Patent number: 8809613
Abstract: The present invention relates to a method for preparing linear alpha-olefins (LAO) by oligomerization of ethylene in the presence of a solvent and homogeneous catalyst, comprising the steps of: (i) feeding ethylene, solvent and catalyst into an oligomerization reactor, (ii) oligomerizing the ethylene in the reactor, (iii) removing a reactor outlet stream comprising solvent, linear alpha-olefins, optionally unreacted ethylene and catalyst from the reactor via a reactor outlet piping system, (iv) dosing at least one additive selected from the group consisting of alcohols, poly-ethylene glycols, polyethylene glycol monoethers, polyethylene glycol diethers, polyamines, amines, amino alcohols and surfactants, (v) transferring the reactor outlet stream containing the additive to a catalyst deactivation and removal section, and (vi) deactivating the catalyst with caustic and removing the deactivated catalyst from the reactor outlet stream, wherein the residence time of the additive in the reactor outlet stream pri
Type:
Grant
Filed:
May 28, 2010
Date of Patent:
August 19, 2014
Assignees:
Saudi Basic Industries Corporation, Linde AG
Inventors:
Peter M. Fritz, Heinz Bölt, Andreas Meiswinkel, Carsten Taube, Florian Winkler, Volker Göke, Wolfgang Müller, Anina Wöhl, Richard Schneider, Uwe Rosenthal, Helmut Fritz, Bernd H. Müller, Normen Peulecke, Stephan Peitz, Bhaskar Reddy Aluri, Mohammed Al-Hazmi, Shahid Majeed Azam, Fuad Mosa, Abdullah Al-Dugathier
Publication number: 20120184692
Abstract: The present invention relates to a method for preparing linear alpha-olefins (LAO) by oligomerization of ethylene in the presence of a solvent and homogeneous catalyst, comprising the steps of: (i) feeding ethylene, solvent and catalyst into an oligomerization reactor, (ii) oligomerizing the ethylene in the reactor, (iii) removing a reactor outlet stream comprising solvent, linear alpha-olefins, optionally unreacted ethylene and catalyst from the reactor via a reactor outlet piping system, (iv) dosing at least one additive selected from the group consisting of alcohols, poly-ethylene glycols, polyethylene glycol monoethers, polyethylene glycol diethers, polyamines, amines, amino alcohols and surfactants, (v) transferring the reactor outlet stre con the additive to a catalyst deactivation and removal section, and (vi) deactivating the catalyst with caustic and removing the deactivated catalyst from the reactor outlet stream, wherein the residence time of the additive in the reactor outlet stream prior to m
Type:
Application
Filed:
May 28, 2010
Publication date:
July 19, 2012
Inventors:
Peter M. Fritz, Heinz Bölt, Andreas Meiswinkel, Carsten Taube, Florian Winkler, Volker Göke, Wolfgang Müller, Anina Wöhl, Richard Schneider, Uwe Rosenthal, Helmut Fritz, Bernd H. Müller, Normen Peulecke, Stephan Peitz, Bhaskar Reddy Aluri, MOhammed Al-Hazmi, Shahid Majeed Azam, Fuad Mosa, Abdullah Al-Dugathier