Abstract: The invention relates to a method of recovering molybdenum from a molybdenum bearing sulfide material. The material is contacted with a leaching solution in the presence of iron compounds and mesophilic or thermophilic iron oxidizing microorganisms and subsequently, a leaching process is performed by controlling the molar ratio of dissolved ferric iron to dissolved molybdenum. Preferably, a high amount and molar excess of dissolved iron is used. The presence of high concentrations of ferric iron in bioleach solutions allows iron-oxidizing microorganisms to grow and oxidize iron and bioleach molybdenite at dissolved Mo concentrations as high as 4.4 g/L. Organic metabolites were not required for protecting cells from Mo toxicity. Maximum dissolution rates depend on reactor configuration, with agglomerated material simulating heap leaching of almost 1% Mo/day, but up to 10.2% Mo/day in suspension/stirred reactor configurations, with rate highly dependent on temperature within the range of 25° C. to 40° C.

Abstract: The invention relates to a method of recovering molybdenum from a molybdenum bearing sulfide material. The material is contacted with a leaching solution in the presence of iron compounds and mesophilic or thermophilic iron oxidizing microorganisms and subsequently, a leaching process is performed by controlling the molar ratio of dissolved ferric iron to dissolved molybdenum. Preferably, a high amount and molar excess of dissolved iron is used. The presence of high concentrations of ferric iron in bioleach solutions allows iron-oxidizing microorganisms to grow and oxidize iron and bioleach molybdenite at dissolved Mo concentrations as high as 4.4 g/L. Organic metabolites were not required for protecting cells from Mo toxicity. Maximum dissolution rates depend on reactor configuration, with agglomerated material simulating heap leaching of almost 1% Mo/day, but up to 10.2% Mo/day in suspension/stirred reactor configurations, with rate highly dependent on temperature within the range of 25° C. to 40° C.

Abstract: The present invention relates to calix[4]arenes which effectively bind alkali metal ions (Na+, K+) and transport them over phase boundaries, their preparation and use.

Abstract: The present invention relates to calix[4]arenes which effectively bind alkali metal ions (Na+, K+) and transport them over phase boundaries, their preparation and use.

Abstract: The invention concerns a process and an apparatus for producing hollow bodies of thermoplastic material by means of extrusion blow molding. A tubular preform of plasticised material is expanded beyond parts of a blow molding mold enclosing it, by means of increased external pressure, wherein the preform, prior to closure of the mold halves, is spread transversely with respect to the extrusion direction and in a separation plane of the blow molding mold, in such a way that it extends between the lateral edges of the mold cavity of the blow molding mold. Prior to removal of the article from the blow molding mold, the bulge portion produced after closure of the blow molding mold is cut open along its length at each of the two sides of the mold at the respective edges extending in the extrusion direction.

Abstract: A process for the production of dish-shaped moldings or hollow bodies of thermoplastic material comprises the step of producing an at least approximately tubular preform by the extrusion of thermoplastic material. The preform is axially divided to form at least one single-layer web of material which is removed from the extrusion head by being engaged by means of a manipulator which spreads and/or straightens the web transversely with respect to the extrusion direction. The web is then transferred to a molding tool by a manipulator for it to be put into its final form in its first heat in the molding tool.

Abstract: The invention concerns a process and an apparatus for producing hollow bodies of thermoplastic material by means of extrusion blow molding. A tubular preform of plasticised material is expanded beyond parts of a blow molding mold enclosing it, by means of increased external pressure, wherein the preform, prior to closure of the mold halves, is spread transversely with respect to the extrusion direction and in a separation plane of the blow molding mold, in such a way that it extends between the lateral edges of the mold cavity of the blow molding mold. Prior to removal of the article from the blow molding mold, the bulge portion produced after closure of the blow molding mold is cut open along its length at each of the two sides of the mold at the respective edges extending in the extrusion direction.

Abstract: The invention relates to a method for producing lithium-transition metal mixtures of general formula Lix(M1yM21-y)nOnz, wherein M1 represents nickel, cobalt or manganese, M2 represents chromium, cobalt, iron, manganese, molybdenum or aluminium, and is different from M1, n is 2 if M1 represents manganese and is 1 otherwise, x is comprised between 0.9 and 1.2, y is comprised between 0.5 and 1.0 and z is comprised between 1.9 and 2.1. According to the inventive method, an intimate mixture composed of transition metal compounds containing oxygen and of a lithium compound containing oxygen is calcinated, said mixture being obtained by processing a solid powder transition metal compound with a solution of said lithium compound, and then drying. At least the M1 compound is used in powder form having a specific surface of at least 20 m2/g (BET) and calcination is carried out in a fluidised bed.

Abstract: High purity ammonium dimolybdate or molybdenum oxide is produced by the pressure oxidation of low grade molybdenite concentrates or molybdenum intermediates. The process entails nearly complete oxidation of the sulfide minerals while optimizing the process chemistry and autoclave conditions to solubilize as little of the molybdenum values as possible. The autoclave discharge 12 is then subjected to a leaching step, either an alkaline leach 50, 400 or ammonium leach 250 process, before or after a liquid/solid separation step 20, 220, 410. The solution is then subjected to (a) filtration 60, 410, solvent extraction 70, 440, crystallization 90, 450, and calcination 120, 480 or (b) filtration 260, 280, crystallization 290, and calcination 320 to produce a product suitable for chemical-grade molybdenum oxide 125, 325, 485.

Abstract: High purity ammonium dimolybdate or molybdenum oxide is produced by the pressure oxidation of low grade molybdenite concentrates or molybdenum intermediates. The process entails nearly complete oxidation of the sulfide minerals while optimizing the process chemistry and autoclave conditions to solubilize as little of the molybdenum values as possible. The autoclave discharge 12 is then subjected to a leaching step, either an alkaline leach 50, 400 or ammonium leach 250 process, before or after a liquid/solid separation step 20, 220, 410. The solution is then subjected to (a) filtration 60, 410, solvent extraction 70, 440, crystallization 90,450, and calcination 120, 480 or (b) filtration 260, 280, crystallization 290, and calcination 320 to produce a product suitable for chemical-grade molybdenum oxide 125, 325, 485.

Abstract: A process for the production of dish-shaped moldings or hollow bodies of thermoplastic material comprises the step of producing an at least approximately tubular preform by the extrusion of thermoplastic material. The preform is axially divided to form at least one single-layer web of material which is removed from the extrusion head by being engaged by means of a manipulator which spreads and/or straightens the web transversely with respect to the extrusion direction. The web is then transferred to a molding tool by a manipulator for it to be put into its final form in its first heat in the molding tool.

Abstract: High purity ammonium dimolybdate or molybdenum oxide is produced by the pressure oxidation of low grade molybdenite concentrates or molybdenum intermediates. The process entails nearly complete oxidation of the sulfide minerals while optimizing the process chemistry and autoclave conditions to solubilize as little of the molybdenum values as possible. The autoclave discharge 12 is then subjected to a leaching step, either an alkaline leach 50, 400 or ammonium leach 250 process, before or after a liquid/solid separation step 20, 220, 410. The solution is then subjected to (a) filtration 60, 410, solvent extraction 70, 440, crystallization 90,450, and calcination 120, 480 or (b) filtration 260, 280, crystallization 290, and calcination 320 to produce a product suitable for chemical-grade molybdenum oxide 125, 325, 485.

Abstract: A method for cleaning surfaces made of concrete, asphalt or similar, especially airport runways, road surfaces, the floors of halls or similar. In order to clean and remove soiling substances, such as rubber, oil, fat, carbon particles or similar, which adhere to a surface, a cleaning agent resulting in the dissolution or detachment of said soiling substances is applied to the surface in question, whereupon a rinsing fluid, especially water, is subsequently used to rinse the surface and to remove the dissolved soiling substances therewith and collected in at least one collector. The cleaning which occurs is quick and devoid of any abrasive effect on a covering coat or wearing coat of the surface to be cleaned. The inventive cleaning agent is made of an aqueous emulsion, containing at least one upper methyl, ethyl, isopropyl carboxylate and at least one multivalent alcohol.

Abstract: The invention relates to a method for producing lithium transition metalates of the general formula (I): Lix(M1yM21−y)nOnz, where M1 represents lithium, cobalt or manganese; M2 represents cobalt, iron, manganese or aluminium and is not equal to M1; n is equal to 2 if M1=M, and 1 in all other cases; x is a number between 0.9 and 1.2; y is a number between 0.5 and 1.0; and z is a number between 1.9 and 2.1. According to the method, an intimate solid mixture is produced of oxygen-containing compounds of the transition metals and oxygen-containing lithium compounds and this mixture calcinated in a reactor, whereby calcination takes place at least partly at an absolute pressure of less than 0.5 bar.

Abstract: The present invention relates to a method for the decomposition of superalloys and subsequent recovery of the metallic constituents.

Abstract: A molybdenum metal powder having an outer shell coating of MoO.sub.2 is useful in flame spray or plasma spray processes and is prepared by partially oxidizing molybdenum powder in a carbon dioxide atmosphere at temperatures of up to 1200.degree. C.

Abstract: A molybdenum metal powder having an outer shell coating of MoO.sub.2 is useful in flame spray or plasma spray processes and is prepared by partially oxidizing molybdenum powder in a carbon dioxide atmosphere at temperatures of up to 1200.degree. C.