Patents by Inventor Wolfgang Holderich

Wolfgang Holderich has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9676705
    Abstract: A compound of the formula SbxFe1Oy (I) in which x varies from 0.4 to 1 inclusive and y varies from 1.6 to 4 inclusive, may be used as a catalyst for catalyzing the ammoxidation reaction of an alcohol of following formula (II) CH2?C(R1)—CH2—OH (II) in which R1 represents a hydrogen atom or a methyl radical, to give nitrile of following formula (III) CH2?C(R1)—C?N (III) in which R1 has the same meaning as in above formula (II), the said reaction being carried out in the gas phase, the said gas phase comprising at least oxygen and ammonia. The present invention also relates to the process for the ammoxidation of an alcohol of formula (II) employing a compound of formula (I) as catalyst.
    Type: Grant
    Filed: April 16, 2014
    Date of Patent: June 13, 2017
    Assignees: ECOLE CENTRALE DE LILLE, UNIVERSITE DES SCIENCES ET TECHNOLOGIES D
    Inventors: Sebastien Paul, Benjamin Katryniok, Franck Dumeignil, Carsten Liebig, Wolfgang Holderich, Cyrille Guillon
  • Patent number: 9346819
    Abstract: A simple, low cost, environmentally friendly and sustainable process for the production of internal dehydration products of hydrogenated sugar, implementing trivalent metal phosphate (metal (III) phosphates) as catalysts during the dehydratation step.
    Type: Grant
    Filed: August 7, 2013
    Date of Patent: May 24, 2016
    Assignee: ROQUETTE FRERES
    Inventors: Mathias Ibert, Herve Wyart, Wolfgang Holderich, Oana-Alice Rusu P.
  • Publication number: 20160023995
    Abstract: A compound of the formula SbxFe1Oy (1) in which x varies from 0.4 to 1 inclusive and y varies from 1.6 to 4 inclusive, may be used as a catalyst for catalysing the ammoxidation reaction of an alcohol of following formula (II) CH2?C(R1)—CH2—OH (II) in which R1 represents a hydrogen atom or a methyl radical, to give nitrile of following formula (III) CH2?C(R1)—C?N (III) in which R1 has the same meaning as in above formula (ii), the said reaction being carried out in the gas phase, the said gas phase comprising at least oxygen and ammonia. The present invention also relates to the process for the ammoxidation of an alcohol of formula (II) employing a compound of formula (I) as catalyst.
    Type: Application
    Filed: April 16, 2014
    Publication date: January 28, 2016
    Inventors: Sebastien Paul, Benjamin Katryniok, Franck Dumeignil, Carsten Liebig, Wolfgang Holderich, Cyrille Guillon
  • Publication number: 20150183796
    Abstract: A simple, low cost, environmentally friendly and sustainable process for the production of internal dehydration products of hydrogenated sugar, implementing trivalent metal phosphate (metal (III) phosphates) as catalysts during the dehydratation step.
    Type: Application
    Filed: August 7, 2013
    Publication date: July 2, 2015
    Inventors: Mathias Ibert, Herve Wyart, Wolfgang Holderich, Oana-Alice Rusu P.
  • Patent number: 8921605
    Abstract: Use of pure lanthanum oxide which is obtained by calcination of oxygen-containing lanthanum salts at temperatures of at least 700° C. as heterogeneous catalyst in the aldol condensation of citral and acetone to give pseudoionone, and process for the preparation of pseudoionone by aldol condensation of citral and acetone in the liquid phase using pure lanthanum oxide.
    Type: Grant
    Filed: July 19, 2011
    Date of Patent: December 30, 2014
    Assignee: DSM IP Assets B.V.
    Inventors: Wolfgang Hölderich, Verena Ritzerfeld, Bernhard Markus Ernst Russbüldt, Erhard Henning Fleischhauer, Werner Bonrath, Reinhard Karge, Jan Schütz
  • Publication number: 20130310607
    Abstract: Use of pure lanthanum oxide which is obtained by calcination of oxygen-containing lanthanum salts at temperatures of at least 700° C. as heterogeneous catalyst in the aldol condensation of citral and acetone to give pseudoionone, and process for the preparation of pseudoionone by aldol condensation of citral and acetone in the liquid phase using pure lanthanum oxide.
    Type: Application
    Filed: July 19, 2011
    Publication date: November 21, 2013
    Applicant: DSM IP ASSETS B.V.
    Inventors: Wolfgang Hölderich, Verena Ritzerfeld, Bernhard Markus Ernst Russbüldt, Erhard Henning Fleischhauer, Werner Bonrath, Reinhard Karge, Jan Schütz
  • Patent number: 7910771
    Abstract: The invention relates to a method for producing acrylic acid in one step by an oxydehydration reaction of glycerol in the presence of molecular oxygen. The reaction preferably carried out in gaseous phase in the presence of a suitable catalyst.
    Type: Grant
    Filed: April 24, 2006
    Date of Patent: March 22, 2011
    Assignee: Arkema France
    Inventors: Jean-Luc Dubois, Christophe Duquenne, Wolfgang Holderich
  • Patent number: 7893255
    Abstract: The present invention relates to a process for the preparation of lauryllactam in which a Beckmann rearrangement of cyclododecanone oxime is carried out. Said process is carried out in the gas phase at a temperature of between 180 and 450° C. in the presence of a microporous material having a three-dimensional inorganic main structure composed of tetrahedra connected via a common edge, called zeolite.
    Type: Grant
    Filed: June 21, 2006
    Date of Patent: February 22, 2011
    Assignee: Arkema France
    Inventors: Eric Lacroix, Serge Hub, Wolfgang Holderich, Wilm Eickelberg, Francois Fajula, Francesco DiRenzo, Markus Brandhorst
  • Patent number: 7655818
    Abstract: The present invention relates to a process for manufacturing acrolein by gas-phase dehydration of glycerol in the presence of strongly acidic solid catalysts with a Hammett acidity H0 of between ?9 and ?18 and preferably between ?10 and ?16.
    Type: Grant
    Filed: January 6, 2006
    Date of Patent: February 2, 2010
    Assignee: Arkema France
    Inventors: Jean-Luc Dubois, Christophe Duquenne, Wolfgang Holderich, Jacques Kervennal
  • Publication number: 20080214836
    Abstract: The present invention relates to a process for the preparation of lauryllactam in which a Beckmann rearrangement of cyclododecanone oxime is carried out. Said process is carried out in the gas phase at a temperature of between 180 and 450° C. in the presence of a microporous material having a three-dimensional inorganic main structure composed of tetrahedra connected via a common edge, called zeolite.
    Type: Application
    Filed: June 21, 2006
    Publication date: September 4, 2008
    Inventors: Eric Lacroix, Serge Hub, Wolfgang Holderich, Wilm Eickelberg, Francois Fajula, Francesco DiRenzo, Markus Brandhorst
  • Publication number: 20080183013
    Abstract: The invention relates to a method for producing acrylic acid in one step by an oxydehydration reaction of glycerol in the presence of molecular oxygen. The reaction is preferably carried out in gaseous phase in the presence of a suitable catalyst.
    Type: Application
    Filed: April 24, 2006
    Publication date: July 31, 2008
    Applicant: Arkema France
    Inventors: Jean-Luc Dubois, Christophe Duquenne, Wolfgang Holderich
  • Patent number: 7396962
    Abstract: The present invention relates to a process for manufacturing acrolein by dehydration of glycerol in the presence of molecular oxygen. The reaction is performed in the liquid phase or in the gas phase in the presence of a solid catalyst. The addition of oxygen makes it possible to obtain good glycerol conversion by inhibiting the deactivation of the catalyst and the formation of by-products.
    Type: Grant
    Filed: January 6, 2006
    Date of Patent: July 8, 2008
    Assignee: Arkema France
    Inventors: Jean-Luc Dubois, Christophe Duquenne, Wolfgang Holderich
  • Publication number: 20080146852
    Abstract: The present invention relates to a process for manufacturing acrolein by dehydration of glycerol in the presence of molecular oxygen. The reaction is performed in the liquid phase or in the gas phase in the presence of a solid catalyst. The addition of oxygen makes it possible to obtain good glycerol conversion by inhibiting the deactivation of the catalyst and the formation of by-products.
    Type: Application
    Filed: January 6, 2006
    Publication date: June 19, 2008
    Applicant: Arkema France
    Inventors: Jean-Luc Dubois, Christophe Duquenne, Wolfgang Holderich
  • Patent number: 6229018
    Abstract: A process for the preparation of nicotinic acid by the direct oxidation of &bgr;-picoline in the gas phase, wherein water and &bgr;-picoline are fed separately to the catalyst bed and the catalyst is based on a titanium dioxide support which has been prepared by the sulfate method and has a high specific surface area and a vanadium oxide content of from 5 to 50 %.
    Type: Grant
    Filed: August 31, 1999
    Date of Patent: May 8, 2001
    Assignee: Degussa Aktiengesellschaft
    Inventors: Dieter Heinz, Wolfgang Hölderich, Steffen Krill, Wolfgang Böck, Klaus Huthmacher
  • Patent number: 6051706
    Abstract: A method is disclosed of producing .epsilon.-caprolactam by the Beckmann rearrangement of cyclohexanone oxime using (B) .beta. zeolites as catalyst.
    Type: Grant
    Filed: May 11, 1999
    Date of Patent: April 18, 2000
    Assignee: Degussa-Huls Aktiengesellschaft
    Inventors: Wolfgang Holderich, Georg Philip Heitmann, Dietrich Arntz
  • Patent number: 5968242
    Abstract: A molecular sieve, which contains in all, or only in some, of its cavities colorant molecules as well as a modifier which is covalently bound to said molecular sieve and which reduces its pore diameter, a process for its preparation as well as its use as pigment for coloring high molecular weight organic materials, preferably biopolymers and plastic materials, glasses, ceramic products, for formulations of decorative cosmetics, for the preparation of paint systems, preferably automotive lacquers, printing inks, dispersion paints and color filters as well as materials comprising the novel molecular sieves.
    Type: Grant
    Filed: December 19, 1997
    Date of Patent: October 19, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Wolfgang Holderich, Nadja Rohrlich, Laurent Chassot
  • Patent number: 5821391
    Abstract: A process for preparing 3-oxyalkylpropan-1-ols by catalytic hydrogenation of 1,3-dioxanes with catalysts comprising a hydrogenation-active component on an acid support.
    Type: Grant
    Filed: April 20, 1998
    Date of Patent: October 13, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Wolfgang Holderich, Marcus Paczkowski, Dieter Heinz, Thomas Kaiser
  • Patent number: 5780686
    Abstract: A process for preparing 4-oxa-amines comprising reacting 1,3-dioxanes with ammonia and hydrogen in the presence of hydrogenation catalysts.
    Type: Grant
    Filed: May 27, 1997
    Date of Patent: July 14, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Wolfgang Holderich, Marcus Paczkowski, Dieter Heinz
  • Patent number: 5780687
    Abstract: A process for preparing 3-oxyalkylpropan-l-ols by catalytic hydrogenation of 1,3-dioxanes with catalysts comprising a hydrogenation-active component on an acid support.
    Type: Grant
    Filed: May 27, 1997
    Date of Patent: July 14, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Wolfgang Holderich, Marcus Paczkowski, Dieter Heinz, Thomas Kaiser
  • Patent number: 5105022
    Abstract: Dialkoxyethenes of the formula ##STR1## where R.sup.1 to R.sup.4 are identical or different and are each straight-chain or branched alkyl or cycloalkyl or R.sup.2 and R.sup.3 may furthermore be hydrogen, aryl or alkenylaryl, and the aromatic may be substituted by further radicals, such as alkyl, alkoxy or halogens, are prepared by a process in which an alcohol of the formula R.sup.4 OH or R.sup.5 OH is eliminated from a trialkoxyethane of the formula (II) ##STR2## where R.sup.1 to R.sup.4 have the above meanings and R.sup.5 is straight-chain or branched alkyl or cycloalkyl, in the presence of a zeolite and/or a phosphate and/or phosphoric acid or boric acid on a carrier and/or an acidic, untreated metal oxide as a catalyst. Zeolites of the pentasil type are preferably used as catalysts.
    Type: Grant
    Filed: September 11, 1990
    Date of Patent: April 14, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Wolfgang Holderich, KoDieter, Werner Bertleff