Patent number: 4399260
Abstract: There is disclosed a process for the preparation of thermoplastic block polymers which comprises contacting conjugated diolefinic monomers selected from the group consisting of isoprene, piperylene, 2-ethyl-1,3-butadiene, 2,3-dimethyl-1,3-butadiene and 1,3-butadiene, and the like, mixed with at least one polyvinyl aromatic coupling compound selected from the group of o, m and p-divinylbenzene, 1,2,4-trivinylbenzene, 1,8-divinylnaphthalene, 1,2-divinyl-3,4-dimethylbenzene, 2,4-divinylbiphenyl, 3,5,4'-trivinylbiphenyl and 1,3,5-trivinylbenzene under solution polymerization conditions with a polystyryllithium catalyst which has been prepared by reacting an alkyllithium compound with a styrene monomer selected from the group consisting of styrene, alpha-methylstyrene, p-methylstyrene, p-t-butylstyrene, 3-methylstyrene, 1-vinylnaphthalene, and the like, in which an amount of polyvinyl aromatic coupling compound ranges from about 1.
Type:
Grant
Filed:
January 4, 1982
Date of Patent:
August 16, 1983
Assignee:
The Goodyear Tire & Rubber Company
Inventor:
William G. Carson