Abstract: This invention concerns a process for the use of hydrogen halides as chain transfer agents in fluoroolefin polymerization.

Abstract: Rechargeable lithium or lithium-ion electrochemical cells having unmodified natural or synthetic graphite anodes in contact with propylene carbonate or butylene carbonate electrolyte solvent are enabled by the addition of tetra- or pentafluorobenzenes having electron-donating substituents on the ring. Both reversible fraction and cycle life are favorably affected.

Abstract: A container having a container body, a thermic module at one end of the body, and a closure at the other end of the body initiates an internal exothermic (or, alternatively, endothermic) chemical reaction to heat its contents when a user actuates the thermic module. A plastic thermic module body is spin-welded to a plastic container body by rotating one relative to and in contact with the other. The container body has multiple layers, including an inner layer such as a so-called oxygen barrier layer that inhibits oxidation and spoilage of the contents, and spin-welding the container body to the module body seals the otherwise-exposed oxygen barrier layer against air or moisture intrusion. The container includes a rotatable cover adhered to the container end over the closure with heat-sensitive adhesive that prevents a user from accessing the contents until a certain temperature is reached.

Abstract: A container having a container body, a thermic module at one end of the body, and a closure at the other end of the body initiates an internal exothermic (or, alternatively, endothermic) chemical reaction to heat its contents when auser actuates the thermic module. A plastic thermic module body is spin-welded to a plastic container body by rotating one relative to and in contact with the other. The container body has multiple layers, including an inner layer such as a so-called oxygen barrier layer that inhibits oxidation and spoilage of the contents, and spin-welding the container body to the module body seals the otherwise-exposed oxygen barrier layer against air or moisture intrusion. The container includes a rotatable cover adhered to the container end over the closure with heat-sensitive adhesive that prevents a user from accessing the contents until a certain temperature is reached.

Abstract: An apparatus for cleaning an article such as a baby bottle includes a handle that is sized and configured to be gripped in one hand of a user, and a reservoir defined within the handle for storing a detergent. A push-pull cap is provided on the handle for dispensing detergent from the reservoir when the handle is squeezed. A brush is connected to the handle, and is sized and configured so as to be able to fit into an open end of a baby bottle to scrub the baby bottle during cleaning. The push-pull cap is advantageously located on a portion of the handle member that is remote from the brush member, so that a user will be able to dispense detergent and scrub without putting down the apparatus, and also have the flexibility to scrub without fear of unwanted detergent leaking into the brush, such as during a final rinse. A novel brush configuration is also disclosed.

Abstract: Disclosed herein are novel amorphous tetrafluoroethylene-hexafluoropropylene (TFE-HFP) dipolymers, and other copolymers containing TFE, HFP and a third monomer, many of which are more random than previous amorphous TFE-HFP copolymers, as well as a novel high productivity continuous process for making these polymers. The polymers are particularly useful in the form of coatings, films and encapsulants.

Abstract: Fluorinated aldehydes are made by reacting a fluorinated acyl chloride with a silicon hydride in the presence of palladium. Also disclosed are fluorinated ether aldehydes and their polymers, a process for making fluorinated aldehydes polymers using titanium or aluminum alkoxide catalysts, and a process for endcapping fluorinated polymers using perfluoroallyl fluorosulfate or fluorine.

Abstract: A process is disclosed for the manufacture of product compounds of the formula HC(R.sup.1).sub.2 C(R.sup.1).sub.2 C(R.sup.2).sub.2 H wherein each R.sup.1 is independently selected from the group consisting of H, F, Cl, CN, R, OR, CO.sub.2 R, C(O)R, OC(O)R, R.sup.f, OR.sup.f, CO.sub.2 R.sup.f, C(O)R.sup.f and OC(O)R.sup.f where R is a hydrocarbyl group and R.sup.f is a C.sub.1 to C.sub.10 polyfluoroalkyl group, provided that at least one R.sup.1 is F, and wherein each R.sup.2 is independently selected from the group consisting of H, F, Cl, CN, R, OR, CO.sub.2 R, C(O)R, OC(O)R, R.sup.f, OR.sup.f, CO.sub.2 R.sup.f, C(O)R.sup.f, OC(O)R.sup.f and difunctional linkages where an R.sup.2 group on each of two adjacent carbon atoms together form a link selected from the group consisting of --CH.sub.2 CH.sub.2 CH.sub.2 --, --CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 --, --CH.sub.2 CH.sub.2 CH(CH.sub.3)--, --CH.sub.2 CH(CH.sub.3)CH.sub.2 --, --C(O)OC(O)--, and norborndiyl.

Abstract: Fluorinated aldehydes are made by reacting a fluorinated acyl chloride with a silicon hydride in the presence of palladium. Also disclosed are fluorinated ether aldehydes and their polymers, a process for making fluorinated aldehydes polymers using titanium or aluminum alkoxide catalysts, and a process for endcapping fluorinated polymers using perfluoroallyl fluorosulfate or fluorine.

Abstract: A reaction of perfluoroolefins with bis(silyl) ethers to produce novel partially fluorinated and perfluorinated copolymers and macrocyclic compounds is disclosed.

Abstract: Fluorinated aldehydes are made by reacting a fluorinated acyl chloride with a silicon hydride in the presence of palladium. Also disclosed are fluorinated ether aldehydes and their polymers, a process for making fluorinated aldehydes polymers using titanium or aluminum alkoxide catalysts, and a process for endcapping fluorinated polymers using perfluoroallyl fluorosulfate or fluorine.

Abstract: A two step process, each of the steps being novel, for the production of trifluorovinyl ethers by reaction of a siloxane with selected acyl fluorides or carboxylic anhydrides, is disclosed. Also disclosed is a novel silyl ester intermediate.

Abstract: Fluorinated olefins are produced by thermolysis of a silyl ester of a fluorinated aliphatic carboxylic acid in the presence of a catalyst which provides fluoride ion, such as potassium fluoride. The fluorinated olefins are useful as monomers and chemical intermediates.

Abstract: Partially fluorinated compounds of specified formulas that are useful as chemical intermediates and monomers are disclosed. Partially fluorinated polymers prepared from one of these compounds are also disclosed. Fluoro-2,2-dimethyldioxolanes and copolymers thereof are further disclosed.

Abstract: A two step process, each of the steps being novel, for the production of trifluorovinyl ethers by reaction of a siloxane with selected acyl fluorides or carboxylic anhydrides, is disclosed. Also disclosed is a novel silyl ester intermediate.

Abstract: A reaction of perfluoroolefins with bis(silyl) ethers to produce novel partially fluorinated and perfluorinated copolymers and macrocyclic compounds is disclosed.

Abstract: Partially fluorinated compounds of specified formulas that are useful as chemical intermediates and monomers are disclosed. Partially fluorinated polymers prepared from one of these compounds are also disclosed. Fluoro-2,2-dimethyldioxolanes and copolymers thereof are further disclosed.

Abstract: Novel hydroxy containing fluorovinyl ethers, polymers of hydroxy containing fluorovinyl ethers, novel cyclic ethers, copolymers of selected hydroxy containing fluorovinyl ethers, a process for reducing ester containing fluorovinyl compounds to the corresponding alcohol with borohydrides, and a process for polymerizing hydroxy containing fluorovinyl ethers are disclosed.

Abstract: Disclosed are fluorinated macromonomers containing one or more hydroxy groups, which are useful as monomers in other polymerization. Also disclosed are processes and an intermediate for making such macromonomers, and condensation and free radically made polymers which contain the macromonomers. The macromonomers are useful for modifying the properties of the polymers into which they are incorporated.