Abstract: The invention id directed to an article which contains a solid ion conductor which has a garnet-like crystal structure and has the stoichiometric composition L7+xAxG3?xZr2O12, where L is in each case independently a monovalent cation, A is in each case independently a divalent cation, G is in each case independently a trivalent cation, 0 ?x?3 and O can be partly or completely replaced by divalent or trivalent anion, wherein the article is a battery, an accumulator, a supercap, a fuel cell, sensor, a thermoelectric converter or an electrochromic device.

Abstract: The invention is directed to an electrode which has been coated with the solid ion conductor which has a garnet-like crystal structure and has the stoichiometric composition L7+xAxG3?xZr2O12, wherein L is in each case independently a monovalent cation, A is in each case independently a divalent cation, G is in each case independently a trivalent cation, 0?x?3 and O can be partly or completely replaced by divalent or trivalent anion.

Abstract: The invention is directed to a solid ion conductor which has a garnet-like crystal structure and has the stoichiometric composition L7+xAxG3?xZr2O12, wherein L is in each case independently a monovalent cation, A is in each case independently a divalent cation, G is in each case independently a trivalent cation, 0?x?3 and O can be partly or completely replaced by divalent or trivalent anion.

Abstract: The present invention concerns chemically stable solid lithium ion conductors, processes for their production and their use in batteries, accumulators, supercaps and electrochromic devices.

Abstract: The present invention concerns chemically stable solid lithium ion conductors, processes for their production and their use in batteries, accumulators, supercaps and electrochromic devices.

Abstract: The present invention concerns chemically stable solid lithium ion conductors, processes for their production and their use in batteries, accumulators, supercaps and electrochromic devices.

Abstract: The present invention relates to the use of chemically stable solid ion conductors having a garnet-like structure in batteries, accumulators, electrochromic devices and other electrochemical cells, and also novel compounds which are suitable for these uses.

Abstract: The present invention concerns chemically stable solid lithium ion conductors, processes for their production and their use in batteries, accumulators, supercaps and electrochromic devices.

Abstract: The invention relates to a fuel cell having a moderate operating temperature which comprises a cathode, an anode and an electrolyte, where at least the cathode comprises a material having the composition (Sr1-xCax)1-yAyMn1-zBzO3-? and A is at least one element from the group consisting of Ba, Pb, Na, K, Y and the lanthanide group, B is at least one element from the group consisting of Mg, Al, Ga, In, Sn and sub-group elements from the 4th, 5th or 6th period, and x adopts values of from 0.2 to 0.8, y adopts values of from 0 to 0.4, z adopts values of from 0 to <1, and ? adopts values which arise taking into account the electroneutrality principle.

Abstract: Lithium is isolated from lithium amalgam by electrolysis over a solid lithium ion conductor having the composition Li4−xSi1−xPxO4, where x is at least 0.3 and not more than 0.7.

Abstract: A lithium ion conductor having the composition Li4−xSi1−xPxO4, where x is at least 0.3 and not more than 0.7, is prepared by shaping and calcining Li4−xSi1−xPxO4, where x is at least 0.3 and not more than 0.7, and/or compounds which are converted into this during calcination, wherein the Li4−xSi1−xPxO4 and/or the compounds is/are used in the form of powder having a mean particle size of not more than 5 microns.

Abstract: The invention relates to a fuel cell having a moderate operating temperature which comprises a cathode, an anode and an electrolyte, where at least the cathode comprises a material having the composition (Sr1-xCax)1-yAyMn1-zBzO3-&dgr; and

Abstract: The present invention provides a process for the production of a K- or Rb-.beta."- or -.beta.-aluminum oxide powder preparation, wherein a cubic densely packed aluminum oxide (.gamma.-aluminum oxide) or a precursor thereof is subjected to attrition together with a doping material or a precursor thereof, the so obtained mixture is calcined in an oxygen-containing atmosphere, potassium oxide or rubidium oxide or a precursor of these compounds is added to the calcination product obtained, the mixture is subjected to attrition and then calcined in an oxygen-containing atmosphere at a temperature greater than 900.degree. C. The present invention also provides a process for the production of a ceramic formed body in which a powder obtained by the above process is converted by attrition, isostatic pressing and sintering into a ceramic formed body. Such a ceramic formed body can be used as an ion conductor.

Abstract: The invention concerns as amperometric gas sensor for the selective deteration with high accuracy of a gas partial pressures. Such a gas sensor includes a solid electrolyte and inert electrodes. The solid electrolyte, contained in the sensor, is selected in such a way that when an electrical current or voltage is applied, ions contained in the electrolyte form a reaction product with the gas to be determined in a secondary equilibrium reaction and with generation of an electrically measurable signal. Preferred solid electrolytes are Na.sup.+ -.beta." aluminum oxide, NASICON, cubic stabilized zirconium oxide and polycrystals of tetragonal zirconium oxide. A method for the selective determination of gases using such electrodes also is described. Preferably an electrical current or voltage source shall be used which feeds a periodic, especially a sawtooth or sinusoidal signal, to the solid electrolyte, as a result of which the formed reaction product is decomposed to the same extent it was previously built up.

Abstract: An electrochromic system. It comprises layers of solid/materials deposited on glass or another substrate. The solids function in an atmosphere that can be dry. One layer is preferably Li.sub.3 AlF.sub.6 and conducts positive lithium ions. Another layer is a counterelectrode. The counterelectrode is improved to the extent that it can reversibly accept ions from and donate them to the ion conductor while remaining extensively transparent. The counterelectrode can be Li.sub.x TiO.sub.y, (Li.sub.2 O).sub.m (WO.sub.3).sub.n (Sb.sub.2 O.sub.3), or (Li.sub.2 O).sub.m (WO.sub.3).sub.n (CeO.sub.2).sub.o.

Abstract: The present invention provides an electrochromic device which is especially suitable as a window, mirror or display element, characterized by a multi-layer construction with at least one layer, enclosed between two coated electrodes, of a material which is either ionically- or mixed ionically- and electronically-conductive, whereby at least one of the two electrode layers consists of transparent material and the ionically- or ionically- and electronically-conductive material is at least so long transparent as no excitation takes place by the application of voltage via the electrodes.

Abstract: A solid electrode in an electrolytic cell for rapid incorporation and exclusion of ions wandering to and from the electrode by way of an electrolyte with a minimum of voltage loss, in particular for a fuel cell, a high-performance battery, an electrochrome sign display unit or an electro-chemical storage element. The electrode comprises a structure having a higher electrical conductivity for electrons or holes than for the ions, and wherein the concentration of the electrons or holes movable within said electrode is lower than the concentration of the ions movable within the electrode.

Abstract: The present invention provides a mixed conducting body, wherein it consists f 98 to 25 mol % of cubic or tetragonal zirconium dioxide, 1.5 to 25 mol % of an oxide stabilizing the zirconium dioxide phase and 0.5 to 50 mol % of at least one oxide of a metal of Group Va and VIa of the Periodic System of Elements and/or titanium dioxide, as well as the usual impurities.This body is outstandingly useful as electrode material for oxygen exchange reactions.

Abstract: A sensor for measuring partial pressures of oxygen with an ion-conducting lid electrolyte of zirconium dioxide as the sensor element, which is arranged between two electrodes for measuring an electrically measurable quantity, is improved so that it is usable at an operating temperature of about 200.degree. C., by providing that the zirconium dioxide as the solid electrolyte is solely in its tetragonal modification and containing an addition of about 2-3 mol % yttrium oxide.

Abstract: A solid state cell for measuring the activity of a component of a mixture using a solid ionic conductor, which is in contact on one side with a reference phase and on the other side with a phase sensitive to the gas component to be determined, is to be improved in such a manner that its detection sensitivity and measuring stability are increased. For this purpose, the gas sensitive phase contains an addition of a substance that increases the electronic conductivity and does not chemically react with the components of the sensitive phase and the gas to be determined.