Patents by Inventor William V. Block

William V. Block has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9039821
    Abstract: The present invention relates to methods and compositions for coating aluminum substrates. In an embodiment, the invention includes a method of applying a coating on an aluminum substrate including contacting the aluminum substrate with a first solution. The first solution can include a zinc metal salt, a sugar acid or alkali metal salt thereof, and an alkali metal hydroxide. The method can also include contacting the aluminum substrate with a second solution. The second solution can include a molybdate salt, an alkanolamine, and a fluorine acid. Other embodiments are also included herein.
    Type: Grant
    Filed: February 28, 2014
    Date of Patent: May 26, 2015
    Assignee: BIRCHWOOD LABORATORIES LLC
    Inventors: William V. Block, David J. Halverson, John T. Nguyen
  • Publication number: 20140190368
    Abstract: The present invention relates to methods and compositions for coating aluminum substrates. In an embodiment, the invention includes a method of applying a coating on an aluminum substrate including contacting the aluminum substrate with a first solution. The first solution can include a zinc metal salt, a sugar acid or alkali metal salt thereof, and an alkali metal hydroxide. The method can also include contacting the aluminum substrate with a second solution. The second solution can include a molybdate salt, an alkanolamine, and a fluorine acid. Other embodiments are also included herein.
    Type: Application
    Filed: February 28, 2014
    Publication date: July 10, 2014
    Applicant: BIRCHWOOD LABORATORIES, INC.
    Inventors: William V. Block, David J. Halverson, John T. Nguyen
  • Patent number: 8691346
    Abstract: The present invention relates to methods and compositions for coating aluminum substrates. In an embodiment, the invention includes a method of applying a coating on an aluminum substrate including contacting the aluminum substrate with a first solution. The first solution can include a zinc metal salt, a sugar acid or alkali metal salt thereof, and an alkali metal hydroxide. The method can also include contacting the aluminum substrate with a second solution. The second solution can include a molybdate salt, an alkanolamine, and a fluorine acid. Other embodiments are also included herein.
    Type: Grant
    Filed: May 6, 2009
    Date of Patent: April 8, 2014
    Assignee: Birchwood Laboratories, Inc.
    Inventors: William V. Block, David J. Halverson, John Thanh Ngoc Nguyen
  • Patent number: 8287663
    Abstract: A process for forming a magnetite coating on a ferrous metal surface and for chemical reagents used to implement the coating process. The process comprises the step of making the ferrous metal surface more reactive by contacting the surface with an activating reagent and then contacting the activated surface with an oxidizing reagent to form the coating at a relatively low temperature range. The surface is activated by contact with an acid solution to form a surface rich in reactive iron. The activated surface is then oxidized by contact with an aqueous reagent of alkali metal hydroxide, alkali metal nitrate, alkali metal nitrite, and mixtures thereof.
    Type: Grant
    Filed: May 17, 2011
    Date of Patent: October 16, 2012
    Assignee: Birchwood Laboratories, Inc.
    Inventors: William V. Block, Bryce D. Devine
  • Publication number: 20110308668
    Abstract: A process for forming a magnetite coating on a ferrous metal surface and for chemical reagents used to implement the coating process. The process comprises the step of making the ferrous metal surface more reactive by contacting the surface with an activating reagent and then contacting the activated surface with an oxidizing reagent to form the coating at a relatively low temperature range. The surface is activated by contact with an acid solution to form a surface rich in reactive iron. The activated surface is then oxidized by contact with an aqueous reagent of alkali metal hydroxide, alkali metal nitrate, alkali metal nitrite, and mixtures thereof.
    Type: Application
    Filed: May 17, 2011
    Publication date: December 22, 2011
    Inventors: William V. Block, Bryce D. Devine
  • Patent number: 7964044
    Abstract: A process for forming a magnetite coating on a ferrous metal surface and for chemical reagents used to implement the coating process. The process comprises the step of making the ferrous metal surface more reactive by contacting the surface with an activating reagent and then contacting the activated surface with an oxidizing reagent to form the coating at a relatively low temperature range. The surface is activated by contact with an acid solution to form a surface rich in reactive iron. The activated surface is then oxidized by contact with an aqueous reagent of alkali metal hydroxide, alkali metal nitrate, alkali metal nitrite, and mixtures thereof.
    Type: Grant
    Filed: October 28, 2004
    Date of Patent: June 21, 2011
    Assignee: Birchwood Laboratories, Inc.
    Inventors: William V. Block, Bryce D. Devine
  • Patent number: 7625439
    Abstract: The ferrous metal chemical conversion coating is comprised of mixed oxides and organometallic compounds of aluminum and iron. A ferrous metal substrate is immersed for a period of time in a bath composition, at a temperature, at a pH, and at a concentration for each constituent of the bath composition, that will form a coating with the desired characteristics. The bath composition comprises water, aluminum salt, oxalic acid, and an oxidizer. The conversion coating is amorphous in nature and can be formed as thin as 1 micron with a coating weight in the range of about 40-250 milligrams per square foot. When sealed with an appropriate rust preventive material, the coating enhances corrosion resistance of the ferrous metal substrate. It is an effective absorbent base for paint finishes. When top coated with a lubricant, the conversion coating aids (a) assembly of parts, (b) break-in of sliding surfaces, and (c) anti-galling.
    Type: Grant
    Filed: September 27, 2006
    Date of Patent: December 1, 2009
    Assignee: Birchwood Laboratories, Inc.
    Inventors: Bryce D. Devine, William V. Block
  • Publication number: 20090280258
    Abstract: The present invention relates to methods and compositions for coating aluminum substrates. In an embodiment, the invention includes a method of applying a coating on an aluminum substrate including contacting the aluminum substrate with a first solution. The first solution can include a zinc metal salt, a sugar acid or alkali metal salt thereof, and an alkali metal hydroxide. The method can also include contacting the aluminum substrate with a second solution. The second solution can include a molybdate salt, an alkanolamine, and a fluorine acid. Other embodiments are also included herein.
    Type: Application
    Filed: May 6, 2009
    Publication date: November 12, 2009
    Inventors: William V. Block, David J. Halverson, John Thanh Ngoc Nguyen
  • Patent number: 7481872
    Abstract: The ferrous metal chemical conversion coating is comprised of mixed oxides and organometallic compounds of aluminum and iron. A ferrous metal substrate is immersed for a period of time in a bath composition, at a temperature, at a pH, and at a concentration for each constituent of the bath composition, that will form a coating with the desired characteristics. The bath composition comprises water, aluminum salt, oxalic acid, and an oxidizer. The conversion coating is amorphous in nature and can be formed as thin as 1 micron with a coating weight in the range of about 40-250 milligrams per square foot. When sealed with an appropriate rust preventive material, the coating enhances corrosion resistance of the ferrous metal substrate. It is an effective absorbent base for paint finishes. When top coated with a lubricant, the conversion coating aids (a) assembly of parts, (b) break-in of sliding surfaces, and (c) anti-galling.
    Type: Grant
    Filed: September 27, 2006
    Date of Patent: January 27, 2009
    Assignee: Birchwood Laboratories, Inc.
    Inventors: Bryce D. Devine, William V. Block
  • Patent number: 7144599
    Abstract: The ferrous metal chemical conversion coating is comprised of mixed oxides and organometallic compounds of aluminum and iron. A ferrous metal substrate is immersed for a period of time in a bath composition, at a temperature, at a pH, and at a concentration for each constituent of the bath composition, that will form a coating with the desired characteristics. The bath composition comprises water, aluminum salt, oxalic acid, and an oxidizer. The conversion coating is amorphous in nature and can be formed as thin as 1 micron with a coating weight in the range of about 40–250 milligrams per square foot. When sealed with an appropriate rust preventive material, the coating enhances corrosion resistance of the ferrous metal substrate. It is an effective absorbent base for paint finishes. When top coated with a lubricant, the conversion coating aids (a) assembly of parts, (b) break-in of sliding surfaces, and (c) anti-galling.
    Type: Grant
    Filed: July 15, 2004
    Date of Patent: December 5, 2006
    Assignee: Birchwood Laboratories, Inc.
    Inventors: William V. Block, Bryce D. Devine
  • Patent number: 6899769
    Abstract: This invention is a method for forming a chemical conversion coating on ferrous metal substrates, the chemical solutions used in the coating and the articles coated thereby. By modifying and combining the features of two existing, but heretofore unrelated, coating technologies, a hybrid conversion coating is formed. Specifically, a molecular iron/oxygen-enriched intermediate coating, such as a dicarboxylate or phosphate, is applied to a ferrous substrate by a first oxidation. The intermediate coating pre-conditions the substrate to form a surface rich in molecular iron and oxygen in a form easily accessible for further reaction. This oxidation procedure is followed by a coloring procedure using a heated (about 120-220 F) oxidizing solution containing alkali metal hydroxide, alkali metal nitrate, alkali metal nitrite or mixtures thereof, which reacts with the iron and oxygen enriched intermediate coating to form magnetite (Fe3O4).
    Type: Grant
    Filed: August 9, 2002
    Date of Patent: May 31, 2005
    Assignee: Birchwood Laboratories, Inc.
    Inventors: Keith N. Ravenscroft, William V. Block
  • Patent number: 6899956
    Abstract: This invention includes improvements to a method for forming a chemical conversion coating on ferrous metal substrates, to the chemical solutions used in the coating and to the articles coated thereby. A first oxidation applies a molecular iron/oxygen-enriched intermediate coating, such as a dicarboxylate or phosphate, to a ferrous substrate. A coloring procedure (a second oxidation) follows the first oxidation procedure, using a heated oxidizing solution that reacts with the iron and oxygen enriched intermediate coating to form magnetite (Fe3O4). The result is the formation of a brown or black finish. An appropriate rust preventive topcoat may seal the substrate. The finish affords protection, a degree of lubricity to aid assembly, break-in of sliding surfaces, provides anti-galling protection and an adherent base for paint finishes.
    Type: Grant
    Filed: May 3, 2002
    Date of Patent: May 31, 2005
    Assignee: Birchwood Laboratories, Inc.
    Inventors: William V. Block, Bryce D. Devine
  • Publication number: 20040250748
    Abstract: This invention is a method for forming a chemical conversion coating on ferrous metal substrates, the chemical solutions used in the coating and the articles coated thereby. By modifying and combining the features of two existing, but heretofore unrelated, coating technologies, a hybrid conversion coating is formed. Specifically, a molecular iron/oxygen-enriched intermediate coating, such as a dicarboxylate or phosphate, is applied to a ferrous substrate by a first oxidation. The intermediate coating pre-conditions the substrate to form a surface rich in molecular iron and oxygen in a form easily accessible for further reaction. This oxidation procedure is followed by a coloring procedure using a heated (about 120-220 F) oxidizing solution containing alkali metal hydroxide, alkali metal nitrate, alkali metal nitrite or mixtures thereof, which reacts with the iron and oxygen enriched intermediate coating to form magnetite (Fe3O4).
    Type: Application
    Filed: May 5, 2004
    Publication date: December 16, 2004
    Inventors: Keith N. Ravenscroft, William V. Block
  • Patent number: 6695931
    Abstract: This invention is a method for forming a chemical conversion coating on ferrous metal substrates, the chemical solutions used in the coating and the articles coated thereby. By modifying and combining the features of two existing, but heretofore unrelated, coating technologies, a hybrid conversion coating is formed. Specifically, a molecular iron/oxygen-enriched intermediate coating, such as a dicarboxylate or phosphate, is applied to a ferrous substrate by a first oxidation. The intermediate coating pre-conditions the substrate to form a surface rich in molecular iron and oxygen in a form easily accessible for further reaction. This oxidation procedure is followed by a coloring procedure using a heated (about 120-220° F.) oxidizing solution containing alkali metal hydroxide, alkali metal nitrate, alkali metal nitrite or mixtures thereof, which reacts with the iron and oxygen enriched intermediate coating to form magnetite (Fe3O4).
    Type: Grant
    Filed: January 2, 2003
    Date of Patent: February 24, 2004
    Assignee: Birchwood Laboratories, Inc.
    Inventors: Keith N. Ravenscroft, William V. Block
  • Publication number: 20030205298
    Abstract: This invention includes improvements to a method for forming a chemical conversion coating on ferrous metal substrates, to the chemical solutions used in the coating and to the articles coated thereby. A first oxidation applies a molecular iron/oxygen-enriched intermediate coating, such as a dicarboxylate or phosphate, to a ferrous substrate. A coloring procedure (a second oxidation) follows the first oxidation procedure, using a heated oxidizing solution that reacts with the iron and oxygen enriched intermediate coating to form magnetite (Fe3O4). The result is the formation of a brown or black finish. An appropriate rust preventive topcoat may seal the substrate. The finish affords protection, a degree of lubricity to aid assembly, break-in of sliding surfaces, provides anti-galling protection and an adherent base for paint finishes.
    Type: Application
    Filed: May 3, 2002
    Publication date: November 6, 2003
    Inventors: William V. Block, Bryce D. Devine
  • Patent number: 6576346
    Abstract: This invention is a method for forming a chemical conversion coating on ferrous metal substrates, the chemical solutions used in the coating and the articles coated thereby. By modifying and combining the features of two existing, but heretofore unrelated, coating technologies, a hybrid conversion coating is formed. Specifically, a molecular iron/oxygen-enriched intermediate coating, such as a dicarboxylate or phosphate, is applied to a ferrous substrate by a first oxidation. The intermediate coating pre-conditions the substrate to form a surface rich in molecular iron and oxygen in a form easily accessible for further reaction. This oxidation procedure is followed by a coloring procedure using a heated (about 120-220° F.) oxidizing solution containing alkali metal hydroxide, alkali metal nitrate, alkali metal nitrite or mixtures thereof, which reacts with the iron and oxygen enriched intermediate coating to form magnetite (Fe3O4).
    Type: Grant
    Filed: November 10, 2000
    Date of Patent: June 10, 2003
    Assignee: Birchwood Laboratories, Inc.
    Inventors: Keith N. Ravenscroft, William V. Block
  • Publication number: 20030079807
    Abstract: This invention is a method for forming a chemical conversion coating on ferrous metal substrates, the chemical solutions used in the coating and the articles coated thereby. By modifying and combining the features of two existing, but heretofore unrelated, coating technologies, a hybrid conversion coating is formed. Specifically, a molecular iron/oxygen-enriched intermediate coating, such as a dicarboxylate or phosphate, is applied to a ferrous substrate by a first oxidation. The intermediate coating pre-conditions the substrate to form a surface rich in molecular iron and oxygen in a form easily accessible for further reaction. This oxidation procedure is followed by a coloring procedure using a heated (about 120-220 F.) oxidizing solution containing alkali metal hydroxide, alkali metal nitrate, alkali metal nitrite or mixtures thereof, which reacts with the iron and oxygen enriched intermediate coating to form magnetite (Fe3O4).
    Type: Application
    Filed: August 9, 2002
    Publication date: May 1, 2003
    Inventors: Keith N. Ravenscroft, William V. Block
  • Patent number: 6527873
    Abstract: This invention is a method for forming a chemical conversion coating on ferrous metal substrates, the chemical solutions used in the coating and the articles coated thereby. By modifying and combining the features of two existing, but heretofore unrelated, coating technologies, a hybrid conversion coating is formed. Specifically, a molecular iron/oxygen-enriched intermediate coating, such as a dicarboxylate or phosphate, is applied to a ferrous substrate by a first oxidation. The intermediate coating pre-conditions the substrate to form a surface rich in molecular iron and oxygen in a form easily accessible for further reaction. This oxidation procedure is followed by a coloring procedure using a heated (about 120-220 F.) oxidizing solution containing alkali metal hydroxide, alkali metal nitrate, alkali metal nitrite or mixtures thereof, which reacts with the iron and oxygen enriched intermediate coating to form magnetite (Fe3O4).
    Type: Grant
    Filed: August 9, 2002
    Date of Patent: March 4, 2003
    Assignee: Birchwood Laboratories, Inc.
    Inventors: Keith N. Ravenscroft, William V. Block
  • Publication number: 20030022007
    Abstract: This invention is a method for forming a chemical conversion coating on ferrous metal substrates, the chemical solutions used in the coating and the articles coated thereby. By modifying and combining the features of two existing, but heretofore unrelated, coating technologies, a hybrid conversion coating is formed. Specifically, a molecular iron/oxygen-enriched intermediate coating, such as a dicarboxylate or phosphate, is applied to a ferrous substrate by a first oxidation. The intermediate coating pre-conditions the substrate to form a surface rich in molecular iron and oxygen in a form easily accessible for further reaction. This oxidation procedure is followed by a coloring procedure using a heated (about 120-220 F) oxidizing solution containing alkali metal hydroxide, alkali metal nitrate, alkali metal nitrite or mixtures thereof, which reacts with the iron and oxygen enriched intermediate coating to form magnetite (Fe3O4).
    Type: Application
    Filed: August 9, 2002
    Publication date: January 30, 2003
    Inventors: Keith N. Ravenscroft, William V. Block
  • Patent number: 6309476
    Abstract: This invention is a method for forming a chemical conversion coating on ferrous metal substrates, the chemical solutions used in the coating and the articles coated thereby. By modifying and combining the features of two existing, but heretofore unrelated, coating technologies, a hybrid conversion coating is formed. Specifically, a molecular iron/oxygen-enriched intermediate coating, such as a dicarboxylate or phosphate, is applied to a ferrous substrate by a first oxidation. The intermediate coating pre-conditions the substrate to form a surface rich in molecular iron and oxygen in a form easily accessible for further reaction. This oxidation procedure is followed by a coloring procedure using a heated (about 120-220° F.) oxidizing solution containing alkali metal hydroxide, alkali metal nitrate, alkali metal nitrite or mixtures thereof, which reacts with the iron and oxygen enriched intermediate coating to form magnetite (Fe3O4).
    Type: Grant
    Filed: May 24, 1999
    Date of Patent: October 30, 2001
    Assignee: Birchwood Laboratories, Inc.
    Inventors: Keith N. Ravenscroft, William V. Block