Abstract: Adhesive coating film consisting of a) a radiation-cured coat which comprises from 40 to 90% by weight, preferably from 50 to 60% by weight, of urethane acrylate, from 0 to 20% by weight, preferably from 10 to 15% by weight, of polyether acrylate, from 10 to 50% by weight, preferably from 25 to 40% by weight, of reactive diluent, from 0 to 30% by weight of pigments from 0 to 10% by weight, preferably from 2 to 5% by weight, of a carboxy-functional (meth)acrylic esther [sic], from 0 to 10% by weight of other customary coatings fillers, and in the case of curing with UV radiation, from 0 to 10% by weight, preferably from 3 to 6% by weight, of photoinitiator, and b) which carries on one side an adhesive composition which has free NCO groups in the freshly applied adhesive composition, can be plastified thermally, especially under the intended processing conditions, and has a markedly weak surface tack.

Abstract: The present invention relates to a radiation-curable binder BM consisting of a copolymer which is composed of: A) from 80 to 99% by weight of a hydroxyl-containing polyether acrylate and/or polyester acrylate A), which optionally contains a mono-, di- and/or polyamine AA) as adduct, and of B) from 1 to 20% by weight of benzophenonetetracarboxylic acid, its anhydrides and/or its esters. The invention additionally relates to processes for the preparation of the binder BM and to the use of the binders BM in radiation-curable coating compositions.

Abstract: The invention relates to a process for the preparation of articles with a three-dimensional surface structure, in which a substrate is printed, at least one of the printing inks employed for the printing being varnish-repellent, and the printed substrate is then varnished. In accordance with the invention, the printed substrate is varnished with a radiation-curable varnish which contains no amino resin and comprisesA) from 18 to 99.9% by weight of an epoxy acrylate, a polyether acrylate or a polyester acrylate,B) from 0.1 to 5.0% by weight of a Bronsted acid or an acid anhydride,C) from 0 [sic] to 12% by weight of a photoinitiator,D) from 0 to 40% by weight of water or at least one organic solvent,E) from 0 [sic] to 10% by weight of a polyol which may be ethoxylated and/or propoxylated and has from 2 to 50 carbon atoms in the molecule, andF) from 0 [sic] to 30% by weight of other auxiliaries and additives,and the varnish coat applied is cured with high-energy radiation.

Abstract: The present invention relates to an acrylicized polyetherpolyol that consists of an ethoxylated polyol having a molecular weight of from 600 to 1000, preferably from 700 to 900, which is esterified with acrylic acid.

Abstract: The invention relates to a process for the preparation of articles with a three-dimensional surface structure, in which a substrate is printed, at least one of the printing inks employed for the printing being varnish-repellent, and the printed substrate is then varnished. In accordance with the invention, the printed substrate is varnished with a radiation-curable varnish which contains no amino resin and comprisesA) from 18 to 99.9% by weight of an epoxy acrylate, a polyether acrylate or a polyester acrylate,B) from 0.1 to 5.0% by weight of a Bronsted acid or an acid anhydride,C) from 0 ?sic! to 12% by weight of a photoinitiator,D) from 0 to 40% by weight of water or at least one organic solvent,E) from 0 ?sic! to 10% by weight of a polyol which may be ethoxylated and/or propoxylated and has from 2 to 50 carbon atoms in the molecule, andF) from 0 ?sic! to 30% by weight of other auxiliaries and additives,and the varnish coat applied is cured with high-energy radiation.

Abstract: The invention relates to powder coatings which are characterized in that they contain as film-forming material a mixture of(A) from 19.9 to 90.0 percent by weight of a synthetic resin which contains epoxide groups and may contain ethylenically unsaturated double bonds, or of a mixture of such epoxide group-containing synthetic resins,(B) from 9.9 to 80.0 percent by weight of a compound which contains carboxyl groups and may contain ethylenically unsaturated double bonds, or of a mixture of such carboxyl group-containing compounds,(C) from 0 to 20 percent by weight of a compound which contains ethylenically unsaturated double bonds and is different from (A) and (B), or of a mixture of such compounds, and(D) from 0.1 to 3.0 percent by weight of an initiator for free-radical polymerizations or of a mixture of initiators for free-radical polymerizations,the percentages by weight of (A)+(B)+(C)+(D) being=200% by weight and the mixture of components (A), (B), (C) and (D) containing from 0.1 to 6.

Abstract: The invention relates to a process for the production of two-coat finishes, in which a pigmented basecoat is first applied, the resulting basecoat film is coated with a powder clearcoat, and basecoat and clearcoat are subsequently baked together. In accordance with the invention, the powder clearcoat employed is a powder coating which contains an epoxide group-containing polyacrylate resin as binder and a mixture of (A) a polyanhydride and (B) a carboxyl group-containing polyester resin as crosslinking agent. The polyester resin can be prepared by reacting a diol (b1), a compound (b2) which contains per molecule at least three functional groups selected from hydroxyl, primary amino, secondary amino, carboxyl and acid anhydride groups, and (b3) a dicarboxylic acid in a molar ratio of (b1): (b2): (b3)=0.0 to 3.0: 1.0: 1.5 to 9.0 to give a polyester resin having an acid value of 40 to 300.

Abstract: The invention relates to a process for the preparation of powder coatings, in which a mixture ofA) a binder comprising an epoxide group-containing synthetic resin or a mixture of epoxide group-containing synthetic resins, andB) a crosslinking agent comprising a compound which contains on statistical average at least two carboxyl groups and at least one acid anhydride group per molecule, or a mixture of such compounds, is admixed before or during the melt homogenization process withC) a polyol or a mixture of polyols in such an amount that from 0.1 to 0.9 hydroxyl groups of component C) are present per acid anhydride group of component B).The mixture is homogenized in the molten state and the resulting homogenized melt, after having cooled and solidified, is powdered.