Abstract: Disclosed are a solid electrolyte and method of manufacturing the same. The solid electrolyte may include a core including a first electrolyte represented by Chemical Formula 1, and a shell including a second electrolyte represented by Chemical Formula 2, and disposed on a surface of the core. LiaPSbX1c??[Chemical Formula 1] Here, a satisfies an equation 4?a?7, b satisfies an equation 3?b?7, c satisfies an equation 0?c?2, and X1 includes Br or I. LidPSeX2f??[Chemical Formula 2] Here, d satisfies an equation 4?d?7, e satisfies an equation 3?e?7, f satisfies an equation 0?f?2, X2 includes Cl or Br, and an ionic radius of X1 is greater than an ionic radius of X2.

Abstract: A method for preparing a lithium ion conductive sulfide, which is capable of independently controlling the elemental ratio of lithium (Li), phosphorus (P), sulfur (S), etc, is provided. The method for preparing a lithium ion conductive sulfide can provide a lithium ion conductive sulfide having a crystal structure and an anion cluster distribution distinguished from those of existing ones.

Abstract: A method for preparing a sulfide-based solid electrolyte which is stable upon exposure to the air is provided. Specifically, a stabilization layer is formed on the surface of a sulfide-based solid electrolyte particle through treatment with a reactive gas. The sulfide-based solid electrolyte with superior air stability can be obtained because oxidation or reduction reactions with water, etc. in the air occur on the stabilization layer rather than on the sulfide-based solid electrolyte particle.

Abstract: A method for preparing a sulfide-based solid electrolyte which is stable upon exposure to the air is provided. Specifically, a stabilization layer is formed on the surface of a sulfide-based solid electrolyte particle through treatment with a reactive gas. The sulfide-based solid electrolyte with superior air stability can be obtained because oxidation or reduction reactions with water, etc. in the air occur on the stabilization layer rather than on the sulfide-based solid electrolyte particle.

Abstract: A method for preparing a lithium ion conductive sulfide, which is capable of independently controlling the elemental ratio of lithium (Li), phosphorus (P), sulfur (S), etc, is provided. The method for preparing a lithium ion conductive sulfide can provide a lithium ion conductive sulfide having a crystal structure and an anion cluster distribution distinguished from those of existing ones.