Abstract: Described herein is a method for coating optical fiber where the coating has been cured by application of a source of monochromatic actinic radiation, such as a light emitting diode, wherein the coating contains a urethane(meth)acrylate oligomer; a (meth)acrylate diluent monomer; a diluent monomer having an electron donating group adjacent to the vinyl group, such as a vinyl ether monomer; and a photoinitiator. Also described are compositions which are capable of undergoing photopolymerization when coated on an optical fiber and when irradiated by a light emitting diode (LED) with improved surface cure and reduced yellowing. Also described are the coated optical fibers produced by such processes and compositions.

Abstract: Described herein is a method for coating optical fiber where the coating has been cured by application of a source of monochromatic actinic radiation, such as a light emitting diode, wherein the coating contains a urethane(meth)acrylate oligomer; a (meth)acrylate diluent monomer; a diluent monomer having an electron donating group adjacent to the vinyl group, such as a vinyl ether monomer; and a photoinitiator. Also described are compositions which are capable of undergoing photopolymerization when coated on an optical fiber and when irradiated by a light emitting diode (LED) with improved surface cure and reduced yellowing. Also described are the coated optical fibers produced by such processes and compositions.

Abstract: The invention provides an optical fiber coated with a Supercoating, wherein the Supercoating comprises at least two layers, wherein the first layer is a Primary Coating that is in contact with the outer surface of the optical fiber and the second layer is a Secondary Coating in contact with the outer surface of the Primary Coating, wherein the cured Primary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 84% to about 99%; B) an in-situ modulus of between about 0.15 MPa and about 0.60 MPa; and C) a Tube Tg, of from about ?25° C. to about ?55° C.; wherein the cured Secondary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 80% to about 98%; B) an in-situ modulus of between about 0.60 GPa and about 1.90 GPa; and C) a Tube Tg, of from about 50° C. to about 80° C.

Abstract: A new radiation curable Secondary Coating for optical fibers is described and claimed wherein said composition comprises a Secondary Coating Oligomer Blend, which is mixed with a first diluent monomer; a second diluent monomer; optionally, a third diluent monomer; an antioxidant; a first photoinitiator; a second photoinitiator; and optionally a slip additive or a blend of slip additives; wherein said Secondary Coating Oligomer Blend comprises: ?) an Omega Oligomer; and ?) an Upsilon Oligomer; wherein said Omega Oligomer is synthesized by the reaction of ?1) a hydroxyl-containing (meth)acrylate; ?2) an isocyanate; ?3) a polyether polyol; and ?4) tripropylene glycol; in the presence of ?5) a polymerization inhibitor; and ?6) a catalyst; to yield the Omega Oligomer; wherein said catalyst is selected from the group consisting of dibutyl tin dilaurate; metal carboxylates, including, but not limited to: organobismuth catalysts such as bismuth neodecanoate; zinc neodecanoate; zirconium neodecanoate; zinc 2-ethylh

Abstract: The invention relates to a Radiation Curable Secondary Coating composition for use on an Optical Fiber. The Radiation Curable Secondary Coating composition is a urethane-free Alpha Oligomer prepared by reaction of the following: (a) an acrylate compound selected from an alcohol-containing acrylate or alcohol-containing methacrylate compound, (b) an anhydride compound, (c) an epoxy-containing compound, (d) optionally an extender compound, and (e) optionally a catalyst. The invention also relates to a coated wire and to a coated optical fiber.

Abstract: The first aspect of the instant claimed invention is a method of formulating radiation curable Supercoatings for application to an optical fiber used in a telecommunications network. A Multi-layer Film Drawdown Method useful in the Method of formulating radiation curable Supercoatings is also described and claimed. Single mode Optical fibers coated with specific radiation curable Supercoatings are also described and claimed.

Abstract: The first aspect of the instant claimed invention is a method of formulating radiation curable Supercoatings for application to an optical fiber used in a telecommunications network. A Multi-layer Film Drawdown Method useful in the Method of formulating radiation curable Supercoatings is also described and claimed. Single mode Optical fibers coated with specific radiation curable Supercoatings are also described and claimed.

Abstract: A Radiation Curable Secondary Coating comprising A) a Secondary Coating Oligomer Blend, which is mixed with B) a first diluent; C) a second diluent; D) an antioxidant; E) a first photoinitiator; F) a second photoinitiator; and G) optionally a slip additive or a blend of slip additives; wherein said Secondary Coating Oligomer Blend comprises: ?) an Alpha Oligomer, which is non-urethane; (?) a Beta Oligomer; which is a urethane or non-urethane. ?) a Gamma Oligomer; wherein said Gamma Oligomer is an epoxy diacrylate.

Abstract: A wet-on-dry process for coating a glass optical fiber with a Radiation Curable Secondary Coating, comprising (a) operating a glass drawing tower to produce a glass optical fiber; (b) applying a radiation curable primary coating composition onto the surface of the optical fiber; (c) applying radiation to effect curing of said radiation curable primary coating composition; (d) applying a Radiation Curable Secondary Coating to the radiation curable primary coating; and (e) applying radiation to effect curing of said Radiation Curable Secondary Coating.

Abstract: The invention relates to a Radiation Curable Secondary Coating composition for use on an Optical Fiber. The Radiation Curable Secondary Coating composition is a urethane-free Alpha Oligomer prepared by reaction of the following: (a) an acrylate compound selected from an alcohol-containing acrylate or alcohol-containing methacrylate compound, (b) an anhydride compound, (c) an epoxy-containing compound, (d) optionally an extender compound, and (e) optionally a catalyst. The invention also relates to a coated wire and to a coated optical fiber.

Abstract: The first aspect of the instant claimed invention is a method of formulating radiation curable Supercoatings for application to an optical fiber used in a telecommunications network. A Multi-layer Film Drawdown Method useful in the Method of formulating radiation curable Supercoatings is also described and claimed. Single mode Optical fibers coated with specific radiation curable Supercoatings are also described and claimed.

Abstract: The invention provides an optical fiber coated with a Supercoating, wherein the Supercoating comprises at least two layers, wherein the first layer is a Primary Coating that is in contact with the outer surface of the optical fiber and the second layer is a Secondary Coating in contact with the outer surface of the Primary Coating, wherein the cured Primary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 84% to about 99%; B) an in-situ modulus of between about 0.15 MPa and about 0.60 MPa; and C) a Tube Tg, of from about ?25° C. to about ?55° C.; wherein the cured Secondary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 80% to about 98%; B) an in-situ modulus of between about 0.60 GPa and about 1.90 GPa; and C) a Tube Tg, of from about 50° C. to about 80° C.

Abstract: The invention relates to a Radiation Curable Secondary Coating composition for use on an Optical Fiber. The Radiation Curable Secondary Coating composition is a urethane-free Alpha Oligomer prepared by reaction of the following: (a) an acrylate compound selected from an alcohol-containing acrylate or alcohol-containing methacrylate compound, (b) an anhydride compound, (c) an epoxy-containing compound, (d) optionally an extender compound, and (e) optionally a catalyst. The invention also relates to a coated wire and to a coated optical fiber.

Abstract: The invention provides an optical fiber coated with a Supercoating, wherein the Supercoating comprises at least two layers, wherein the first layer is a Primary Coating that is in contact with the outer surface of the optical fiber and the second layer is a Secondary Coating in contact with the outer surface of the Primary Coating, wherein the cured Primary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 84% to about 99%; B) an in-situ modulus of between about 0.15 MPa and about 0.60 MPa; and C) a Tube Tg, of from about ?25° C. to about ?55° C.; wherein the cured Secondary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 80% to about 98%; B) an in-situ modulus of between about 0.60 GPa and about 1.90 GPa; and C) a Tube Tg, of from about 50° C. to about 80° C.

Abstract: The invention relates to a Radiation Curable Secondary Coating composition for use on an Optical Fiber. The Radiation Curable Secondary Coating composition is a urethane-free Alpha Oligomer prepared by reaction of the following: (a) an acrylate compound selected from an alcohol-containing acrylate or alcohol-containing methacrylate compound, (b) an anhydride compound, (c) an epoxy-containing compound, (d) optionally an extender compound, and (e) optionally a catalyst. The invention also relates to a coated wire and to a coated optical fiber.

Abstract: The first aspect of the instant claimed invention is a method of formulating radiation curable Supercoatings for application to an optical fiber used in a telecommunications network. A Multi-layer Film Drawdown Method useful in the Method of formulating radiation curable Supercoatings is also described and claimed. Single mode Optical fibers coated with specific radiation curable Supercoatings are also described and claimed.

Abstract: The invention relates to a Radiation Curable Secondary Coating composition for use on an Optical Fiber. The Radiation Curable Secondary Coating composition is a urethane-free Alpha Oligomer prepared by reaction of the following: (a) an acrylate compound selected from an alcohol-containing acrylate or alcohol-containing methacrylate compound, (b) an anhydride compound, (c) an epoxy-containing compound, (d) optionally an extender compound, and (e) optionally a catalyst. The invention also relates to a coated wire and to a coated optical fiber.

Abstract: The invention relates to a Radiation Curable Secondary Coating composition for use on an Optical Fiber. The Radiation Curable Secondary Coating composition is a urethane-free Alpha Oligomer prepared by reaction of the following: (a) an acrylate compound selected from an alcohol-containing acrylate or alcohol-containing methacrylate compound, (b) an anhydride compound, (c) an epoxy-containing compound, (d) optionally an extender compound, and (e) optionally a catalyst. The invention also relates to a coated wire and to a coated optical fiber.

Abstract: A Radiation Curable Secondary Coating comprising A) a Secondary Coating Oligomer Blend, which is mixed with B) a first diluent; C) a second diluent; D) an antioxidant; E) a first photoinitiator; F) a second photoinitiator; and G) optionally a slip additive or a blend of slip additives; wherein said Secondary Coating Oligomer Blend comprises: ?) an Alpha Oligomer, which is non-urethane; ?) a Beta Oligomer; which is a urethane or non-urethane. ?) a Gamma Oligomer; wherein said Gamma Oligomer is an epoxy diacrylate.

Abstract: The invention provides an optical fiber coated with a Supercoating, wherein the Supercoating comprises at least two layers, wherein the first layer is a Primary Coating that is in contact with the outer surface of the optical fiber and the second layer is a Secondary Coating in contact with the outer surface of the Primary Coating, wherein the cured Primary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 84% to about 99%; B) an in-situ modulus of between about 0.15 MPa and about 0.60 MPa; and C) a Tube Tg, of from about ?25° C. to about ?55° C.; wherein the cured Secondary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 80% to about 98%; B) an in-situ modulus of between about 0.60 GPa and about 1.90 GPa; and C) a Tube Tg, of from about 50° C. to about 80° C.