Abstract: Thermal barrier coatings consist of a tantala-zirconia mixture that is stabilized with two or more stabilizers. An exemplary thermal barrier coating consists of, by mole percent: about 8% to about 30% YO1.5; about 8% to about 30% YbO1.5 or GdO1.5 or combination thereof; about 8% to about 30% TaO2.5; about 0% to about 10% HfO2; and a balance of ZrO2.

Abstract: Thermal barrier coatings, which may be used in gas turbine engines, comprise or consist of a tantala-niobia-zirconia mixture that is stabilized with two or more stabilizers. An exemplary thermal barrier coating comprises or consists of, by mole percent: about 2% to about 30% YO1.5; about 8% to about 30% YbO1.5 or GdO1.5 or combination thereof; about 6% to about 30% TaO2.5; about 0.1% to about 10% NbO2.5; about 0% to about 10% HfO2; and a balance of ZrO2.

Abstract: Thermal barrier coatings, which may be used in gas turbine engines, comprise or consist of a tantala-niobia-zirconia mixture that is stabilized with two or more stabilizers. An exemplary thermal barrier coating comprises or consists of, by mole percent: about 2% to about 30% YO1.5; about 8% to about 30% YbO1.5 or GdO1.5 or combination thereof; about 6% to about 30% TaO2.5; about 0.1% to about 10% NbO2.5; about 0% to about 10% HfO2; and a balance of ZrO2.

Abstract: A turbine engine, an engine structure, and a method of forming an engine structure are provided herein. In an embodiment, an engine structure includes a metal substrate, a thermal barrier coating layer, and a metal silicate protective layer. The thermal barrier coating layer overlies the metal substrate, and the thermal barrier coating layer has columnar grains with gaps defined between the columnar grains. The metal silicate protective layer is formed over the thermal barrier coating layer, and the metal silicate protective layer covers the columnar grains and the gaps between the columnar grains.

Abstract: A ceramic composition of matter includes a solvent material and a solute material. The solvent material comprises zirconia or hafnia, or a mixture thereof, which is stabilized with a stabilizing oxide. The solute material comprises a metal oxide of the formula, XaOb, where X is a metallic element, O is oxygen, and “a” and “b” are stoichiometric coefficients. The difference in density between the solvent material and the solute material is less than about 30%.

Abstract: Thermal barrier coatings consist of a tantala-zirconia mixture that is stabilized with two or more stabilizers. An exemplary thermal barrier coating consists of, by mole percent: about 8% to about 30% YO1.5; about 8% to about 30% YbO1.5 or GdO1.5 or combination thereof; about 8% to about 30% TaO2.5; about 0% to about 10% HfO2; and a balance of ZrO2.

Abstract: A turbine engine, an engine structure, and a method of forming an engine structure are provided herein. In an embodiment, an engine structure includes a metal substrate, a thermal barrier coating layer, and a metal silicate protective layer. The thermal barrier coating layer overlies the metal substrate, and the thermal barrier coating layer has columnar grains with gaps defined between the columnar grains. The metal silicate protective layer is formed over the thermal barrier coating layer, and the metal silicate protective layer covers the columnar grains and the gaps between the columnar grains.

Abstract: Embodiments of a method are provided for fabricating a high temperature castable article, such as a casting mold or a core. In one embodiment, the method includes the steps of providing a suspension containing a plurality of ceramic particles and a photo-curable monomer; photo-curing selected portions of the suspension to produce a green body coated, at least partially, with uncured suspension; and removing the uncured suspension from the green body under process conditions at which the viscosity of the uncured suspension is reduced. The process conditions include exposing the green body to one of the group consisting of: (i) microwave energy sufficient to excite a dipole moment of the uncured suspension and (ii) sonic energy sufficient to induce shear-thinning of the uncured suspension. The green body is then heat treated to produce the high temperature castable article.