Patents by Inventor Wolfgang Holderich
Wolfgang Holderich has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 9676705Abstract: A compound of the formula SbxFe1Oy (I) in which x varies from 0.4 to 1 inclusive and y varies from 1.6 to 4 inclusive, may be used as a catalyst for catalyzing the ammoxidation reaction of an alcohol of following formula (II) CH2?C(R1)—CH2—OH (II) in which R1 represents a hydrogen atom or a methyl radical, to give nitrile of following formula (III) CH2?C(R1)—C?N (III) in which R1 has the same meaning as in above formula (II), the said reaction being carried out in the gas phase, the said gas phase comprising at least oxygen and ammonia. The present invention also relates to the process for the ammoxidation of an alcohol of formula (II) employing a compound of formula (I) as catalyst.Type: GrantFiled: April 16, 2014Date of Patent: June 13, 2017Assignees: ECOLE CENTRALE DE LILLE, UNIVERSITE DES SCIENCES ET TECHNOLOGIES DInventors: Sebastien Paul, Benjamin Katryniok, Franck Dumeignil, Carsten Liebig, Wolfgang Holderich, Cyrille Guillon
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Patent number: 9346819Abstract: A simple, low cost, environmentally friendly and sustainable process for the production of internal dehydration products of hydrogenated sugar, implementing trivalent metal phosphate (metal (III) phosphates) as catalysts during the dehydratation step.Type: GrantFiled: August 7, 2013Date of Patent: May 24, 2016Assignee: ROQUETTE FRERESInventors: Mathias Ibert, Herve Wyart, Wolfgang Holderich, Oana-Alice Rusu P.
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Publication number: 20160023995Abstract: A compound of the formula SbxFe1Oy (1) in which x varies from 0.4 to 1 inclusive and y varies from 1.6 to 4 inclusive, may be used as a catalyst for catalysing the ammoxidation reaction of an alcohol of following formula (II) CH2?C(R1)—CH2—OH (II) in which R1 represents a hydrogen atom or a methyl radical, to give nitrile of following formula (III) CH2?C(R1)—C?N (III) in which R1 has the same meaning as in above formula (ii), the said reaction being carried out in the gas phase, the said gas phase comprising at least oxygen and ammonia. The present invention also relates to the process for the ammoxidation of an alcohol of formula (II) employing a compound of formula (I) as catalyst.Type: ApplicationFiled: April 16, 2014Publication date: January 28, 2016Inventors: Sebastien Paul, Benjamin Katryniok, Franck Dumeignil, Carsten Liebig, Wolfgang Holderich, Cyrille Guillon
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Publication number: 20150183796Abstract: A simple, low cost, environmentally friendly and sustainable process for the production of internal dehydration products of hydrogenated sugar, implementing trivalent metal phosphate (metal (III) phosphates) as catalysts during the dehydratation step.Type: ApplicationFiled: August 7, 2013Publication date: July 2, 2015Inventors: Mathias Ibert, Herve Wyart, Wolfgang Holderich, Oana-Alice Rusu P.
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Patent number: 8921605Abstract: Use of pure lanthanum oxide which is obtained by calcination of oxygen-containing lanthanum salts at temperatures of at least 700° C. as heterogeneous catalyst in the aldol condensation of citral and acetone to give pseudoionone, and process for the preparation of pseudoionone by aldol condensation of citral and acetone in the liquid phase using pure lanthanum oxide.Type: GrantFiled: July 19, 2011Date of Patent: December 30, 2014Assignee: DSM IP Assets B.V.Inventors: Wolfgang Hölderich, Verena Ritzerfeld, Bernhard Markus Ernst Russbüldt, Erhard Henning Fleischhauer, Werner Bonrath, Reinhard Karge, Jan Schütz
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Publication number: 20130310607Abstract: Use of pure lanthanum oxide which is obtained by calcination of oxygen-containing lanthanum salts at temperatures of at least 700° C. as heterogeneous catalyst in the aldol condensation of citral and acetone to give pseudoionone, and process for the preparation of pseudoionone by aldol condensation of citral and acetone in the liquid phase using pure lanthanum oxide.Type: ApplicationFiled: July 19, 2011Publication date: November 21, 2013Applicant: DSM IP ASSETS B.V.Inventors: Wolfgang Hölderich, Verena Ritzerfeld, Bernhard Markus Ernst Russbüldt, Erhard Henning Fleischhauer, Werner Bonrath, Reinhard Karge, Jan Schütz
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Patent number: 7910771Abstract: The invention relates to a method for producing acrylic acid in one step by an oxydehydration reaction of glycerol in the presence of molecular oxygen. The reaction preferably carried out in gaseous phase in the presence of a suitable catalyst.Type: GrantFiled: April 24, 2006Date of Patent: March 22, 2011Assignee: Arkema FranceInventors: Jean-Luc Dubois, Christophe Duquenne, Wolfgang Holderich
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Patent number: 7893255Abstract: The present invention relates to a process for the preparation of lauryllactam in which a Beckmann rearrangement of cyclododecanone oxime is carried out. Said process is carried out in the gas phase at a temperature of between 180 and 450° C. in the presence of a microporous material having a three-dimensional inorganic main structure composed of tetrahedra connected via a common edge, called zeolite.Type: GrantFiled: June 21, 2006Date of Patent: February 22, 2011Assignee: Arkema FranceInventors: Eric Lacroix, Serge Hub, Wolfgang Holderich, Wilm Eickelberg, Francois Fajula, Francesco DiRenzo, Markus Brandhorst
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Patent number: 7655818Abstract: The present invention relates to a process for manufacturing acrolein by gas-phase dehydration of glycerol in the presence of strongly acidic solid catalysts with a Hammett acidity H0 of between ?9 and ?18 and preferably between ?10 and ?16.Type: GrantFiled: January 6, 2006Date of Patent: February 2, 2010Assignee: Arkema FranceInventors: Jean-Luc Dubois, Christophe Duquenne, Wolfgang Holderich, Jacques Kervennal
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Publication number: 20080214836Abstract: The present invention relates to a process for the preparation of lauryllactam in which a Beckmann rearrangement of cyclododecanone oxime is carried out. Said process is carried out in the gas phase at a temperature of between 180 and 450° C. in the presence of a microporous material having a three-dimensional inorganic main structure composed of tetrahedra connected via a common edge, called zeolite.Type: ApplicationFiled: June 21, 2006Publication date: September 4, 2008Inventors: Eric Lacroix, Serge Hub, Wolfgang Holderich, Wilm Eickelberg, Francois Fajula, Francesco DiRenzo, Markus Brandhorst
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Publication number: 20080183013Abstract: The invention relates to a method for producing acrylic acid in one step by an oxydehydration reaction of glycerol in the presence of molecular oxygen. The reaction is preferably carried out in gaseous phase in the presence of a suitable catalyst.Type: ApplicationFiled: April 24, 2006Publication date: July 31, 2008Applicant: Arkema FranceInventors: Jean-Luc Dubois, Christophe Duquenne, Wolfgang Holderich
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Patent number: 7396962Abstract: The present invention relates to a process for manufacturing acrolein by dehydration of glycerol in the presence of molecular oxygen. The reaction is performed in the liquid phase or in the gas phase in the presence of a solid catalyst. The addition of oxygen makes it possible to obtain good glycerol conversion by inhibiting the deactivation of the catalyst and the formation of by-products.Type: GrantFiled: January 6, 2006Date of Patent: July 8, 2008Assignee: Arkema FranceInventors: Jean-Luc Dubois, Christophe Duquenne, Wolfgang Holderich
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Publication number: 20080146852Abstract: The present invention relates to a process for manufacturing acrolein by dehydration of glycerol in the presence of molecular oxygen. The reaction is performed in the liquid phase or in the gas phase in the presence of a solid catalyst. The addition of oxygen makes it possible to obtain good glycerol conversion by inhibiting the deactivation of the catalyst and the formation of by-products.Type: ApplicationFiled: January 6, 2006Publication date: June 19, 2008Applicant: Arkema FranceInventors: Jean-Luc Dubois, Christophe Duquenne, Wolfgang Holderich
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Patent number: 6229018Abstract: A process for the preparation of nicotinic acid by the direct oxidation of &bgr;-picoline in the gas phase, wherein water and &bgr;-picoline are fed separately to the catalyst bed and the catalyst is based on a titanium dioxide support which has been prepared by the sulfate method and has a high specific surface area and a vanadium oxide content of from 5 to 50 %.Type: GrantFiled: August 31, 1999Date of Patent: May 8, 2001Assignee: Degussa AktiengesellschaftInventors: Dieter Heinz, Wolfgang Hölderich, Steffen Krill, Wolfgang Böck, Klaus Huthmacher
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Patent number: 6051706Abstract: A method is disclosed of producing .epsilon.-caprolactam by the Beckmann rearrangement of cyclohexanone oxime using (B) .beta. zeolites as catalyst.Type: GrantFiled: May 11, 1999Date of Patent: April 18, 2000Assignee: Degussa-Huls AktiengesellschaftInventors: Wolfgang Holderich, Georg Philip Heitmann, Dietrich Arntz
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Patent number: 5968242Abstract: A molecular sieve, which contains in all, or only in some, of its cavities colorant molecules as well as a modifier which is covalently bound to said molecular sieve and which reduces its pore diameter, a process for its preparation as well as its use as pigment for coloring high molecular weight organic materials, preferably biopolymers and plastic materials, glasses, ceramic products, for formulations of decorative cosmetics, for the preparation of paint systems, preferably automotive lacquers, printing inks, dispersion paints and color filters as well as materials comprising the novel molecular sieves.Type: GrantFiled: December 19, 1997Date of Patent: October 19, 1999Assignee: Ciba Specialty Chemicals CorporationInventors: Wolfgang Holderich, Nadja Rohrlich, Laurent Chassot
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Patent number: 5821391Abstract: A process for preparing 3-oxyalkylpropan-1-ols by catalytic hydrogenation of 1,3-dioxanes with catalysts comprising a hydrogenation-active component on an acid support.Type: GrantFiled: April 20, 1998Date of Patent: October 13, 1998Assignee: Hoechst AktiengesellschaftInventors: Wolfgang Holderich, Marcus Paczkowski, Dieter Heinz, Thomas Kaiser
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Patent number: 5780686Abstract: A process for preparing 4-oxa-amines comprising reacting 1,3-dioxanes with ammonia and hydrogen in the presence of hydrogenation catalysts.Type: GrantFiled: May 27, 1997Date of Patent: July 14, 1998Assignee: Hoechst AktiengesellschaftInventors: Wolfgang Holderich, Marcus Paczkowski, Dieter Heinz
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Patent number: 5780687Abstract: A process for preparing 3-oxyalkylpropan-l-ols by catalytic hydrogenation of 1,3-dioxanes with catalysts comprising a hydrogenation-active component on an acid support.Type: GrantFiled: May 27, 1997Date of Patent: July 14, 1998Assignee: Hoechst AktiengesellschaftInventors: Wolfgang Holderich, Marcus Paczkowski, Dieter Heinz, Thomas Kaiser
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Patent number: 5105022Abstract: Dialkoxyethenes of the formula ##STR1## where R.sup.1 to R.sup.4 are identical or different and are each straight-chain or branched alkyl or cycloalkyl or R.sup.2 and R.sup.3 may furthermore be hydrogen, aryl or alkenylaryl, and the aromatic may be substituted by further radicals, such as alkyl, alkoxy or halogens, are prepared by a process in which an alcohol of the formula R.sup.4 OH or R.sup.5 OH is eliminated from a trialkoxyethane of the formula (II) ##STR2## where R.sup.1 to R.sup.4 have the above meanings and R.sup.5 is straight-chain or branched alkyl or cycloalkyl, in the presence of a zeolite and/or a phosphate and/or phosphoric acid or boric acid on a carrier and/or an acidic, untreated metal oxide as a catalyst. Zeolites of the pentasil type are preferably used as catalysts.Type: GrantFiled: September 11, 1990Date of Patent: April 14, 1992Assignee: BASF AktiengesellschaftInventors: Wolfgang Holderich, KoDieter, Werner Bertleff