Abstract: A process can be used for preparing silicone (meth)acrylates, according to which at least one acetoxysilicone is reacted with at least one hydroxyfunctional (meth)acrylic acid ester. The corresponding silicone (meth)acrylates are useful, and can be used in curable compositions.

Abstract: The invention relates to a method for the degradation of epoxy hybrid resin which contains at least one chemically incorporated siloxane, wherein the at least one siloxane chemically incorporated in the epoxy hybrid resin is chemically incorporated into the epoxy hybrid resin via at least two SiC bonds, and wherein the silicon fraction, expressed in percent by mass of silicon, based on the total epoxy hybrid resin is 1.5 percent by mass?silicon fraction?10 percent by mass, wherein the epoxy hybrid resin is contacted with a mixture of at least one alkali metal alkoxide and at least one alcohol.

Abstract: A process can be used for increasing the molecular weight of low molecular weight ?,?-polysiloxanediols. The process involves heating the low molecular weight ?,?-polysiloxanediols in the presence of acetic anhydride at temperatures of 80° C. to 220° C., preferably at temperatures of 100 to 200° C., and particularly preferably at temperatures of 120-180° C., for 1 h to 24 h, preferably for 2 h to 16 h, and particularly preferably for 3 h to 12 h. The molar amount of the silanol groups used is greater than that of the acetic anhydride used.

Abstract: A process prepares unbranched hydrosiloxanes bearing dimethylhydrosiloxy groups by providing of a siloxane mixture having at least two different siloxanes and allowing the siloxane mixture to react in the presence of a sulfonic acid ion exchange resin in an equilibration reaction to form a reaction mixture, wherein the siloxanes used collectively have dimethylhydrosiloxy groups, methylhydrosiloxy groups, dimethylsiloxy groups and preferably trimethylsiloxy groups, and wherein the reaction mixture is monitored by ultrasound measurement in order to ascertain the suitable juncture for ending of the equilibration reaction, and the equilibration reaction is ended once the juncture ascertained has been reached.

Abstract: The invention relates to a process for preparing acid-free hydrosiloxane equilibrates. A mixture is contacted with a macrocrosslinked water-containing cation exchange resin that contains sulfonic acid groups and left to react with rearrangement of the SiOSi bonds until the acid-free hydrosiloxane equilibrate produced in this way, in a metal-catalysed hydrosilylating addition onto at least one unsaturated polyether affords an addition product that is clear at T=25° C. The rearrangement of the SiOSi bonds is implemented in the temperature range from 10 to 50° C. The cation exchange resin is characterized in that the product P of the specific surface area thereof and the average pore diameter thereof is P?2.2×10?3 m3/kg and the specific surface area A is ?35 m2/g, and in that it additionally has a water.

Abstract: Curable condensation compounds are obtainable by a reaction of non-end-equilibrated acetoxy group-bearing siloxanes with at least one alkoxy-functional polysiloxane, in the presence of a catalyst.

Abstract: A process prepares hydrosiloxanes using acid-modified aluminium silicate as equilibration catalyst, where pulverulent aluminium silicate is applied, with mixing, to a siloxane mixture that consists of at least two siloxanes and at least one SiH-functional siloxane. The acid-modified aluminium silicate is prepared in situ with addition of acid, and the resulting reaction mixture is allowed to react with further mixing in the sense of an equilibration.

Abstract: Process for producing PU foams by reacting at least one polyol component with at least one isocyanate component in the presence of one or more catalysts that catalyse the isocyanate-polyol and/or isocyanate-water and/or isocyanate trimerization reactions, and optionally one or more chemical or physical blowing agents, with use of SiOC-linked, linear polydialkylsiloxane-polyoxyalkylene block copolymers having repeat (AB) units, obtainable through the reaction of polyether diols with equilibrated ?,?-diacetoxypolydialkylsiloxanes, wherein a sufficient amount of the SiOC-linked, linear polydialkylsiloxane-polyoxyalkylene block copolymers having repeat (AB) units is added such that the proportion by mass of said component based on the finished PU foam is from 0.0001% to 10% by weight, preferably 0.01% to 6% by weight, especially 0.05% to 5% by weight.

Abstract: A method for the physical reutilization of siliconized papers includes at least a first step (a), treating at least one siliconized paper by contacting it with at least one alcohol and at least one alkali metal alkoxide with introduction of heat, and without removing from the reaction mixture any water that occurs, and then, a second step (b), removing the at least one desiliconized paper resulting from the first step (a) from the optionally previously neutralized reaction mixture.

Abstract: Curable condensation compounds are useful, obtainable by the reaction of end-equilibrated acetoxy group-bearing siloxanes with at least one alkoxy-functional polysiloxane, in the presence of a catalyst.

Abstract: The present invention provides a process for depolymerizing waste silicones to afford siloxane cycles, wherein the process comprises a first step of reacting the waste silicone with at least one alcohol and at least one alkali metal alkoxide without removing any potentially occurring water from the reaction mixture, subsequently neutralizing the reaction mixture, removing the solid constituents and then distillatively removing the optionally previously added solvent and excess alcohol and subsequently heating the obtained alkoxysiloxane with at least one fatty alcohol and at least one alkali metal alkoxide with mixing and distillatively removing the siloxane cycles formed.

Abstract: Process for producing endcapped, liquid siloxanes having chain lengths of greater than 3 silicon atoms from end-of-life silicones, especially from silicone elastomers and/or silicone rubbers, by acid-catalysed depolymerization thereof in a solvent-free reaction system comprising at least one compound providing end groups MR, at least one compound providing D units, and at least one Brønsted acid.

Abstract: The production of SiOC-bonded, linear polydimethylsiloxane-polyoxyalkylene block copolymers comprising repeating (AB) units by reaction of polyether diols with trifluoromethanesulfonic acid-acidified, equilibrated ?,?-diacetoxypolydimethylsiloxanes is described, wherein the reaction is undertaken by adding a solid, liquid or gaseous base, optionally using inert solvents.

Abstract: Processes may produce alkoxysiloxane(s) by reaction of siloxane parent structure(s) with alkali metal alkoxide(s). Such processes may include reacting siloxane parent structure(s) by mixing with alkali metal alkoxide(s) with heating and optionally adding silicon dioxide, but without adding alcohol and without removal of any potentially occurring water from the reaction mixture; and neutralizing the resulting reaction mixture by adding Brønsted acid(s), optionally solvent(s), and preferably separating solid constituents; and subsequently isolating the alkoxysiloxane(s) by thermally separating volatile compounds. The siloxane parent structure(s) may be a hexamethylcyclotrisiloxane (D3), octamethylcyclotetrasiloxane (D4), decamethylcyclopentasiloxane (D5), dodecamethylcyclohexasiloxane (D6), mixture of cyclic branched D/T type siloxanes, silicone oils preferably including at least 100 D units, polydimethylsiloxanediol(s), and/or ?,?-divinylsiloxane(s).

Abstract: A process for producing one or more alkoxysiloxanes by thermal reaction of at least one siloxane parent structure with at least one alkali metal alkoxide and at least one alcohol, where the process includes mixing, while heating, the at least one siloxane parent structure with the at least includes one alcohol and the at least one alkali metal alkoxide to form a reaction mixture, neutralizing the reaction mixture by addition of at least one Brønsted acid and optionally with addition of at least one solvent, and subsequently isolating the one or more alkoxysiloxanes by thermal separation of volatile compounds. Potentially occurring water is not removed from the reaction mixture and the reaction mixture does not include solvents which form an azeotrope with water and/or further dehydrating agents.

Abstract: A process for producing alkoxysiloxanes by thermal reaction of at least one waste silicone with at least one alkali metal alkoxide and at least one alcohol. The process includes a first step of reacting the at least one waste silicone by mixing with at least one alcohol and at least one alkali metal alkoxide with heating, but without removing any potentially occurring water from the reaction mixture, and a second step of neutralizing the reaction mixture resulting from this reaction using at least one Brønsted acid and separating the solid constituents, and subsequently isolating the alkoxysiloxane by thermal separation of volatile compounds.

Abstract: Process for producing SiOC-bonded, linear polydimethylsiloxane-polyoxyalkylene block copolymers comprising repeating (AB) units, comprising pretreating acidified, end-equilibrated ?,?-diacetoxypolydimethylsiloxanes with a base and reacting the ?,?-diacetoxypolydimethylsiloxanes resulting therefrom with polyether diols in the presence of a solid, liquid or gaseous base, optionally using inert solvents.

Abstract: The invention describes (i) reaction systems for the production of siloxanes bearing acetoxy functions, comprising a) silanes and/or siloxanes bearing alkoxy groups and/or b) silanes and/or siloxanes bearing acetoxy groups, c) silanes and/or siloxanes bearing hydroxy groups, d) optionally simple siloxane cycles and/or DT cycles, e) a reaction medium, comprising acetic anhydride, perfluoroalkanesulfonic acid and preferably acetic acid, (ii) a process for producing linear or branched siloxanes bearing acetoxy functions and also the use of same for producing polyethersiloxanes.

Abstract: Described is a process for producing SiOC-bonded polyether siloxanes branched in the siloxane portion from cyclic branched siloxanes of the D/T type, wherein said process comprises in a first step reacting the mixtures of cyclic branched siloxanes of the D/T type with acetic anhydride optionally in admixture with simple siloxane cycles under acid catalysis to afford acetoxy-bearing branched siloxanes, in a second step performing the equilibration of the acetoxy-modified branched siloxane with superacid, preferably with addition of acetic acid and in a third step reacting the superacid-treated acetoxysiloxane with polyetherols optionally in the presence of bases and optionally in the presence of an inert solvent.

Abstract: Upcycling process for producing acidic, end-equilibrated siloxanes bearing acetoxy groups and having chain lengths of greater than 3 silicon atoms from end-of-life silicones by thermal digestion in an acidic reaction medium comprising acetic anhydride, acetic acid and at least one further Brønsted acid having a pKa of <4, the digestion taking place in a reactor having a volume of at least 1 liter.