Patents by Inventor Wilfried Toltsch
Wilfried Toltsch has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 9932469Abstract: A heterophasic propylene ethylene copolymer having an MFR2 of 0.5 to 100 g/10 m in and obtained using single site catalysis comprising: (i) a propylene homopolymer or propylene ethylene copolymer matrix having up to 4 wt % ethylene; and (ii) an ethylene propylene rubber (EPR) dispersed in the matrix; said heterophasic propylene ethylene copolymer having a xylene cold soluble content (XS) of 20 to 40%; wherein the ethylene content of the xylene cold soluble fraction of said heterophasic propylene ethylene copolymer is between 70 and 90 wt. %; wherein the xylene cold soluble fraction of said heterophasic propylene ethylene copolymer has an intrinsic viscosity (IV) of 3.0 dl/g or more; and wherein the melting enthalpy (?HM) of the heterophasic propylene ethylene copolymer is between 10 and 30 J/g at a temperature of 0 to 130° C.Type: GrantFiled: January 6, 2015Date of Patent: April 3, 2018Assignee: Borealis, AGInventors: Jingbo Wang, Petar Doshev, Luigi Resconi, Wilfried Toltsch
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Publication number: 20170335035Abstract: The present invention relates to an olefin polymerization process, wherein propylene and 1-butene and optionally ethylene are reacted in the presence of a Ziegler-Natta catalyst system so as to obtain a polypropylene, wherein the polypropylene comprises 1-butene-derived comonomer units in an amount of from 0.5 to 15 wt % and optionally ethylene-derived comonomer units in an amount of up to 3 wt %, and the Ziegler-Natta catalyst system comprises an external donor of the formula (I) (R3)z(R2O)YSi(R1)X??(I).Type: ApplicationFiled: December 28, 2015Publication date: November 23, 2017Inventors: Wilfried TOLTSCH, Luigi RESCONI
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Publication number: 20170247484Abstract: A process for the preparation of a hetero-phasic copolymer of propylene and ethylene comprising polymerising propylene and ethylene in the gas phase in the presence of a solid particulate catalyst free from an external carrier comprising: (i) a symmetrical complex of formula (I), wherein M is zirconium or hafnium; each X is a sigma lig- and; L is a divalent bridge selected from —R?2C—, —R?2C—CR?2-, —R?2Si—, —R?2Si—SiR?2—, —R?2Ge—, wherein each R? is independently a hydrogen atom, C1-C20-alkyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; R2 is a C1-C20 hydrocarbyl radical; R5 is a C1-C20 hydrocarbyl radical; R6 is a tertiary C4-C20 hydrocarbyl radical; R7 is a hydrogen atom or a C1-10-hydrocarbyl radical; n is 0 to 3; R1 is a C1-C20 hydrocarbyl radical and optionally two adjacent R1 groups taken together can form a further mono or multi-cyclic ring condensed to Ph ring optionally substituted by one or two groups R4; and R4 is a C1-C10 alkyl radical and (ii) a cocatalyst, preferabType: ApplicationFiled: September 11, 2015Publication date: August 31, 2017Applicant: BOREALIS AGInventors: Luigi RESCONI, Norbert HAFNER, Wilfried TÖLTSCH
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Publication number: 20170247480Abstract: A process for the preparation of a copolymer of propylene and ethylene comprising polymerising propylene and ethylene in the gas phase in the presence of a solid particulate catalyst free from an external carrier comprising: (i) a symmetrical complex of formula (I), wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from —R?2C—, —R?2C—CR?2—, —R?2Si—, —R?2Si—SiR?2—, —R?2Ge—, wherein each R? is independently a hydrogen atom, C1-C20-alkyi, tri(C1-C20-aikyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; R2 is a C1-C20 hydrocarbyl radical; m is 2 to 5; R9 is a H or C1-C20 hydrocarbyl radical; R7 is a hydrogen atom or a C1-10-hydrocarbyl radical; n is 0 to 3; R1 is a C1-C20 hydrocarbyl radical and optionally two adjacent R1 groups taken together can form a further mono or multicyclic ring condensed to Ph ring optionally substituted by one or two groups R4; and R4 is a C1-C10 alkyl radical; and (ii) a cocatalyst, preferably comprising an organometallic compound ofType: ApplicationFiled: September 11, 2015Publication date: August 31, 2017Applicant: BOREALIS AGInventors: Luigi RESCONI, Wilfried TÖLTSCH, Jingbo WANG
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Patent number: 9701772Abstract: A process for the preparation of a propylene copolymer, preferably a heterophasic propylene copolymer, in a multistage polymerisation process in the presence of a single site catalyst, said process comprising: (I) in a slurry polymerisation step, polymerising propylene and optionally at least one C2-10 alpha olefin comonomer; and subsequently (II) in a gas polymerisation step polymerising propylene and optionally at least one C2-10 alpha olefin comonomer, in the presence of catalyst and polymer from step (I); (III) in a second gas polymerisation step, polymerising propylene and at least one C2-10 alpha olefin comonomer in the presence of the catalyst and polymer from step (II); wherein said catalyst comprises (i) a metallocene complex of a group (IV) metal, said metallocene comprising at least two cyclopentadienyl type ligands; (ii) a boron based cocatalyst; and (iii) an aluminoxane cocatalyst; said catalyst being in solid form, preferably in solid particulate form, and being free from an external carrier.Type: GrantFiled: July 22, 2014Date of Patent: July 11, 2017Assignee: BOREALIS AGInventors: Luigi Resconi, Wilfried Töltsch, Wang Jingbo
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Patent number: 9670347Abstract: Polypropylene composition comprising comonomer units derived from ethylene in an amount of from 9.0 to 52.0 mol-% and comonomer units derived from a higher a-olefin in an amount of from 0.4 to 3.0 mol-%, wherein said polypropylene composition has an amount of xylene cold solubles of at least 30 wt.-%, wherein further the xylene cold soluble fraction has an ethylene content of from 20.0 to 80.0 mol-% and a higher a-olefin content from 0.1 to 1.5 mol-%.Type: GrantFiled: July 14, 2014Date of Patent: June 6, 2017Assignee: BOREALIS AGInventors: Wilfried Töltsch, Luigi Resconi, Kristin Reichelt
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Publication number: 20160333175Abstract: A heterophasic propylene ethylene copolymer having an MFR2 of 0.5 to 100 g/10m in and obtained using single site catalysis comprising: (i) a propylene homopolymer or propylene ethylene copolymer matrix having up to 4 wt % ethylene; and (ii) an ethylene propylene rubber (EPR) dispersed in the matrix; said heterophasic propylene ethylene copolymer having a xylene cold soluble content (XS) of 20 to 40%; wherein the ethylene content of the xylene cold soluble fraction of said heterophasic propylene ethylene copolymer is between 70 and 90 wt.%; wherein the xylene cold soluble fraction of said heterophasic propylene ethylene copolymer has an intrinsic viscosity (IV) of 3.0 dl/g or more; and wherein the melting enthalpy (AHM) of the heterophasic propylene ethylene copolymer is between 10 and 30 J/g at a temperature of 0 to 130° C.Type: ApplicationFiled: January 6, 2015Publication date: November 17, 2016Applicant: BOREALIS AGInventors: Jingbo WANG, Petar DOSHEV, Luigi RESCONI, Wilfried TOLTSCH
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Publication number: 20160311951Abstract: The present invention relates to an olefm polymerization process, wherein propylene and 1-butene and optionally ethylene are reacted in the presence of a Ziegler-Natta catalyst system so as to obtain a polypropylene, wherein the polypropylene comprises 1-butene-derived comonomer units in an amount of from 5 to 20 wt % and optionally ethylene-derived comonomer units in an amount of up to 3 wt %, and the Ziegler-Natta catalyst system comprises an external donor of the following formula (I): (R3)z(R2O)ySi(R1)x.Type: ApplicationFiled: January 12, 2015Publication date: October 27, 2016Applicant: Borealis AGInventors: Kristin REICHELT, Wilfried TÖLTSCH, Luigi RESCONI
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Publication number: 20160280899Abstract: Polypropylene composition comprising comonomer units derived from ethylene in an amount of from 9.0 to 52.0 mol-% and comonomer units derived from a higher a-olefin in an amount of from 0.4 to 3.0 mol-%, wherein said polypropylene composition has an amount of xylene cold solubles of at least 30 wt.-%, wherein further the xylene cold soluble fraction has an ethylene content of from 20.0 to 80.0 mol-% and a higher a-olefin content from 0.1 to 1.5 mol-%.Type: ApplicationFiled: July 14, 2014Publication date: September 29, 2016Applicant: BOREALIS AGInventors: Wilfried TÖLTSCH, Luigi RESCONI, Kristin REICHELT
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Publication number: 20160176997Abstract: A process for the preparation of a propylene copolymer, preferably a heterophasic propylene copolymer, in a multistage polymerisation process in the presence of a single site catalyst, said process comprising: (I) in a slurry polymerisation step, polymerising propylene and optionally at least one C2-10 alpha olefin comonomer; and subsequently (II) in a gas polymerisation step polymerising propylene and optionally at least one C2-10 alpha olefin comonomer, in the presence of catalyst and polymer from step (I); (III) in a second gas polymerisation step, polymerising propylene and at least one C2-10 alpha olefin comonomer in the presence of the catalyst and polymer from step (II); wherein said catalyst comprises (i) a metallocene complex of a group (IV) metal, said metallocene comprising at least two cyclopentadienyl type ligands; (ii) a boron based cocatalyst; and (iii) an aluminoxane cocatalyst; said catalyst being in solid form, preferably in solid particulate form, and being free from an external carrier.Type: ApplicationFiled: July 22, 2014Publication date: June 23, 2016Applicant: BOREALIS AGInventors: Luigi Resconi, Wilfried Töltsch, Wang Jingbo
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Publication number: 20160168285Abstract: A process for the preparation of a propylene homopolymer in a multistage polymerisation process in the presence of a single site catalyst, said process comprising: (I) in a slurry polymerisation step, polymerising propylene in the presence of said single site catalyst; and subsequently (II) in a gas polymerisation step polymerising propylene in the presence of catalyst and polymer from step (I) so as to form a propylene homopolymer; wherein said catalyst comprises (i) a metallocene complex of a Group 4 metal, said metallocene comprising at least two cyclopentadienyl type ligands; (ii) a boron based cocatalyst; and (iii) an aluminoxane cocatalyst; said catalyst being in solid form, preferably in solid particulate form, and being free from an external carrier.Type: ApplicationFiled: July 22, 2014Publication date: June 16, 2016Applicant: BOREALIS AGInventors: Luigi Resconi, Wilfried Töltsch, Noureddine Ajellal, Ville Virkkunen, Ismo Lehtiniemi
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Publication number: 20160152810Abstract: A heterophasic propylene ethylene copolymer having an MFR2 of 0.5 to 100 g/10 min and obtained using single site catalysis comprising: (i) at least 40 wt % of a propylene homopolymer or propylene ethylene copolymer matrix having up to 4 wt % comonomer; (ii) at least 10 wt % of an ethylene propylene rubber dispersed in the matrix, said heterophasic propylene ethylene copolymer having a xylene cold soluble content (XS) of 12 to 60%; wherein the ethylene content of the xylene cold soluble fraction of said heterophasic propylene ethylene copolymer is between 18 and 70 wt. %; and wherein the intrinsic viscosity of the XS fraction of said heterophasic propylene ethylene copolymer is greater than the intrinsic viscosity of the matrix fraction of said copolymer.Type: ApplicationFiled: July 10, 2014Publication date: June 2, 2016Applicant: BOREALIS AGInventors: Luigi RESCONI, Wilfried TOLTSCH, Jingbo WANG, Markus GAHLEITNER
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Publication number: 20140079899Abstract: Propylene copolymer a. comprising at least 1-hexene as a comonomer, b. having a comonomer content in the range of 1.0 to 3.0 wt.-%, c. having a xylene soluble fraction equal or below 2.5 wt.-%, and d. being partially crystallized in the ?-modification.Type: ApplicationFiled: November 20, 2013Publication date: March 20, 2014Applicant: Borealis AGInventors: Klaus Bernreitner, Manfred Stadlbauer, Norbert Hafner, Wilfried Töltsch, Pirjo Jääskeläinen
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Patent number: 8637625Abstract: Propylene copolymer (a) comprising at least 1-butene as a comonomer, (b) having a comonomer content in the range of 1.0 to 3.0 wt.-%, (c) having a xylene soluble fraction equal or below 2.5 wt.-%, and (d) being partially crystallized in the ?-modification.Type: GrantFiled: November 16, 2009Date of Patent: January 28, 2014Assignee: Borealis AGInventors: Klaus Bernreitner, Manfred Stadlbauer, Norbert Hafner, Wilfried Töltsch
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Patent number: 8367174Abstract: Propylene copolymer a. comprising at least 1-hexene as a comonomer, b. having a comonomer content in the range of 1.0 to 3.0 wt.-%, c. having a xylene soluble fraction equal or below 2.5 wt.-%, d. having a polydispersity index (PI) of equal or below 4.0 Pa?1, and e. being partially crystallized in the ?-modification.Type: GrantFiled: November 16, 2009Date of Patent: February 5, 2013Assignee: Borealis AGInventors: Klaus Bernreitner, Manfred Stadlbauer, Norbert Hafner, Wilfried Töltsch
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Publication number: 20110315264Abstract: Propylene copolymer a. comprising at least 1-hexene as a comonomer, b. having a comonomer content in the range of 1.0 to 3.0 wt.-%, c. having a xylene soluble fraction equal or below 2.5 wt.-%, d. having a polydispersity index (PI) of equal or below 4.0 Pa?1, and e. being partially crystallized in the ?-modification.Type: ApplicationFiled: November 16, 2009Publication date: December 29, 2011Inventors: Klaus Bernreitner, Manfred Stadlbauer, Norbert Hafner, Wilfried Töltsch
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Publication number: 20110293867Abstract: Propylene copolymer (a) comprising at least 1-butene as a comonomer, (b) having a comonomer content in the range of 1.0 to 3.0 wt.-%, (c) having a xylene soluble fraction equal or below 2.5 wt.-%, and (d) being partially crystallized in the ?-modification.Type: ApplicationFiled: November 16, 2009Publication date: December 1, 2011Applicant: Borealis AGInventors: Klaus Bernreitner, Manfred Stadlbauer, Norbert Hafner, Wilfried Töltsch
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Publication number: 20110104416Abstract: Propylene copolymer a. comprising at least 1-hexene as a comonomer, b. having a comonomer content in the range of 1.0 to 3.0 wt.-%, c. having a xylene soluble fraction equal or below 2.5 wt.-%, and d. being partially crystallized in the ?-modification.Type: ApplicationFiled: May 20, 2009Publication date: May 5, 2011Applicant: Borealis AGInventors: Klaus Bernreitner, Manfred Stadlbauer, Norbert Hafner, Wilfried Töltsch, Pirjo Jääskeläinen
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Patent number: 7579422Abstract: The present invention relates to a process for preparing a propylene random copolymer comprising polymerization of propylene with a comonomer, said comonomer being ethylene or an ?-olefin comprising at least four carbon atoms, in the presence of a catalyst in a multistage process comprising polymerization of propylene with a comonomer in a first reaction zone including at least one slurry reactor to give a first polymerization product, transferring said first product to a second reaction zone including at least one gas phase reactor and polymerisations of propylene with a comonomer in said gas phase reactor in the presence of said first polymerization product, wherein the temperature in the gas phase reactor is at least 10° C. higher than in the slurry reactor and to a polymer obtainable by this process.Type: GrantFiled: August 9, 2007Date of Patent: August 25, 2009Assignee: Borealis Technology OyInventors: Pirjo Jaaskelainen, Norbert Hafner, Paivi Pitkanen, Markus Gahleitner, Olli Tuominen, Wilfried Toltsch
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Patent number: 7470756Abstract: The present invention relates to a process for preparing a propylene random copolymer comprising polymerisation of propylene with a comonomer, said comonomer being ethylene or an ?-olefin comprising at least four carbon atoms, in the presence of a catalyst in a muiltistage process comprising polymerisation of propylene with a comonomer in a first reaction zone including at least one slurry reactor to give a first polymerisation product, transferring said first product to a second reaction zone including at least one gas phase reactor and polymerisations of propylene with a comonomer in said gas phase reactor in the presence of said first polymerisation product, wherein the temperature in the gas phase reactor is at least 10° C. higher than in the slurry reactor and to a polymer obtainable by this process.Type: GrantFiled: June 26, 2002Date of Patent: December 30, 2008Assignee: Borealis Technology OyInventors: Pirjo Jääskeläinen, Norbert Hafner, Päivi Pitkänen, Markus Gahleitner, Olli Tuominen, Wilfried Töltsch