Patents by Inventor Wolfgang Merk
Wolfgang Merk has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 4667044Abstract: Aromatic mono or polycarboxylic acid glycidyl esters are obtained in good yields and high purity by transesterification of the corresponding aromatic carboxylic acid alkyl esters with glycidol in the presence of weakly toxic catalysts, namely the alkali, ammonium, and alkaline earth metal salts of pseudohalogen hydride acids with readily polarizable anions.Type: GrantFiled: May 28, 1982Date of Patent: May 19, 1987Assignee: Degussa AktiengesellschaftInventors: Friedbert Nees, Peter Werle, Gunther Reissmann, Wolfgang Merk
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Patent number: 4501668Abstract: There are employed water soluble low molecular weight polycondensation products produced by the condensation of acrolein and formaldehyde in a molar ratio between 1:1 and 1:10 in aqueous or aqueous-organic medium in the presence of a basic catalyst for the elimination of hydrogen sulfide and iron sulfide present in aqueous systems. The condensation reaction can also be carried out in the additional presence of water soluble monohydric or polyhydric alcohols and/or acid amides.Type: GrantFiled: December 6, 1983Date of Patent: February 26, 1985Assignee: Degussa AktiengesellschaftInventors: Wolfgang Merk, Karl-Heinz Rink
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Patent number: 4501840Abstract: Pentaerythritol is treated at a temperature of about 180.degree. to 220.degree. C. with a strongly alkaline acting material, e.g. calcium oxide. The thus treated pentaerythritol serves as a costabilizer e.g., with the salt of a polyvalent metal and a carboxylic acid, for a vinyl chloride resin, e.g. polyvinyl chloride and has outstanding properties as such.Type: GrantFiled: October 20, 1983Date of Patent: February 26, 1985Assignee: Degussa AktiengesellschaftInventors: Peter Werle, Wolfgang Merk
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Patent number: 4492643Abstract: There is described new alkylene bismelamines and their production. They correspond to the formula ##STR1## in which o is a number from 10 to 18. Alkylene bismelamines serve as stabilizers for formaldehyde solutions and as such have an outstanding suitability and activity.Type: GrantFiled: November 1, 1982Date of Patent: January 8, 1985Assignee: Degussa AktiengesellschaftInventors: Peter Werle, Holger Focke, Klaus Popp, Wolfgang Merk
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Patent number: 4479820Abstract: There are employed as biocides for aqueous systems water soluble low molecular weight polycondensation products which are produced from acrolein and formaldehyde in the molar ratio between 1:1 and 1:10 in aqueous or aqueous-organic medium in the presence of a basic catalyst. The condensation reaction can also be carried out in the additional presence of water soluble mono- or polyhydric alcohols and/or acid amides.Type: GrantFiled: February 8, 1983Date of Patent: October 30, 1984Assignee: Degussa AkteingesellschaftInventors: Wolfgang Merk, Karl-Heinz Rink
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Patent number: 4405783Abstract: Pure hydroxypropyltheophylline is produced by the catalytic reaction of theophylline with glycidol in the presence of a hydroxide of a short chain alcoholate of an alkali metal or an alkali metal salt of a pseudohydrohalic acid which has a readily polarizable anion. The catalyst is suitably employed in an amount between 0.01 and 0.2 moles per mole of theophylline. The dihydroxypropyltheophylline is obtained directly in the reaction in a high purity.Type: GrantFiled: June 14, 1982Date of Patent: September 20, 1983Assignees: Degussa Aktiengesellschaft, Degussa AktiengesellschaftInventors: Volker Binder, Wolfgang Merk, Peter Werle
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Patent number: 4390732Abstract: Guaiacol glycerine ether is obtained in very good yield and in very high purity by reacting glycidol with o-methyoxyphenol in the presence of an alkali hydroxide, an alkali alcoholate, an alkali cyanate or an alkali thiocyanate at 80.degree. to 150.degree. C. An especially effective purification of the crude product can be obtained by adding hydrogen peroxide, preferably prior to cooling.Type: GrantFiled: February 10, 1982Date of Patent: June 28, 1983Assignee: Degussa AGInventors: Wolfgang Merk, Rudolf M. Wagner, Peter Werle, Robert S. Nygren
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Patent number: 4389333Abstract: There are described new bisguanamines of the formula ##STR1## where n is a number from 10 to 20 and their production. The bisguanamines are stabilizers for formaldehyde solutions and have outstanding qualifications and action for this purpose.Type: GrantFiled: February 5, 1982Date of Patent: June 21, 1983Assignee: Degussa AktiengesellschaftInventors: Peter Werle, Wolfgang Merk, Gerhard Pohl, Friedhelm Hoevels
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Patent number: 4339578Abstract: There are described new bisguanamines of the formula ##STR1## where n is a number from 10 to 20 and their production. The bisguanamines are stabilizers for formaldehyde solutions and have outstanding qualifications and action for this purpose.Type: GrantFiled: May 5, 1980Date of Patent: July 13, 1982Assignee: Degussa AktiengesellschaftInventors: Peter Werle, Wolfgang Merk, Gerhard Pohl, Friedhelm Hoevels
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Patent number: 4189550Abstract: There are used as antistatic agents for thermoplastic synthetic resins compounds of the formulae ##STR1## where R and R' are saturated alkyl groups in which the sum of the carbon atoms in the two alkyl groups is 4 to 30 carbon atoms and wherein one of R and R' can be hydrogen,R.sup.2 is hydrogen, lower alkyl with one to 5 carbon atoms, 2-hydroxyethyl, 2-hydroxypropyl, 2,3-dihydroxypropyl, benzyl o-,m- and/or p-methylbenzyl, o-,m- and/or p-chlorobenzyl, o-,m- and/or p-bromobenzyl, aminoalkyl (C.sub.2 to C.sub.6), preferably aminoalkyl (C.sub.2 and C.sub.3), alkyl (C.sub.1 to C.sub.6)-amino-alkyl (C.sub.2 to C.sub.6), 2-hydroxyethyl-aminoalkyl (C.sub.2 to C.sub.6), 2-hydroxypropyl-aminoalkyl (C.sub.2 to C.sub.6) or 2,3-dihydroxypropyl-aminoalkyl (C.sub.2 to C.sub.6),R.sup.3 in case the compound is present as the ammonium salt is hydrogen or a lower alkyl group with 1 to 5 carbon atoms,R.sup.4 is hydrogen or hydroxyl, andX.sup.Type: GrantFiled: July 27, 1977Date of Patent: February 19, 1980Assignees: Deutsche Gold- und Silber-Scheindeanstalt vormals Roessler, Henkel & Cie GmbHInventors: Werner Schwarze, Wolfgang Merk, Volker Binder
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Patent number: 4090024Abstract: Skatylhydantoin is prepared by hydrogenation of indolalhydantoin in the presence of a solvent and a hydrogenation catalyst wherein the solvent is a compound of the formula ##STR1## or a mixture of (I) and (II) and in which either R.sub.1 to R.sub.3 are hydrogen or R.sub.1 is hydrogen or a straight or branched chain alkyl group with 1 to 6 carbon atoms and R.sub.2 and R.sub.3 each are straight or branched chain alkyl groups with 1 to 8 carbon atoms or an aryl group, or R.sub.2 and R.sub.3 together are a straight or branched chain alkylene group with 2 to 8 carbon atoms; or one of R.sub.2 and R.sub.3 is hydrogen and R.sub.1 and R.sub.2 or R.sub.3 are joined to form a straight or branched chain alkylene group with 2 to 8 carbon atoms; and R.sub.4 to R.sub.7 each are straight or branched chain alkyl groups with 1 to 8 carbon atoms, an aryl group, an alkaryl group or an aralkyl group, or two of the substituents R.sub.4 to R.sub.Type: GrantFiled: February 3, 1977Date of Patent: May 16, 1978Assignee: Deutsche Gold- und Silber-Scheideanstalt Vormals RoesslerInventors: Wolfgang Merk, Gerd Schreyer, Horst Weigel
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Patent number: 4083872Abstract: There are prepared compounds of the formulae ##STR1## where R and R.sup.1 are saturated alkyl groups in which the sum of the carbon atoms in the two alkyl groups is 4 to 30 carbon atoms and wherein one of R and R.sup.1 can be hydrogen,R.sup.2 is hydrogen, lower alkyl with one to five carbon atoms, 2-hydroxyethyl, 2-hydroxypropyl, 2,3-dihydroxypropyl, benzyl,o-,m- or p-methylbenzyl, o-,m- or p-chlorobenzyl, o-,m- or p-bromobenzyl, aminoalkyl (C.sub.2 to C.sub.6), preferably aminoalkyl (C.sub.2 and C.sub.3), alkyl (C.sub.1 to C.sub.5)-aminoalkyl (C.sub.2 to C.sub.6), 2-hydroxyethyl-aminoalkyl (C.sub.2 to C.sub.6), 2-hydroxypropyl-aminoalkyl (C.sub.2 to C.sub.6) or 2,3-dihydroxy-propyl-aminoalkyl (C.sub.2 to C.sub.6),R.sup.3 in case the compound is present as the ammonium salt is hydrogen or a lower alkyl group with 1 to 5 carbon atoms, andX- is a monovalent, inorganic or organic acid group or one equivalent of a polybasic inorganic or organic group.Type: GrantFiled: January 30, 1976Date of Patent: April 11, 1978Assignees: Deutsche Gold- und Silber-Scheideanstalt vormals Roessler, Henkel Kommandit- Gesellschaft auf Aktien (Henkel KGaA)Inventors: Werner Schwarze, Wolfgang Merk, Volker Binder
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Patent number: 4070531Abstract: There are used as antistatic agents for thermoplastic synthetic resins compounds of the formulae ##STR1## where R and R' are saturated alkyl groups in which the sum of the carbon atoms in the two alkyl groups is 4 to 30 carbon atoms and wherein one of R and R' can be hydrogen,R.sup.2 is hydrogen, lower alkyl with one to 5 carbon atoms, 2-hydroxyethyl, 2-hydroxypropyl, 2,3-dihydroxypropyl, benzyl o-,m- and/or p-methylbenzyl, o-,m- and/or p-chlorobenzyl, o-,m- and/or p-bromobenzyl, aminoalkyl (C.sub.2 to C.sub.6), preferably aminoalkyl (C.sub.2 and C.sub.3), alkyl (C.sub.1 to C.sub.6)-aminoalkyl (C.sub.2 to C.sub.6), 2-hydroxyethyl-aminoalkyl (C.sub.1 to C.sub.6), 2-hydroxypropyl-aminoalkyl (C.sub.2 to C.sub.6) or 2,3-dihydroxypropyl-aminoalkyl (C.sub.2 to C.sub.6),R.sup.3 in case the compound is present as the ammonium salt is hydrogen or a lower alkyl group with 1 to 5 carbon atoms,R.sup.4 is hydrogen or hydroxyl, andX.sup.Type: GrantFiled: January 30, 1976Date of Patent: January 24, 1978Assignees: Deutsche Gold- und Silber-Scheideanstalt Vormals Roessler, Henkel & Cie. GmbHInventors: Werner Schwarze, Wolfgang Merk, Volker Binder
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Patent number: 4061869Abstract: There are prepared compounds of the formula ##STR1## where R and R.sup.1 are saturated and preferably linear alkyl groups in which the sum of carbon atoms in the two alkyl groups is 4 to 30,One of R and R.sup.1 can also be hydrogen,R.sup.2 is hydrogen or if R.sup.3 is hydrogen, thenR.sup.2 is the group ##STR2## where n is 1 to 10, R.sup.3 is hydrogen or, if R.sup.2 is hydrogen, thenR.sup.3 is the group ##STR3## and R.sup.4 is hydrogen or methyl.The compounds are useful as antistatic agents for thermoplastic resins.Type: GrantFiled: May 18, 1976Date of Patent: December 6, 1977Assignees: Deutsche Gold- und Silber-Scheideanstalt vormals Roessler, Henkel U. CieInventors: Werner Schwarze, Wolfgang Merk, Volker Binder