Abstract: A lighting apparatus that includes a light source and a phosphor composition radiationally coupled to the light source is presented. The phosphor composition includes a first phosphor that includes a phase of general formula (I): L3ZO4(Br2-nXn):Eu2+ wherein 0?n?1; L is Zn, Mg, Ca, Sr, Ba, or combinations thereof; Z is Si, Ge, or a combination thereof; and X is F, Cl, I, or combinations thereof.

Abstract: A method includes obtaining a potassium hexafluorosilicate (PFS)-based powder, obtaining a fluidization material, and mixing the PFS-based powder with the fluidization material to form a PFS-based mixture. The PFS-based mixture is configured to be mixed with a resinous material to form a flowing phosphor blend configured to be placed onto a light source to form a phosphor on the light source.

Abstract: A method includes mixing a first fluoride phosphor powder that is doped with tetravalent manganese with a treatment solution for a designated period of time, stopping the mixing to allow the fluoride phosphor powder to settle, removing at least some liquid that has separated from the first fluoride phosphor powder, repeating (a) the mixing, (b) the stopping of the mixing, and (c) removing at least some of the liquid during one or more additional cycles, and obtaining a second fluoride phosphor powder following the repeating of the mixing, the stopping of the mixing, and the removing of at least some of the liquid. The second fluoride phosphor powder includes a reduced amount of the manganese relative to the first fluoride phosphor powder.

Abstract: A lighting apparatus includes a semiconductor light source in direct contact with a polymer composite comprising a color stable Mn4+ doped phosphor, wherein the lighting apparatus has a color shift of 1.5 MacAdam ellipses after operating for at least 2,000 hour at a LED current density greater than 2 A/cm2, a LED wall-plug efficiency greater than 40%, and a board temperature greater than 25° C.

Abstract: Coating systems suitable for use in generating fluorescent visible light, and lamps provided with such coating systems. The coating systems includes a phosphor-containing coating that contains at least a first phosphor that is predominantly excited by ultraviolet radiation of a first wavelength to emit visible light and absorbs but is less efficiently excited by ultraviolet radiation of a second wavelength. The coating system further includes a second phosphor that absorbs the ultraviolet radiation of the second wavelength and little if any of the ultraviolet radiation of the first wavelength.

Abstract: Blue and green-emitting Eu2+-activated oxyhalide phosphors of formula A-E may be used in devices for lighting or display applications: A. M3SiO3X4:Eu2+; B. M5Si3O9X4:Eu2+; C. M1.64Si0.82O3.1X0.36:Eu2+; D. M10Si3O9X14:Eu2+; E. M2SiO3X2:Eu2+; and wherein M is Ba, Ca, Sr, or a mixture thereof; X is Cl or Br, or a mixture thereof.

Abstract: A phosphor composition is disclosed. A phosphor composition, comprises at least 10 atomic % bromine; silicon, germanium or combination thereof; oxygen; a metal M, wherein M comprises zinc (Zn), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), or combinations thereof; and an activator comprising europium. The phosphor composition is formed from combining carbonate or oxides of metal M, silicon oxide, and europium oxide; and then firing the combination. A lighting apparatus including the phosphor composition is also provided. The phosphor composition may be combined with an additional phosphor to generate white light.

Abstract: A method includes obtaining particles of a phosphor precursor of formula Ax[MFy]:Mn4+, reducing sizes of the particles of the phosphor precursor by wet milling the particles and annealing the particles that are wet milled by contacting the particles with a fluorine-containing oxidizing agent. Additionally, a manganese doped complex fluoride phosphor prepared by this method is provided. A lighting apparatus and backlight device that include manganese-doped phosphor prepared by this method also are provided.

Abstract: In an embodiment, the disclosure provides a light source comprising at least one solid state light emitter. The light source, in operation, emits substantially white light having a Lighting Preference Index (LPI) of at least about 105, and this emission from the light source comprises a UV-violet flux of at least about 1%. Use of the lamps, light sources, and methods of the present disclosure may afford the ability to display linens and clothing under energy-efficient LED-based illumination, and may impart an effect to (especially white) clothing, that makes them look cleaner than under illumination by prior art LED lamps.

Abstract: Light sources that emit light having enhanced color spectrum characteristics are described. A color metric called the Lighting Preference Index (LPI) is disclosed that enables quantitative optimization of color preference by tailoring the spectral power distribution of the light source. In an embodiment, a lamp includes at least one blue light source having peak wavelength in the range of about 400 nanometer (nm) to about 460 nm, at least one green or yellow-green light source having peak wavelength in the range of about 500 nm to about 580 nm, and at least one red light source having peak wavelength in the range of about 600 nm to about 680 nm, wherein the lamp has an LPI of at least 120.

Abstract: Coating systems suitable for use in fluorescent lamps, particularly as scattering agents within a UV-reflecting coating for the purpose of improving fluorescent lamp luminosity. Such a coating system is provided on a transparent or translucent substrate and includes a phosphor coating and a scattering agent that scatters UV rays. The scattering agent includes an inorganic powder present in a separate UV-reflecting layer adjacent the phosphor coating and/or dispersed in the phosphor coating so that the scattered UV rays are absorbed by the phosphor coating and cause the phosphor coating to emit visible light. The inorganic powder exhibits low or no absorption to UV rays having wavelengths of 185 nm and 254 nm and is not reactive with mercury.

Abstract: A process for preparing a color stable Mn4+ doped complex fluoride phosphor of formula I includes Ax(M(1?m), Mnm)Fy??(I) contacting a first aqueous HF solution comprising (1?m) parts of a compound of formula HxMFy, and a second aqueous HF solution comprising m*n parts of a compound of formula Ax[MnFy], with a third aqueous HF solution comprising (1?n) parts of the compound of formula Ax[MnFy] and a compound of formula AaX, to yield a precipitate comprising the color stable Mn4+ doped complex fluoride phosphor; wherein A is Li, Na, K, Rb, Cs, NR4 or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; R is H, lower alkyl, or a combination thereof; X is an anion; a is the absolute value of the charge of the X anion; x is the absolute value of the charge of the [MFy] ion; y is 5, 6 or 7; 0<m?0.05; 0.1?n?1.

Abstract: A phosphor composition is disclosed. A phosphor composition, comprises at least 10 atomic % bromine; silicon, germanium or combination thereof; oxygen; a metal M, wherein M comprises zinc (Zn), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), or combinations thereof; and an activator comprising europium. The phosphor composition is formed from combining carbonate or oxides of metal M, silicon oxide, and europium oxide; and then firing the combination. A lighting apparatus including the phosphor composition is also provided. The phosphor composition may be combined with an additional phosphor to generate white light.

Abstract: A phosphor composition is presented. The phosphor composition includes a first phosphor that includes a phase of general formula (I): L3ZO4(Br2-nXn):Eu2+?? (I) wherein 0?n?1; L is Zn, Mg, Ca, Sr, Ba, or combinations thereof; Z is Si, Ge, or a combination thereof; and X is F, Cl, I, or combinations thereof. A lighting apparatus that includes a light source and the phosphor composition radiationally coupled to the light source is also presented.

Abstract: A method of forming a phosphor composition is disclosed. The method includes mixing co-precipitated yttrium-europium oxalate with an inorganic flux material to form an oxalate-flux mixture; and heating the oxalate-flux mixture at a temperature in a range from about 800° C. to about 1400° C., to form the phosphor composition. The phosphor has a general formula of (Y1-x-yAyEux)2O3 with 0<x<1 and 0?y<1, wherein A is at least one element selected from the group consisting of gadolinium, lutetium, lanthanum, scandium and terbium.

Abstract: A lighting apparatus having a phosphor material radiationally coupled to a light source is presented. The phosphor material includes a green emitting phosphor composition of general formula I: R3?x?zMxCezT5?yNyO12?x?yFx+y; where 0?x<3.0; 0?y<5.0, 0<z?0.30; and if x=0, then y>0 or if y=0, then x>0; R is Y, Tb, Gd, La, Lu or a combination thereof; T is Al, Sc, Ga, In or combinations thereof; M is Ca, Sr, Ba or a combination thereof; N is Mg, Zn or a combination thereof. The phosphor composition of formula I may be combined with an additional phosphor to generate white light.

Abstract: A green emitting phosphor composition is disclosed. A phosphor composition of formula Ca1-xEuxAlB3O7, where 0<x<0.5 is formed from combining calcium carbonate, boron oxide, aluminum oxide, and europium oxide; and then firing the combination. A lighting apparatus including the phosphor composition is also provided. The phosphor composition may be combined with an additional phosphor to generate white light.

Abstract: A process for preparing a Mn+4 doped phosphor of formula I Ax[MFy]:Mn+4?? I includes gradually adding a first solution to a second solution and periodically discharging the product liquor from the reactor while volume of the product liquor in the reactor remains constant; wherein A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; y is 5, 6 or 7. The first solution includes a source of M and HF and the second solution includes a source of Mn to a reactor in the presence of a source of A.

Abstract: Processes for producing particles of rare earth-containing phosphor materials, in which the particles have a core-shell structure and the shell has a lower rare earth content than the core. Such a process may include contacting a core particle with a precursor comprising Na(La,Ce,Tb)P2O7 to form a mixture, and then heating the mixture to a temperature sufficient to decompose the Na(La,Ce,Tb)P2O7 to evolve and melt an NaPO3 flux and initiate deposition of a (La,Ce,Tb)PO4 shell on each core particle in the presence of the molten NaPO3 flux.

Abstract: Phosphor-containing coating compositions and methods capable of changing the lumen maintenance characteristics of phosphor-containing coatings and fluorescent lamps that utilize such coatings. Lumen maintenance of a fluorescent lamp can be modified by forming a phosphor-containing coating to contain at least a first phosphor that depreciates during operation of the fluorescent lamp, and forming the phosphor-containing coating to further contain an additive composition in a sufficient amount and sufficiently uniformly distributed in the phosphor-containing coating to inhibit depreciation of the first phosphor during operation of the fluorescent lamp.