Abstract: A system and method for the treating at least one undesirable constituent in an aqueous mixture utilizing a particulate solids catalyst. The aqueous mixture and the particulate solids catalyst form a slurry which is wet oxidized.

Abstract: A wet oxidation process is used to control the concentration of reduced sulfur compounds from a viscose process. The wet oxidation process oxidizes the reduced sulfur compounds to convert such reduced sulfur compounds to an alkali sulfate and/or thiosulfate species. The alkali sulfate stream is recycled to the viscose process. Oxidation is performed under elevated temperature and pressure conditions such that the offgas has an oxygen concentration of between about 2% to 18% and the alkali sulfate stream has a pH of about 2 to 10.

Abstract: The invention is a process for treating waste slurry generated in the electric furnace production of phosphorus in which a superatmospheric reactor is operated at an elevated temperature to destroy cyanides, phosphorus, and phosphides present in the waste. The process transforms wastes from the phosphorus electric furnace process into non-hazardous solid, liquid, and gaseous wastes that meet environmental regulatory requirements regarding solids for phosphorous, cyanide, phosphine and cyanide flux, and TCLP metals, and regarding the filtrate for UTS metals.

Abstract: A system and method for providing an oxidized liquid effluent stream substantially free of volatile compounds is provided. The system includes a stripper positioned downstream of a separator, or disposed within a separator. The method involves volatilizing volatile compounds by performing a separation followed by stripping, or in the same chamber as the separation. In another aspect, the invention involves adjusting the pH of the oxidized waste stream prior to stripping in order to convert ionic species to volatile species that can be removed by stripping.

Abstract: A process for treating wastewaters containing carbonaceous COD and at least one nitrogen-containing compound is disclosed comprising wet oxidizing the wastewater with an oxidizing agent at a temperature less than 373.degree. C. and a pressure sufficient to maintain a liquid water phase, to produce an oxidized wastewater containing a reduced concentration of COD. The nitrogen of the nitrogen-containing compound is substantially converted to ammonia, nitrate and nitrite. Sufficient inorganic nitrogen-containing compound is added to the oxidized wastewater to produce essentially equal concentrations of ammonia-nitrogen and nitrite-nitrogen plus nitrate-nitrogen. Mineral acid is added to the oxidized wastewater to produce a pH between 4 and 7, and optionally, a transition metal salt is added, to catalyze a thermal denitrification step. The wastewater is heated at temperatures between about 100.degree. C. and 300.degree. C. to decompose the nitrogen compounds, producing a purified wastewater.

Abstract: A process for treatment of caustic sulfide liquor by wet oxidation in a ferrous-based alloy system at temperatures less than about 175.degree. C. is described. The liquor is first analyzed for alkalinity consuming species and for nonsulfidic alkalinity. If excess alkalinity consuming species is present compared to nonsulfidic alkalinity, then additional nonsulfidic alkalinity is added to the raw liquor such that excess alkalinity is present during wet oxidation treatment, thus preventing excessive corrosion to the ferrous-base alloy system.

Abstract: A two-stage wet oxidation process for COD removal from high strength wastewater is disclosed. The wastewater stream is treated in a first stage subcritical wet oxidation zone at temperatures between about 250.degree. and 374.degree. C. to remove a substantial portion of the COD. Subsequently, all or a portion of the first stage oxidized waste stream is treated in a second stage supercritical wet oxidation zone at temperatures of 374.degree. to about 600.degree. C. to remove any remaining COD content. Both stages of wet oxidation treatment are carried out at essentially the same system pressure.

Abstract: A process for treatment of caustic sulfide liquor by wet oxidation in a nickel-based alloy system is described. The liquor is first analyzed for alkalinity consuming species and for nonsulfidic alkalinity. If excess alkalinity consuming species is present compared to nonsulfidic alkalinity, then additional nonsulfidic alkalinity is added to the raw liquor such that excess alkalinity is present during wet oxidation treatment, thus preventing excessive corrosion to the nickel-base alloy system.

Abstract: A two-stage process for purifying wastewater includes the steps of biophysical anaerobic treatment to remove the majority of the COD, followed by biophysical aerobic treatment to further purify the wastewater. A powdered adsorbent, preferably powdered activated carbon, is used with biological solids in each treatment step. Excess biophysical solids from the aerobic step are transferred to the anaerobic step for digestion. Fresh powdered adsorbent is added to the aerobic treatment step to compensate for that transferred to the anaerobic treatment step. Solids concentration in the anaerobic step is controlled by wasting solids to disposal.

Abstract: A two-stage, batch process for purifying wastewater containing organic and adsorbable pollutants includes the steps of introducing a predetermined quantity of the wastewater into an aeration and settling zone of a primary treatment zone and aerating therein in the presence of a powered absorbent, such as activated carbon, and biologically active solids, terminating aeration and retaining the thus-treated wastewater in the aeration and settling zone a sufficient time for a substantial portion of the suspended solids to settle by gravity. A predetermined amount of the partialy-treated wastewater is withdrawn from the aeration and settling zone and introduced into a contact zone wherein it is agitated, preferably by aeration, in the presence of a powered adsorbent, agitation is terminated and the solids are allowed to settle by gravity. After completion of settling, clarified, substantially solids-free water is withdrawn from the contact zone.

Abstract: A two-stage process for purifying wastewater containing organic and adsorbable pollutants includes the steps of first aerating the wastewater in the presence of a powdered adsorbent, such as activated carbon, and biologically active solids in the aeration zone of a primary treatment zone which also includes a quiescent zone. The thus-treated water passes from the aeration zone to the quiescent zone where it is retained a sufficient time for a substantial portion of the suspended solids to settle by gravity. The partially-treated wastewater overflowing from the quiescent zone is introduced into one or more contact zones wherein it is agitated, preferably by aeration, in the presence of a powdered adsorbent, agitation is terminated and the solids are allowed to settle by gravity and, after completion of settling, clarified, substantially solids-free water is withdrawn from each contact zone.

Abstract: Regenerated adsorbent particles, such as activated carbon, are recovered from a wet oxidation-regenerated mixed liquor sludge from a wastewater treatment system by diluting and settling a blowdown slurry from the wet oxidation reactor to obtain a first aqueous phase containing primarily regenerated adsorbent particles and fine ash particles and a first solids phase containing primarily grit particles. The first aqueous phase is combined with a portion of the regenerated adsorbent particle slurry withdrawn from the upper portion of the wet oxidation reactor and, after treatment with a dispersing agent and then an anionic flocculating agent, the resulting mixture is settled to obtain a second aqueous phase containing primarily fine ash particles and a second solids phase containing primarily regenerated adsorbent particles.

Abstract: A process for treating high strength BOD containing liquors includes the step of mildly mixing and contacting the liquors with anaerobic bacteria and a powdered adsorbent support medium to remove a substantial portion of the organic matter and generate a methane fuel gas. Use of the powdered support medium at 0.1-20 g/l enables high removal of BOD in short treatment times, rapid clarification of treated liquors, and increased adsorbability of liquor color.In a subsequent decolorizing embodiment, digested and clarified liquors are contacted with reduced concentrations of powdered color adsorbent to produce a treated liquor low in dissolved organic matter and color.The spent streams of powdered adsorbent support medium-biomass and/or powdered color adsorbent are preferably regenerated and reused.

Abstract: Disinfection of aqueous media contaminated with microorganisms is effected by contacting said media with a gas phase in which a plasma is generated by focused laser radiation. Similarly, wastewaters containing organic susbstances are purified by contacting them with an oxygen-containing gas phase in which a plasma is generated by focused laser radiation which promotes oxidation of the organic substances to innocuous products.

Abstract: An improvement in the delignification (pulping) of raw cellulose by treatment with oxygen and an alkaline buffer solution at elevated temperature and pressure, which comprises carrying out the process in an unflooded condition, that is, where contact between the raw cellulose and buffer solution is intermittent, both gaseous and liquid phases being present at all times. Optionally, cupric ion may be present as a catalyst.