Patents by Inventor William J. Heilman

William J. Heilman has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8168838
    Abstract: A process for the preparation of a synthetic predominantly single carbon number hydrocarbon fluid comprises the steps of: contacting an alpha olefin having a carbon number of 4 to 30 with a single site catalyst under conditions effective to produce reactive hydrocarbon oligomers that contain reactive double bonds and comprising predominantly dimers, trimers, and tetramers wherein at least 10 weight percent of such reactive hydrocarbon oligomers at least one of trimers and tetramers; separating at least one of said trimers and tetramers in said reactive hydrocarbon oligomers; dimerizing said separated one of said trimers tetramers by contacting said separated one of said trimers or tetramers with a dimerization catalyst thereby producing an unsaturated synthetic hydrocarbon fluid; and contacting said unsaturated synthetic hydrocarbon fluid with hydrogen in the presence of a hydrogenation catalyst thereby producing a synthetic hydrocarbon fluid having predominantly single carbon number.
    Type: Grant
    Filed: January 19, 2010
    Date of Patent: May 1, 2012
    Assignee: Shell Oil Company
    Inventors: William J Heilman, Yajnanarayana Halmuthur Jois, Abraham Robert De Kraker, Wei Song
  • Publication number: 20110178348
    Abstract: A process for the preparation of a synthetic predominantly single carbon number hydrocarbon fluid comprises the steps of: contacting an alpha olefin having a carbon number of 4 to 30 with a single site catalyst under conditions effective to produce reactive hydrocarbon oligomers that contain reactive double bonds and comprising predominantly dimers, trimers, and tetramers wherein at least 10 weight percent of such reactive hydrocarbon oligomers at least one of trimers and tetramers; separating at least one of said trimers and tetramers in said reactive hydrocarbon oligomers; dimerizing said separated one of said trimers tetramers by contacting said separated one of said trimers or tetramers with a dimerization catalyst thereby producing an unsaturated synthetic hydrocarbon fluid; and contacting said unsaturated synthetic hydrocarbon fluid with hydrogen in the presence of a hydrogenation catalyst thereby producing a synthetic hydrocarbon fluid having predominantly single carbon number.
    Type: Application
    Filed: January 19, 2010
    Publication date: July 21, 2011
    Inventors: William J. HEILMAN, Yajnanarayana Halmuthur Jois, Abraham Robert De Kraker, Wei Song
  • Patent number: 7524796
    Abstract: Polymer suspensions prepared with non-aqueous, oil-free carrier fluids, for use in oil or gas well servicing. The polymer suspensions typically comprise a hydrophilic polymer, an organic clay, a stabilizer, and a carrier fluid selected from propylene glycol and butylene glycol. The addition of isopropyl alcohol, a polar activator, lowers the viscosity of the suspension. The further addition of neopentyl glycol further lowers viscosity and improves cross-linking of the polymer. The composition is both stable and environmentally acceptable.
    Type: Grant
    Filed: February 27, 2008
    Date of Patent: April 28, 2009
    Inventors: William J. Heilman, Asoke K. Deysarkar
  • Patent number: 7129197
    Abstract: One or more oligomers of an olefin are prepared in the presence of a single-site catalyst. Preferably, the olefin is an ?-olefin, and the oligomers are a poly-alpha-olefin (PAO). The PAO so prepared is completely or substantially free of tertiary hydrogen resulting from isomerization. Consequently, the PAO possesses improved biodegradability, improved oxidation resistance, and/or a relatively higher viscosity index. The PAO has many useful applications, such as a component of a lubricant.
    Type: Grant
    Filed: August 29, 2002
    Date of Patent: October 31, 2006
    Assignee: Shell Oil Company
    Inventors: Wei Song, William J. Heilman
  • Patent number: 6730818
    Abstract: A novel series of copolymers and terpolymers, useful as base oils for synthetic lubricants, are produced by polymerization of ethylene, an alpha-olefin, and optionally a third monomer comprising an alpha-olefin of 3 to 20 carbon atoms, in the presence of a combination catalyst comprising a compound of a transition metal of Group IVb of the Periodic Table and an aluminoxane. The copolymer or terpolymer may be further processed by thermal cracking to yield novel cracked polymers, and the cracked polymers may be hydrogenated. The copolymers or terpolymers may also be hydroisomerized. All the polymers are useful as base oils for lubricating oils and consumer products.
    Type: Grant
    Filed: May 22, 2002
    Date of Patent: May 4, 2004
    Assignee: Penzoil-Quaker State Company
    Inventors: William J. Heilman, I-Ching Chiu, James C. W. Chien
  • Patent number: 6586646
    Abstract: Various vinylidene-containing polymers are obtained in the presence of a single-site catalyst. For example, the polymers include ethylene/isobutene copolymer, ethylene/propylene/isobutene terpolymer, ethylene/styrene/isobutene terpolymer, ethylene/&agr;-methyl-styrene/isobutene terpolymer, propylene/isobutene copolymer, styrene/isobutene copolymer, and &agr;-methyl-styrene/isobutene copolymer. These polymers may be used to formulate lubricant oils.
    Type: Grant
    Filed: November 24, 1999
    Date of Patent: July 1, 2003
    Assignee: Pennzoil-Quaker State Company
    Inventors: William J. Heilman, I-Ching Chiu, Wei Song, James C. W. Chien
  • Publication number: 20030055184
    Abstract: One or more oligomers of an olefin are prepared in the presence of a single-site catalyst. Preferably, the olefin is an &agr;-olefin, and the oligomers are a poly-alpha-olefin (PAO). The PAO so prepared is completely or substantially free of tertiary hydrogen resulting from isomerization. Consequently, the PAO possesses improved biodegradability, improved oxidation resistance, and/or a relatively higher viscosity index. The PAO has many useful applications, such as a component of a lubricant.
    Type: Application
    Filed: August 29, 2002
    Publication date: March 20, 2003
    Applicant: Pennzoil-Quaker State Company
    Inventors: Wei Song, William J. Heilman
  • Publication number: 20020193647
    Abstract: A novel series of copolymers and terpolymers, useful as base oils for synthetic lubricants, are produced by polymerization of ethylene, an alpha-olefin, and optionally a third monomer comprising an alpha-olefin of 3 to 20 carbon atoms, in the presence of a combination catalyst comprising a compound of a transition metal of Group IVb of the Periodic Table and an aluminoxane. The copolymer or terpolymer may be further processed by thermal cracking to yield novel cracked polymers, and the cracked polymers may be hydrogenated. The copolymers or terpolymers may also be hydroisomerized. All the polymers are useful as base oils for lubricating oils and consumer products.
    Type: Application
    Filed: May 22, 2002
    Publication date: December 19, 2002
    Applicant: Pennzoil-Quaker State Company
    Inventors: William J. Heilman, I-Ching Chiu, James C. W. Chien
  • Patent number: 6417416
    Abstract: A novel series of copolymers and terpolymers, useful as base oils for synthetic lubricants, are produced by polymerization of ethylene, an alpha-olefin, and optionally a third monomer comprising an alpha-olefin of 3 to 20 carbon atoms, in the presence of a combination catalyst comprising a compound of a transition metal of Group IVb of the Periodic Table and an aluminoxane. The copolymer or terpolymer may be further processed by thermal cracking to yield novel cracked polymers, and the cracked polymers may be hydrogenated. The copolymers or terpolymers may also be hydroisomerized. All the polymers are useful as base oils for lubricating oils and consumer products.
    Type: Grant
    Filed: June 19, 2000
    Date of Patent: July 9, 2002
    Assignee: Pennzoil-Quaker State Company
    Inventors: William J. Heilman, I-Ching Chiu, James C. W. Chien
  • Publication number: 20010044562
    Abstract: A novel series of copolymers and terpolymers, useful as base oils for synthetic lubricants, are produced by polymerization of ethylene, an alpha-olefin, and optionally a third monomer comprising an alpha-olefin of 3 to 20 carbon atoms, in the presence of a combination catalyst comprising a compound of a transition metal of Group IVb of the Periodic Table and an aluminoxane. The copolymer or terpolymer may be further processed by thermal cracking to yield novel cracked polymers, and the cracked polymers may be hydrogenated. The copolymers or terpolymers may also be hydroisomerized. All the polymers are useful as base oils for lubricating oils and consumer products.
    Type: Application
    Filed: March 7, 2001
    Publication date: November 22, 2001
    Applicant: Pennzoil-Quaker State Company
    Inventors: William J. Heilman, I-Ching Chiu, James C.W. Chien
  • Patent number: 6124513
    Abstract: A novel series of copolymers and terpolymers, usefull as base oils for synthetic lubricants, are produced by polymerization of ethylene, an alpha-olefin, and optionally a third monomer comprising an alpha-olefin of 3 to 20 carbon atoms, in the presence of a combination catalyst comprising a compound of a transition metal of Group IVb of the Periodic Table and an aluminoxane. The copolymer or terpolymer may be further processed by thermal cracking to yield novel cracked polymers, and the cracked polymers may be hydrogenated. The copolymers or terpolymers may also be hydroisomerized. All the polymers are useful as base oils for lubricating oils and consumer products.
    Type: Grant
    Filed: June 20, 1997
    Date of Patent: September 26, 2000
    Assignee: Pennzoil-Quaker State Company
    Inventors: William J. Heilman, I-Ching Chiu, James C. W. Chien
  • Patent number: 6066329
    Abstract: Transparent stiff gel candles comprising a hydrocarbon oil, a wick, and one or more triblock, radial block or multiblock copolymer of a thermoplastic rubber, and optionally a diblock copolymer.
    Type: Grant
    Filed: March 3, 1999
    Date of Patent: May 23, 2000
    Assignee: Pennzoil Products Company
    Inventors: David S. Morrison, William J. Heilman
  • Patent number: 5879694
    Abstract: Transparent stiff gel candles comprising a hydrocarbon oil, a wick, and one or more triblock, radial block or multiblock copolymer of a thermoplastic rubber, and optionally a diblock copolymer.
    Type: Grant
    Filed: February 11, 1997
    Date of Patent: March 9, 1999
    Assignee: Pennzoil Products Company
    Inventors: David S. Morrison, William J. Heilman
  • Patent number: 5728907
    Abstract: Tetraalkylmethanes are synthetic lubricants. The preferred structure contains four straight chain alkyl groups which may be the same or different and have from 1 to 2 or 5 to 14 carbon atoms. Mixtures are also disclosed as are novel methods for preparation of the tetraalkylmethanes.
    Type: Grant
    Filed: October 27, 1995
    Date of Patent: March 17, 1998
    Assignee: Pennzoil Products Company
    Inventors: Michael P. Squicciarini, William J. Heilman
  • Patent number: 5436379
    Abstract: Fully synthetic lubricating base oil compositions are formulated from blends of 50-97 wt % of synthetic hydrocarbons and 3-30 wt % isobutylene oligomers. The lubricating base oil composition have constant viscosity indexes which are higher than those of the components used to form the compositions. The synthetic hydrocarbon and isobutylene oligomers are combinable in various amounts with conventional additives to form multi-grade engine lubricants, which are shear stable.
    Type: Grant
    Filed: January 14, 1994
    Date of Patent: July 25, 1995
    Assignee: Pennzoil Products Company
    Inventors: William J. Heilman, Clifford G. Venier
  • Patent number: 5221534
    Abstract: Health and beauty aid compositions comprise one or more health and beauty aid components contained in a gel comprising a mineral oil containing from blends of di- and triblock copolymers based on synthetic thermoplastic rubbers.
    Type: Grant
    Filed: February 4, 1991
    Date of Patent: June 22, 1993
    Assignee: Pennzoil Products Company
    Inventors: Paul J. DesLauriers, William J. Heilman
  • Patent number: 5188724
    Abstract: A pour point depressant for lubricating oils comprises an olefin copolymer which contains alkyl side chains having carbon atoms, wherein the average side chain length in the copolymer is 10.5 to 12.0.
    Type: Grant
    Filed: February 6, 1991
    Date of Patent: February 23, 1993
    Assignee: Pennzoil Products Company
    Inventors: William J. Heilman, Bruce E. Wilburn
  • Patent number: 5180865
    Abstract: Fully synthetic lubricating base oil compositions are formulated from blends of 50-97 wt % of synthetic hydrocarbons and 3-50 wt % isobutylene oligomers. The lubricating base oil compositions have constant viscosity indexes which are higher than those of the components used to form the compositions. The synthetic hydrocarbon and isobutylene oligomers are combinable in various amounts with conventional additives to form multi-grade engine lubricants, which are shear stable.
    Type: Grant
    Filed: December 6, 1991
    Date of Patent: January 19, 1993
    Assignee: Pennzoil Products Company
    Inventors: William J. Heilman, Clifford G. Venier
  • Patent number: 5015507
    Abstract: A method of converting a rusted surface to a durable one comprises applying a composition for converting a rusted metal surface to form durable preparative coatings thereon, the rust conversion composition comprising a reducing agent which will function to reduce trivalent iron to divalent iron on the substrate, an organic monomer which is capable of polymerization in the presence of the reducing agent, on the surface, and a free radical initiator which will function to polymerize the organic monomer to form the durable coating.
    Type: Grant
    Filed: January 31, 1989
    Date of Patent: May 14, 1991
    Assignee: Pennzoil Products Company
    Inventors: Paul J. DesLauriers, William J. Heilman
  • Patent number: 4956111
    Abstract: A pour point depressant for lubricating oils comprises a poly(methacrylate) polymer having the repeating unit ##STR1## wherein R is an alkyl group having an average chain length in the polymer of 12.6 to 13.8, and n is an integer indicating the number of repeating units, the value of n being sufficient to provide a molecular weight of 10,000 to 300,000 for the polymer, the pour point depressant having the capacity to reduce the stable pour point to -35.degree. C., while being compatible with other additives such as viscosity index improvers and detergents.
    Type: Grant
    Filed: January 25, 1989
    Date of Patent: September 11, 1990
    Assignee: Pennzoil Products Company
    Inventors: Bruce E. Wilburn, William J. Heilman