Patents by Inventor Willem Gerrit HAIJE

Willem Gerrit HAIJE has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11897839
    Abstract: The invention relates to an improved process and system for the synthesis of dimethyl ether (DME) from a feedstock comprising H2 and COx, wherein x=1-2. The process according to the invention comprises (a) subjecting the gaseous mixture comprising synthesis gas originating from step (c) to DME synthesis by contacting it with a catalyst capable of converting synthesis gas to DME to obtain a gaseous mixture comprising DME; (b) subjecting a gaseous mixture comprising the gaseous mixture originating from step (a) to a separation-enhanced reverse water gas shift reaction; and (c) subjecting the gaseous mixture originating from step (b) to DME/synthesis gas separation to obtain DME and a gaseous mixture comprising synthesis gas, which is recycled to step (a). Herein, the feedstock is introduced in step (a) or step (b) and the molar ratio of H2 to COx in the gaseous mixture which is subjected to step (b) is at least (x+0.8). Also a system for performing the reaction according to the invention is disclosed.
    Type: Grant
    Filed: August 31, 2020
    Date of Patent: February 13, 2024
    Assignee: NEDERLANDSE ORGANISATIE VOOR TOEGEPAST—NATUURWETENSCHAPPELIJK ONDERZOEK TNO
    Inventors: Franciscus Petrus Felix Van Berkel, Hendricus Adrianus Johannes Van Dijk, Paul Dean Cobden, Willem Gerrit Haije, Jaap Ferdinand Vente
  • Publication number: 20200399195
    Abstract: The invention relates to an improved process and system for the synthesis of dimethyl ether (DME) from a feedstock comprising H2 and COx, wherein x=1-2. The process according to the invention comprises (a) subjecting the gaseous mixture comprising synthesis gas originating from step (c) to DME synthesis by contacting it with a catalyst capable of converting synthesis gas to DME to obtain a gaseous mixture comprising DME; (b) subjecting a gaseous mixture comprising the gaseous mixture originating from step (a) to a separation-enhanced reverse water gas shift reaction; and (c) subjecting the gaseous mixture originating from step (b) to DME/synthesis gas separation to obtain DME and a gaseous mixture comprising synthesis gas, which is recycled to step (a). Herein, the feedstock is introduced in step (a) or step (b) and the molar ratio of H2 to COx in the gaseous mixture which is subjected to step (b) is at least (x+0.8). Also a system for performing the reaction according to the invention is disclosed.
    Type: Application
    Filed: August 31, 2020
    Publication date: December 24, 2020
    Applicant: Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek TNO
    Inventors: Franciscus Petrus Felix VAN BERKEL, Hendricus Adrianus Johannes VAN DIJK, Paul Dean COBDEN, Willem Gerrit HAIJE, Jaap Ferdinand VENTE
  • Patent number: 10759728
    Abstract: The invention relates to an improved process and system for the synthesis of dimethyl ether (DME) from a feedstock comprising H2 and COx, wherein x=1-2. The process according to the invention comprises (a) subjecting the gaseous mixture comprising synthesis gas originating from step (c) to DME synthesis by contacting it with a catalyst capable of converting synthesis gas to DME to obtain a gaseous mixture comprising DME; (b) subjecting a gaseous mixture comprising the gaseous mixture originating from step (a) to a separation-enhanced reverse water gas shift reaction; and (c) subjecting the gaseous mixture originating from step (b) to DME/synthesis gas separation to obtain DME and a gaseous mixture comprising synthesis gas, which is recycled to step (a). Herein, the feedstock is introduced in step (a) or step (b) and the molar ratio of H2 to COx in the gaseous mixture which is subjected to step (b) is at least (x+0.8). Also a system for performing the reaction according to the invention is disclosed.
    Type: Grant
    Filed: January 12, 2017
    Date of Patent: September 1, 2020
    Assignee: NEDERLANDSE ORGANISATIE VOOR TOEGEPAST-NATUURWETENSCHAPPELIJK ONDERZOEK TNO
    Inventors: Franciscus Petrus Felix Van Berkel, Hendricus Adrianus Johannes Van Dijk, Paul Dean Cobden, Willem Gerrit Haije, Jaap Ferdinand Vente
  • Publication number: 20190016656
    Abstract: The invention relates to an improved process and system for the synthesis of dimethyl ether (DME) from a feedstock comprising H2 and COx, wherein x=1-2. The process according to the invention comprises (a) subjecting the gaseous mixture comprising synthesis gas originating from step (c) to DME synthesis by contacting it with a catalyst capable of converting synthesis gas to DME to obtain a gaseous mixture comprising DME; (b) subjecting a gaseous mixture comprising the gaseous mixture originating from step (a) to a separation-enhanced reverse water gas shift reaction; and (c) subjecting the gaseous mixture originating from step (b) to DME/synthesis gas separation to obtain DME and a gaseous mixture comprising synthesis gas, which is recycled to step (a). Herein, the feedstock is introduced in step (a) or step (b) and the molar ratio of H2 to COx in the gaseous mixture which is subjected to step (b) is at least (x+0.8). Also a system for performing the reaction according to the invention is disclosed.
    Type: Application
    Filed: January 12, 2017
    Publication date: January 17, 2019
    Applicant: Stichting Energieonderzoek Centrum Nederland
    Inventors: Franciscus Petrus Felix VAN BERKEL, Hendricus Adrianus Johannes VAN DIJK, Paul Dean COBDEN, Willem Gerrit HAIJE, Jaap Ferdinand VENTE