Patents by Inventor Willard H. Sawyer

Willard H. Sawyer has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4016106
    Abstract: A process for the formation of a catalyst of predetermined pore size distribution and pore volume from an alumina hydrogel formed and obtained by precipitation from a solution containing a hydrous form of alumina in 1-5 wt. % concentration and an anion that is soluble in an alkaline solution and forms an aluminum salt, at pH 8-12, and temperature ranging about 15.degree. F.-120.degree. F., and then extended by contact with a water-soluble polymer containing from 2 to about 24 monomer units from the group consisting of (a) polyethylene glycols, (b) polypropylene glycols, and (c) polyethylene amines sufficient to absorb the polymer and displace water from the pores until the weight ratio of polymer:alumina ranges about 0.5:1 to about 4:1.
    Type: Grant
    Filed: January 5, 1976
    Date of Patent: April 5, 1977
    Assignee: Exxon Research and Engineering Company
    Inventors: Willard H. Sawyer, Michael T. Duncan
  • Patent number: 3998722
    Abstract: A hydrotreating process, particularly a hydroconversion process, wherein a hydrogenation catalyst is contacted with a hydrocarbon or hydrocarbonaceous feed containing 1050.degree. F.+ materials at a preselected high initial temperature and maintained essentially at this temperature throughout an operating run. In accordance with such mode of operation certain advantages are obtained, these including: (1) greater overall conversion of 1050.degree. F.+ to 1050.degree. F.- hydrocarbon products at a given level of hydrodesulfurization, catalyst consumption rate, with the same reactor volume and pressure requirements; (2) greater overall reduction of Con carbon; and (3) improved overall feed metals reduction.
    Type: Grant
    Filed: December 31, 1975
    Date of Patent: December 21, 1976
    Inventors: Francis X. Mayer, James H. Taylor, Jr., David E. Mueller, Willard H. Sawyer
  • Patent number: 3993601
    Abstract: This invention relates to novel catalysts, of two distinct types, useful for the catalytic hydroconversion of the 1050.degree. F.+ hydrocarbon material contained in heavy crudes and residua such that the resulting product will be suitable for further processing in conventional refinery operations allowing maximization of clean liquid products. Catalysts, which include Group VIB and Group VIII metals, preferably in admixture, and preferably including a Group IVA metal, notably germanium, having certain critical ranges of physical characteristics inclusive of large uniform pore sizes, are used for the conversion, these having been shown to possess improved catalytic activity and selectivity for the hydroconversion of the 1050.degree. F.+ materials of the heavy feeds and residua. Novel methods are described for the preparation of such catalysts, as well as for use of such catalyst. One of the catalysts, i.e.
    Type: Grant
    Filed: December 16, 1974
    Date of Patent: November 23, 1976
    Assignee: Exxon Research and Engineering Company
    Inventors: Fred M. Long, Willard H. Sawyer
  • Patent number: 3993598
    Abstract: This invention relates to novel catalysts, of two distinct types, useful for the catalytic hydroconversion of the 1050.degree. F.+ hydrocarbon material contained in heavy crudes and residua such that the resulting product will be suitable for further processing in conventional refinery operations allowing maximization of clean liquid products. Catalysts, which include Group VIB and Group VIII metals, preferably in admixture, and preferably including a Group IVA metal, notably germanium, having certain critical ranges of physical characteristics inclusive of large uniform pore sizes, are used for the conversion, these having been shown to possess improved catalytic activity and selectivity for the hydroconversion of the 1050.degree. F.+ materials of the heavy feeds and residua. Novel methods are described for the preparation of such catalysts, as well as for use of such catalysts. One of the catalysts, i.e.
    Type: Grant
    Filed: December 16, 1974
    Date of Patent: November 23, 1976
    Assignee: Exxon Research and Engineering Company
    Inventors: William F. Arey, Jr., Glen P. Hamner, Willard H. Sawyer
  • Patent number: 3989645
    Abstract: This invention relates to novel catalysts, of two distinct types, useful for the catalytic hydroconversion of the 1050.degree. F.+ hydrocarbon material contained in heavy crudes and residua such that the resulting product will be suitable for further processing in conventional refinery operations allowing maximization of clean liquid products. Catalysts, which include Group VIB and Group VIII metals, preferably in admixture, and preferably including a Group IVA metal, notably germanium, having certain critical ranges of physical characteristics inclusive of large uniform pore sizes, are used for the conversion, these having been shown to possess improved catalytic activity and selectivity for the hydroconversion of the 1050.degree. F.+ materials of the heavy feeds and residua. Novel methods are described for the preparation of such catalysts, as well as for use of such catalysts. One of the catalysts, i.e.
    Type: Grant
    Filed: December 16, 1974
    Date of Patent: November 2, 1976
    Assignee: Exxon Research and Engineering Company
    Inventors: Fred M. Long, Willard H. Sawyer
  • Patent number: 3985684
    Abstract: This invention relates to novel catalysts, of two distinct types, useful for the catalytic hydroconversion of the 1050.degree.F.+ hydrocarbon material contained in heavy crudes and residua such that the resulting product will be suitable for further processing in conventional refinery operations allowing maximization of clean liquid products. Catalysts, which include Group VIB and Group VIII metals, preferably in admixture, and preferably including a Group IVA metal, notably germanium, having certain critical ranges of physical characteristics inclusive of large uniform pore sizes, are used for the conversion, these having been shown to possess improved catalytic activity and selectivity for the hydroconversion of the 1050.degree.F.+ materials of the heavy feeds and residua. Novel methods are described for the preparation of such catalysts, as well as for use of such catalysts. One of the catalysts, i.e.
    Type: Grant
    Filed: December 16, 1974
    Date of Patent: October 12, 1976
    Assignee: Exxon Research and Engineering Company
    Inventors: William F. Arey, Jr., Glen P. Hamner, Willard H. Sawyer
  • Patent number: 3977962
    Abstract: This invention relates to novel catalysts, of two distinct types, useful for the catalytic hydroconversion of the 1050.degree.F.+ hydrocarbon material contained in heavy crudes and residua such that the resulting product will be suitable for further processing in conventional refinery operations allowing maximization of clean liquid products. Catalysts, which include Group VIB and Group VIII metals, preferably in admixture, and preferably including a Group IVA metal, notably germanium, having certain critical ranges of physical characteristics inclusive of large uniform pore sizes, are used for the conversion, these having been shown to possess improved catalytic activity and selectivity for the hydroconversion of the 1050.degree.F.+ materials of the heavy feeds and residua. Novel methods are described for the preparation of such catalysts, as well as for use of such catalysts. One of the catalysts, i.e.
    Type: Grant
    Filed: December 16, 1974
    Date of Patent: August 31, 1976
    Assignee: Exxon Research and Engineering Company
    Inventors: William F. Arey, Jr., Glen P. Hamner, Willard H. Sawyer