resin film is formed by embedding nanospheres in pores of polyacrylate inverse opal framework material and then filling the pores of the double-inverse opal photonic crystal resin film with an ethanol solution with hydrophilic acrylamide dissolved therein followed by photopolymerization to form a polyacrylamide network, so as to obtain the double-inverse opal photonic crystal resin film using water as ink. A mass fraction of hydrophilic acrylamide in the ethanol solution is 2 to 8 wt.%. The resin film can induce water to penetrate into the pores of the double-inverse opal photonic crystal resin film, making the nanospheres in the pores of the inverse opal framework distribute from random to order under the action of buoyancy force, thereby eliminating scattering interference and producing brilliant structural colors by regulating refractive index contrast.

Abstract: A method for rapidly repairing a road surface includes: forming a base layer reinforcing material by low-shrinkage unsaturated polyester resin, diluent, expansion agent, accelerator, and polymerization inhibitor, adding a curing agent and pouring into a base layer at a damaged part of the road surface until infiltration is stopped; laying chopped basalt fiber, forming a surface layer repair material by acrylate monomer, acrylic resin polymer, silane coupling agent, calcium carbonate powder, talc powder, quartz sand, metal hydroxide flame retardant and accelerator, polymerization inhibitor and short cut basalt fiber; adding curing agent to fill the road surface and solidifying. The repairing method can not only play a reinforcing effect on the road base, but also repair the surface layer on the damaged parts such as cracks on road surface, so as to realize the dual functions of the base layer reinforcement and the surface layer repair.

Abstract: A bilayer photonic crystal photoswitch thin-film device having the optical characteristics of both 2D and 3D photonic crystals, and a preparation method thereof are provided. When the bilayer photonic crystal photoswitch thin-film device is rotated periodically, different colors can be observed at a fixed rotation angle, that is, the device has the attribute of changing colors by means of rotation, and can thus realize the opening and closing of an optical path. The bilayer photonic crystal photoswitch thin-film new device has broad application prospects in the fields of photoswitches, optical waveguides, optical prisms, warming signs, anti-counterfeiting and information coding, etc.