Patents by Inventor William E. Starner
William E. Starner has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
-
Patent number: 5618905Abstract: A curable epoxy resin composition comprising a polyepoxide resin and an amine curative characterized in that the amine curative comprises a partially methylated polyalkylene polyamine having at least three amine nitrogens and at least two active amine hydrogens.Type: GrantFiled: January 16, 1996Date of Patent: April 8, 1997Assignee: Air Products and Chemicals, Inc.Inventors: John A. Marsella, William E. Starner, Richard S. Myers
-
Patent number: 5591812Abstract: A curable epoxy resin composition comprising a polyepoxide resin and an amine curative characterized in that the amine curative comprises (a) the reaction product of excess monomethylamine (MMA) and an aliphatic or cycloaliphatic polyglycidyl ether and (b) an amine curative. When a diglycidyl ether is used in the reaction the resulting product can be described by the following structure: ##STR1## where R is an aliphatic, cycloaliphatic or aromatic organic radical and m is 0-3.Type: GrantFiled: January 26, 1996Date of Patent: January 7, 1997Assignee: Air Products and Chemicals, Inc.Inventor: William E. Starner
-
Patent number: 5480958Abstract: This invention relates to improved one part polyepoxide resins which are tough and have enhanced flexible and elastic properties. The polyepoxide resins comprise a polyepoxide resin based on a polyglycidyl ether of a phenol, an oxazolidone toughener and a latent amine curative. The improvement in the polyepoxide resin formulation comprises incorporating an oxazolidone toughener represented by the formula: ##STR1## wherein R is the residue of an aliphatic glycol or aliphatic ether glycol having from 2 to 20 carbon atoms.Type: GrantFiled: September 21, 1994Date of Patent: January 2, 1996Assignee: Air Products and Chemicals, Inc.Inventors: William E. Starner, Richard S. Myers
-
Patent number: 5426157Abstract: This invention relates to improved polyepoxide resins having enhanced physical and elastic properties. The polyepoxide resins comprise a polyepoxide resin based on a polyglycidyl ether of a phenolic-type compound and an acrylate-terminated urethane prepolymer. The improvement in the polyepoxide resin formulation comprises incorporating a polymethylated amine curative having two secondary amine hydrogens represented by the formula: ##STR1## wherein R is alkylene or polyalkylene polyamine having from 2 to 20 carbon atoms. The presence of the aliphatic amine reactive component along with the acrylate-terminated urethane prepolymer results in an epoxy resin having enhanced properties.Type: GrantFiled: March 16, 1994Date of Patent: June 20, 1995Assignee: Air Products and Chemicals, Inc.Inventors: William E. Starner, John A. Marsella, Richard S. Myers
-
Patent number: 5426169Abstract: This invention relates to improved polyepoxide resins having enhanced physical and elastic properties. The polyepoxide resins comprise a polyepoxide resin based on a polyglycidyl ether of a phenolic-type compound and an amine curing agent. The improvement in the polyepoxide resin formulation comprises incorporating an aliphatic, aliphatic ether or ester component having monofunctional reactivity with an amine hydrogen, an amine curative having from 3 to 10, and preferably 3 to 5 epoxide reactive hydrogen atoms into the epoxy resin, and a diglycidyl ether of a polyalkyleneoxide. The presence of the monofunctional and aliphatic amine reactive component along with the diglycidyl ether of a polyalkyleneoxide results in an epoxy resin having enhanced properties.Type: GrantFiled: November 2, 1993Date of Patent: June 20, 1995Assignee: Air Products and Chemicals, Inc.Inventor: William E. Starner
-
Patent number: 5334654Abstract: This invention relates to improved polyepoxide resins having enhanced physical and elastic properties. The polyepoxide resins comprise an polyepoxide resin based on a polyglycidyl ether of a phenolic type compound and an acrylate terminated urethane prepolymer. The improvement in the polyepoxide resin formulation comprises incorporating an aliphatic, aliphatic ether or ester component having monofunctional reactivity with an amine hydrogen and an amine curative having from 3 to 10, and preferably 3 to 5 epoxide reactive hydrogen atoms into the epoxy resin. The presence of the monofunctional and aliphatic amine reactive component along with the acrylate terminated urethane prepolymer results in an epoxy resin having the enhanced properties.Type: GrantFiled: May 3, 1993Date of Patent: August 2, 1994Assignee: Air Products and Chemicals, Inc.Inventors: William E. Starner, Susan G. Musselman
-
Patent number: 5260483Abstract: Methods of producing N-aryl amides comprise reacting an aromatic isocyanate compound with substantially anhydrous carboxylic acid and recovering the resulting N-aryl amide. Additionally, or alternatively, methods of forming N-aryl amides comprise reacting an aromatic isocyanate compound with substantially anhydrous carboxylic acid in the presence of an anhydrous hydrogen halide or hydrolytically unstable halide compound and recovering the resulting N-aryl amide. These reactions may occur in the presence of an aprotic solvent.Type: GrantFiled: September 9, 1991Date of Patent: November 9, 1993Assignee: Drexel UniversityInventors: Franklin A. Davis, William E. Starner
-
Patent number: 5202001Abstract: A wiped film evaporation process for reducing the amount of residual organic polyisocyanate, especially toluene diisocyanate, in a polyurethane prepolymer reaction product mixture. An inert sweeping gas is added to the evaporation process, preferably after first passing through a holdup volume of the prepolymer which has passed through the evaporation zone.Type: GrantFiled: July 9, 1991Date of Patent: April 13, 1993Assignee: Air Products and Chemicals, Inc.Inventors: William E. Starner, Bernard A. Toseland, Reinaldo M. Machado
-
Patent number: 5051152Abstract: A wiped film evaporation process for reducing the amount of residual toluene diisocyanate in a polyurethane prepolymer reaction product mixture. An inert sweeping gas is added to the evaporation process, preferably after first passing through a holdup volume of the prepolymer which has passed through the evaporation zone.Type: GrantFiled: September 26, 1989Date of Patent: September 24, 1991Assignee: Air Products and Chemicals, Inc.Inventors: Albert J. Siuta, William E. Starner, Bernard A. Toseland, Reinaldo M. Machado
-
Patent number: 5041670Abstract: Methods of producing N-phenyl amines comprise reacting a phenyl-containing isocyanate with HR, and a boron complexing agent in an aprotic solvent, wherein R, is --OH or --COOH (i.e., water or formic acid), neutralizing the resulting N-aryl amide to N-aryl amine and recovering the N-aryl amine.Type: GrantFiled: March 29, 1988Date of Patent: August 20, 1991Assignee: Drexel UniversityInventors: Franklin A. Davis, William E. Starner
-
Patent number: 4786703Abstract: This invention relates to a polyisocyanate prepolymer for polyurethane/urea elastomer synthesis and to the resulting elastomer. The prepolymer is formed by reacting toluenediisocyanate with a long chain polyol under conditions such that essentially a 2:1 adduct is formed. Excess toluenediisocyanate is removed prior to forming the elastomer.Type: GrantFiled: April 15, 1987Date of Patent: November 22, 1988Assignee: Air Products and Chemicals, Inc.Inventors: William E. Starner, Jeremiah P. Casey, Barton Milligan, Susan M. Clift
-
Patent number: 4724256Abstract: This invention relates to urethane linked hydroxy aromatic isocyanates and to a process for producing such urethane linked hydroxy aromatic isocyanates. The compositions are formed by reacting one equivalent aromatic diisocyanate with one equivalent of an alkylene polyol under conditions such that only one of the isocyanate groups react with the hydroxyl group of the polyol. Conditions are controlled such that the urethane linked hydroxy aromatic isocyanates are formed. The resulting product is suited for producing a variety of elastomers including a one component polyurethane elastomer.Type: GrantFiled: January 13, 1987Date of Patent: February 9, 1988Assignee: Air Products and Chemicals, Inc.Inventors: William E. Starner, Barton Milligan, Roland E. Grandin
-
Patent number: 4722989Abstract: This invention relates to a solvent-free process for producing polyurethane/urea elastomers wherein an aromatic diisocyanate is reacted with a compound having active Zerewitinoff hydrogen atoms and an aromatic diamine chain extender. The improvement for producing urethanes having a wide range of properties comprises including a urethane-linked diisocyanate in the polyurethane urea elastomer. The urethane-linked diisocyanate is one that is formed by reacting toluenediisocyanate or substituent thereof with a short chain diol under conditions such that the urethane linked diisocyanate comprises two equivalents isocyanate per equivalent diol.Type: GrantFiled: March 16, 1987Date of Patent: February 2, 1988Assignee: Air Products and Chemicals, Inc.Inventors: William E. Starner, Barton Milligan, Jeremiah P. Casey
-
Patent number: 4683279Abstract: This invention relates to urethane linked mixtures of 2,4- and 2,6-toluenediisocyanates (ULTDI dimers) having low melting points and to a method of forming these systems. The urethane linked toluenediisocyanates containing from 45-90% of the 2,4- and 10-55% of the 2,6- isomer by weight are formed by reacting two moles of an appropriate isomer mix of toluenediisocyanate, with one mole of a specific alkylene glycol, e.g., 1,2-butanediol, diethylene glycol or dipropylene glycol under conditions such that essentially only one of the isocyanate groups on a toluenediisocyanate molecule reacts with a hydroxyl group of the glycol. Conditions are controlled such that the urethane linked toluenediisocyanates are formed. The resulting product, which has two unreacted isocyanate groups, is suited for producing a variety of elastomers including polyurethane polyurethane/urea or polyurea elastomers.Type: GrantFiled: July 8, 1986Date of Patent: July 28, 1987Assignee: Air Products and Chemicals, Inc.Inventors: Barton Milligan, William E. Starner, Roland E. Grandin, Jeremiah P. Casey
-
Patent number: 4332736Abstract: Acylated 1-hydroxyalkylidene-1, 1-diphosphonic acid (HADPA) can be produced almost instantaneously with less than 5% (by weight) phosphorus acid byproduct by introducing PX.sub.3 (where X is a halide) into a reactor containing R--COOH at or above a specified temperature. The acylated HADPA can then be hydrolyzed and substantially pure HADPA obtained by vacuum distillation. Of particular importance is the addition of PCl.sub.3 to acetic acid at a temperature of between 105.degree. C. and 120.degree. C. to produce acetylated 1-hydroxyethylidene-1, 1-diphosphonic acid (HEDPA).Type: GrantFiled: September 22, 1980Date of Patent: June 1, 1982Assignee: Air Products and Chemicals, Inc.Inventors: William E. Starner, Walter F. Yext