Abstract: A creep-resistant zircon article and a method of manufacturing the creep-resistant zircon article are described herein. In one example, the creep-resistant zircon article has the shape of a forming apparatus (e.g., isopipe) which is used in the fusion process to manufacture glass sheets.

Abstract: A creep-resistant zircon article and a method of manufacturing the creep-resistant zircon article are described herein. In one example, the creep-resistant zircon article has the shape of a forming apparatus (e.g., isopipe) which is used in the fusion process to manufacture glass sheets.

Abstract: The present invention relates to an ordered mesoporous carbon and method for manufacturing the ordered mesoporous carbon which is made from a surfactant, a carbon precursor, water (possibly mixed with an acid) and a water immiscible oil. In addition, the present invention relates to a method of formulating a composition which is used to manufacture the ordered mesoporous carbon. Moreover, the present invention relates to an activated carbon which is made by partially oxidizing an ordered mesoporous carbon.

Abstract: The present invention relates to an ordered mesoporous carbon and method for manufacturing the ordered mesoporous carbon which is made from a surfactant, a carbon precursor, water (possibly mixed with an acid) and a water immiscible oil. In addition, the present invention relates to a method of formulating a composition which is used to manufacture the ordered mesoporous carbon. Moreover, the present invention relates to an activated carbon which is made by partially oxidizing an ordered mesoporous carbon.

Abstract: Bulk and supported catalysts are prepared from an aqueous slurry containing a catalytically active material and a binder. The slurry is either coated onto a support and dried to form a porous, high surface area phase containing the catalytically active material, or reduced to a paste-like consistency, molded and dried to form a bulk catalyst. The processes and catalysts may be employed in various catalytic chemical processes to achieve high effectiveness factor of the catalytically active material while achieving a lower pressure drop.

Abstract: Alumina-silica catalyst supports having substantially high surfaces areas are formed by extrusion, drying and firing of a plasticized batch including an alumina-silica powder component, acid, organic binder and water. The alumina-silica powder component can be formed either by the mixing of alumina- and silica-source powders or by forming a slurry therefrom which is spray dried to form a particulate material prior to batching.

Abstract: High-surface-area alumina honeycombs are subjected to a water vapor pre-treatment to obtain protection from cracking damage on subsequent exposure to aqueous media e.g., aqueous solutions for depositing catalysts on the honeycombs.

Abstract: A process of making a supported catalyst includes steps of preparing a washcoat containing a mixture of hydrolyzed silicon alkoxide and a filler, depositing the washcoat on a surface of a solid support, drying the washcoat deposited on the surface of the solid support to form a coating on the surface of the solid support, and distributing a metal catalyst on the coating. The resulting supported catalyst may be used in a reaction vessel, such as a fixed bed reactor, for effecting a catalytic reaction, such as catalytic hydrogenation of an edible oil. The washcoatings can be formulated to provide a viscous composition that can be applied to form a thick coating on a substrate. The dried washcoatings exhibit excellent stability, cohesive layering strength, and adhesive strength between the coating and a substrate.

Abstract: Bulk and supported catalysts are prepared from an aqueous slurry containing a catalytically active material and a binder. The slurry is either coated onto a support and dried to form a porous, high surface area phase containing the catalytically active material, or reduced to a paste-like consistency, molded and dried to form a bulk catalyst. The processes and catalysts may be employed in various catalytic chemical processes to achieve high effectiveness factor of the catalytically active material while achieving a lower pressure drop.

Abstract: Crack-free alumina honeycombs are made by comminuting anhydrous aluminum oxide powder, blending and mulling the powder with an aluminum oxide or aluminum hydroxide permanent binder, a polymeric aluminum salt, a temporary binder, an aqueous acidic peptizing agent, and water, and thereafter homogenizing, extruding, drying and firing the extrudate to form the crack-free honeycomb.

Abstract: A process of making a supported catalyst includes steps of preparing a washcoat containing a mixture of hydrolyzed silicon alkoxide and a filler, depositing the washcoat on a surface of a solid support, drying the washcoat deposited on the surface of the solid support to form a coating on the surface of the solid support, and distributing a metal catalyst on the coating. The resulting supported catalyst may be used in a reaction vessel, such as a fixed bed reactor, for effecting a catalytic reaction, such as catalytic hydrogenation of an edible oil. The washcoatings can be formulated to provide a viscous composition that can be applied to form a thick coating on a substrate. The dried washcoatings exhibit excellent stability, cohesive layering strength, and adhesive strength between the coating and a substrate.

Abstract: High-surface-area alumina honeycombs are subjected to a water vapor pre-treatment to obtain protection from cracking damage on subsequent exposure to aqueous media e.g., aqueous solutions for depositing catalysts on the honeycombs.

Abstract: Crack-free alumina honeycombs of high strength and high surface area are made from anhydrous alumina powder extrusion batches incorporating a combination of a hydrous aluminum oxide or aluminum hydroxide permanent binder and a polymeric aluminum salt; extruded honeycombs incorporating these constituents plus temporary binders, peptizing aqueous acid additions and water exhibit significantly reduced drying shrinkage, and thus reduced cracking, high fired surface area, and high fired strength.

Abstract: Strong, high-surface-area honeycombs of alumina or other ceramic composition are provided by compounding and shaping a moldable ceramic powder extrusion batches including a cellulosic temporary binder and a high-surface-area boehmite precursor for a permanent binder, hydrating the shaped honeycomb to develop a boehmite binding phase, and calcining the hydrated body to develop the binder and provide a ceramic honeycomb of high strength and porosity.

Abstract: Axial flow dehydrogenation reactors comprising multiple catalyst beds formed of honeycomb monoliths, the beds being separated from each other by heating stages to maintain reactant stream temperature, provide low pressure drop and improved conversion efficiency when used alone or in combination with other reactors, e.g., as reactor upgrades for series reactor systems incorporating radial flow reactor stages.

Abstract: Extruded honeycomb dehydrogenation catalysts of high structural integrity, composed of potassium oxide (carbonate)-promoted oxide-stabilized iron oxides and having a honeycomb cell density in the range of 15-400 channels per square inch, a channel wall thickness in the range of 0.2-3 mm, and an axial crushing strength in excess of 100 psi, are prepared from extrusion batches incorporating polymer binders exhibiting improved compatibility with high batch concentrations of dissolved catalyst precursors or constituents.

Abstract: A sensor for selectively detecting HC classes, e.g., alkanes, alkenes and aromatics, in a gas mixture comprising a metal oxide seiniconductor catalyst which is catalytically active for the selective HC classes; the reactions selected from the group consisting of partial oxidation, oxidative dehydrogenation, oxidative coupling and isomerization. Each of these reactions results in imparting a change in the electrical conductivity of the metal oxide which is proportional to the concentration of the HC in the gas mixture. Suitable metal oxide catalysts include Bi.sub.2 O.sub.3 --MoO.sub.3, CoO--MoO.sub.3, SnO.sub.2 --MoO.sub.3, TeO.sub.2 --MoO.sub.3, Sb.sub.2 O.sub.5 --V.sub.2 O.sub.5 --MoO.sub.3, SnO.sub.2 --Sb.sub.2 O.sub.5, Nb.sub.2 O--V.sub.2 O.sub.5 --MoO.sub.3, V.sub.2 O.sub.5 --MoO.sub.3, ZnO--Fe.sub.2 O.sub.3, Li.sub.2 O--MgO, V.sub.2 O.sub.5 --P.sub.2 O.sub.5, metal oxide compounds of a spinel or perovskite crystalline structure, and mixtures thereof.

Abstract: A method for improving the adsorption properties of a hydrocarbon adsorber involves contacting a molecular sieve hydrocarbon adsorber at ambient temperature with an agent for modifying the acid sites of the molecular sieve to impregnate the molecular sieve with the agent. The average pore diameter of the intracrystalline porosity of the molecular sieve is about 3 to 20 angstroms. The agent has an anionic portion which is retained within the structure of the molecular sieve. The modified molecular sieve has the ability to retain adsorbed hydrocarbons at higher temperatures than the unmodified molecular sieve. The acid-modified molecular sieve can be used to remove hydrocarbons from a hydrocarbon-containing stream. The hydrocarbon-containing stream is passed through the modified adsorber at atmospheric pressure at a temperature ranging from room temperature to about 150.degree. C. to cause adsorption and retention of the hydrocarbons.

Abstract: A method for improving the adsorption properties of a hydrocarbon adsorber which involves contacting a molecular sieve hydrocarbon adsorber with an agent for modifying the acid sites of the molecular sieve to impregnate the molecular sieve with the agent. The resulting acid-modified molecular sieve has the ability to retain adsorbed hydrocarbons at higher temperatures than the molecular sieve in the un-modified state. The acid-modified molecular sieve can be used to remove hydrocarbons from a workstream. The workstream is passed through the modified adsorber at atmospheric pressure at a temperature ranging from room temperature to about 150.degree. C. to cause adsorption and retention of the hydrocarbons. The adsorbed hydrocarbons can then be desorbed at a higher temperature than would otherwise occur with an unmodified adsorber.

Abstract: A phosphate-Al.sub.2 O.sub.3 material is disclosed wherein the phosphate is homogeneously dispersed throughout, the specific surface area as measured by N.sub.2 BET method is at least about 50 m.sup.2 /g, and the average pore radius is no greater than about 200.ANG.. A method is disclosed for producing the material which comprises forming a precursor material by wet-mixing a phosphate yielding species and an aluminum oxide yielding species which can be aluminum oxide, aluminum hydroxylated oxides, aluminum hydroxide, aluminum alkoxides, and combinations thereof, in amounts sufficient to result in an AlPO.sub.4 content of about 3 to 12 percent by weight in the phosphate-Al.sub.2 O.sub.3, drying and heat-treating the precursor material at a temperature and for a time sufficient to form the phosphate- Al.sub.2 O.sub.3. The material is used as a support for catalyst metals.