Abstract: A cured silicone foam exhibiting high flame resistance and forming hard chars on burning, contains from about 1 to 60 percent by weight of wollastonite mineral, based on the weight of the composition. The silicone foam can be formed from any of the curable polyorganosiloxane foam-forming compositions known in the art. Preferred are those polyorganosiloxane foams cured using a platinum group metal catalyst. In a preferred composition the silicone foam is formed by curing a composition comprising a liquid polyorganosiloxane containing an average of at least two alkenyl radicals per molecule, an organohydrogensiloxane containing at least three silicon-bonded hydrogen atoms per molecule, a hydroxyl-containing compound, wollastonite, and a platinum catalyst.