Patents by Inventor Wolfgang R. Balzer
Wolfgang R. Balzer has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 6146429Abstract: The dye carrier composition for oxidative dyeing of hair advantageously includes a combination of about 0.01 to 5 percent by weight of developer substance and about 0.01 to 5 percent by weight of coupler substance, from 0.1 to 10 percent by weight beeswax and from 0.1 to 10 percent by weight of one or more protein hydrolyzates and/or amino acids. The composition can also contain 0.1 to 30 weight percent of an non-ionic and/or anionic wetting agent or emulsifier and the protein hydrolyzates preferably include silk protein hydrolyzate and/or keratin hydrolyzate.Type: GrantFiled: May 11, 1998Date of Patent: November 14, 2000Assignee: Wella AktiengesellschaftInventors: Anette Gast, Petra Braun, Wolfgang R. Balzer, Herbert Deutz
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Patent number: 5888484Abstract: The creamy bleaching agent suspension is mixed with an oxidizing agent prior to applying it to the hair to form a composition for bleaching or decolorizing hair. This creamy bleaching agent suspension contains less than 2.5% by weight water and a mixture of at least one inorganic persalt, at least one alkaline reacting salt, from 0.5 to 20 percent by weight of a thickening substance, which consists essentially of an acrylic acid polymer and one or more cellulose, alginate and/or polysaccharide polymers, and from 26.5 to 35 percent by weight of at least one oil or wax, and, as needed, one or more cosmetic additive ingredient. From 0.1 to 3 percent by weight of the acrylic acid polymer must be present in the composition.Type: GrantFiled: October 28, 1996Date of Patent: March 30, 1999Assignee: Wella AGInventors: Manfred Schmitt, Holger Gottmann, Wolfgang R. Balzer, Hartmut Schiemann
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Patent number: 5766576Abstract: The oxidation hair dye composition for oxidative dyeing of hair is based on a combination of developer substance and coupler substance and contains at least one 3,4,5-triamino-pyrazole derivative compound selected from the group consisting of 1-methyl-3,4,5-triaminopyrazole, 3,5-diamino-1-methyl-4-methylaminopyrazole, 3,5-diamino-4-(2'-hydroxyethyl) amino-1-methylpyrazole and physiologically compatible, water-soluble salts of the foregoing pyrazole derivative compounds, as the developer substance. The invention also includes novel 3,4,5-triaminopyrazole derivative compounds.Type: GrantFiled: September 9, 1996Date of Patent: June 16, 1998Assignee: Wella AktiengesellschaftInventors: Isolde Lowe, Stefan Gerstung, Wolfgang R. Balzer
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Patent number: 5718731Abstract: The oxidation hair dye composition contains from 0.01 to 4.0 percent by weight of a developer substance including at least one diaminopyrazole of the formula (I) ##STR1## wherein R.sup.1 is selected from the group consisting of hydrogen, an alkyl group having from 1 to 6 carbon atoms, a hydroxyalkyl group having from 2 to 4 carbon atoms and a substituted or unsubstituted benzyl group, and R.sup.2 and R.sup.3, independently, are each selected from the group consisting of hydrogen, an alkyl group having from 1 to 6 carbon atoms and a hydroxyalkyl group having from 2 to 4 carbon atoms; and from 0.01 to 4.0 percent by weight of a coupler substance including at least one m-phenylenediamine selected from the group consisting of N-(3-dimethylamino)phenyl urea and 3-(N-methylsulfonyl)amino-N,N-dimethylaniline.Type: GrantFiled: August 13, 1996Date of Patent: February 17, 1998Assignee: Wella AktiengesellschaftInventors: Isolde Loewe, Alexa Weinges, Wolfgang R. Balzer, Stefan Gerstung
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Patent number: 5674476Abstract: The method of making a granulate composition for decolorizing or bleaching hair consists of preparing a powdery mixture consisting of from 30 to 65% by weight of one or more inorganic persulfates, from 1 to 20% by weight of a binding agent selected from the group consisting of polyvinylpyrrolidone and polyethylene glycols having molecular weights of 200 to 10,000; of 15 to 45% by weight of at least one salt selected from the group consisting of alkali metal carbonates, alkaline earth metal carbonates, alkali metal hydrogen carbonates, alkali metal silicates and from 0.Type: GrantFiled: March 8, 1996Date of Patent: October 7, 1997Assignee: Wella AktiengesellschaftInventors: Thomas Clausen, Wolfgang R. Balzer, Volker Port, Jolanthe Kujawa
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Patent number: 5663366Abstract: The subject matter of the present invention is directed to a process for producing 4,5-diaminopyrazole derivatives of the general formula (I) ##STR1## where R.sub.1 and R.sub.2 independently designate hydrogen, a C.sub.1 - to C.sub.6 -alkyl radical or a C.sub.2 - to C.sub.4 -hydroxyalkyl radical, which can be used as dye precursors, for example for hair dyes, and to new pyrazole derivatives.When using the process according to the invention good yields of isomer-pure 4,5-diaminopyrazole derivatives of general formula (I) can be obtained.Type: GrantFiled: May 20, 1996Date of Patent: September 2, 1997Assignee: Wella AktiengesellschatInventors: Hans Neunhoeffer, Stefan Gerstung, Thomas Clausen, Wolfgang R. Balzer
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Patent number: 5645610Abstract: The new coupler compounds of the invention are 4-amino-2 -(2'-hydroxyethyl)-amino-5-methoxytoluene and/or 4-amino-2-(2'-hydroxyethyl)amino-5-chlorotoluene. The invention also includes an oxidation hair dye composition including an effective amount, advantageously from 0.01 to 5 percent by weight, of the above-mentioned new coupler compounds together with one or more known developer compounds and optionally certain direct dyes.Type: GrantFiled: May 26, 1995Date of Patent: July 8, 1997Inventors: Wolfgang R. Balzer, Anke Frank, Alexa Weinges
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Patent number: 5637115Abstract: The oxidation hair dye composition consists of a combination of 0.01 to 10 percent by weight of one or more developer substances and 0.01 to 5 percent by weight of one or more coupler substances, and 0.01 to 2 percent by weight of one or more azo dye compounds of the formula I, A--N=N--B, wherein A is a p-aminophenyl group or a 3-pyridyl group and B is a 2,6-diamino-3-pyridyl group or a substituted 4-[N,N-bis-(2'-hydroxyethyl)amino]phenyl group of formula IV: ##STR1## wherein R is hydrogen, an alkyl group having from 1 to 6 carbon atoms, fluorine, chlorine, bromine or iodine; andone or more cosmetic additive selected from the group consisting of solvents, surfactants, antioxidants, thickeners, pH-adjusting compounds, hair care materials and additional dye components. The additional dye components can be 6-amino-2-methylphenol, 2-amino-5-methylphenol, triphenylmethane dye compounds and/or aromatic nitro dye compounds.Type: GrantFiled: January 16, 1996Date of Patent: June 10, 1997Assignee: Wella AktiengesellschatInventors: Wolfgang R. Balzer, Hans-Juergen Braun
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Patent number: 5542953Abstract: The composition for the oxidative dyeing of hair contains at least one coupler of the general formula ##STR1## where R is a straight-chain or branched C.sub.1 - to C.sub.4 -alkyl group, X is chlorine or fluorine, and R.sup.1 is a straight-chain or branched C.sub.1 - to C.sub.4 -alkyl group or a straight-chain or branched C.sub.2 - to C.sub.4 -hydroxyalkyl group. The 5-halogen-2,4-bis(alkylamino)-1-alkylbenzenes of the formula (I) are novel. The couplers of the general formula (I) may be obtained through simple chemical reactions, are easily soluble in water and have an outstanding shelf stability, in particular as a constituent of the hair dye composition described here. The dyeing results which can be achieved with the hair dye composition according to the invention are particularly distinguished by the color intensity of the red hues, in addition to the multitude of shades, and by a good purity of color with respect to blue hues.Type: GrantFiled: October 22, 1993Date of Patent: August 6, 1996Assignee: Wella AGInventors: Wolfgang R. Balzer, Thomas Clausen, Anke Frank, Alexa Weinges
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Patent number: 5534267Abstract: The composition for oxidative dyeing of hair based on a combination of developer substances and coupler substances, contains as a developer substance 4,5-diamino-1-(4'-methoxybenzyl)pyrazole, 4,5-diamino-1-(4'-methylbenzyl)pyrazole, 4,5-diamino-1-(4'-chlorobenzyl)pyrazole, 4,5-diamino-1-(3'-methoxybenzyl)pyrazole, 4-amino-1-(4'-methoxy-benzyl) -5-methylaminopyrazole or 4-amino-5-(2'-hydroxyethyl)amino-1-(4'-methoxybenzyl)pyrazole.Type: GrantFiled: June 7, 1994Date of Patent: July 9, 1996Assignee: Wella AktiengesellschaftInventors: Hans Neunhoeffer, Stefan Gerstung, Thomas Clausen, Wolfgang R. Balzer
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Patent number: 5430159Abstract: The hair dye composition includes at least one N-phenylaminopyrazole compound of the formula (V) ##STR1## wherein R.sup.1 is hydrogen, an alkyl group having from one to four carbon atoms or a hydroxyalkyl group having from two to four carbon atoms; R.sup.2 and R.sup.3 are each independently either a hydrogen, an amino groups or an alkyl group having from one to four carbon atoms; and R.sup.4 is hydrogen, an alkyl group having from one to four carbon atoms, an alkoxy group having from one to four carbon atoms or a halogen; and at least one conventional ingredient for hair dye compositions selected from the group consisting of emollients; preservatives; perfume oils; solvents; anionic, cationic, amphoteric and nonionic surfactants; thickeners; starch derivatives; cellulose derivatives; petrolatum; paraffin oil; fatty acids; conditioners; lanolin derivatives; cholesterol; pantothenic acid and betaines.Type: GrantFiled: May 9, 1994Date of Patent: July 4, 1995Assignee: Wella AktiengesellschaftInventors: Hans Neunhoeffer, Stefan Gerstung, Thomas Clausen, Wolfgang R. Balzer
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Patent number: 5409503Abstract: The composition for oxidative dyeing of hair contains 0.01 to 5.0 percent by weight of at least one 5-aminophenol compound of the formula ##STR1## wherein R is an alkyl group having 1 to 4 carbon atoms, X is fluorine or OR.sup.1 and R.sup.1 is an alkyl group having 2 to 4 carbon atoms, a monohydroxyalkyl group with 2 to 4 carbon atoms or a dihydroxyalkyl group with 3 and 4 carbon atoms, and physiologically tolerated water-soluble salts thereof as coupler substance; and 0.1 to 6.1 percent by weight of a total amount of the coupler substance and at least one developer substance. The developer substance can be 1,4-diaminobenzene, 2,5-diaminotoluene, 2,5-diaminobenzyl alcohol, 2-(2'-hydroxyethyl)-1,4-diaminobenzene, 4-aminophenol, 4-amino-3-methylphenol, 4-amino-2-methoxymethylphenol, 4-amino-2-ethoxy-methylphenol and tetraaminophyrimidine and physiologically tolerated water-soluble salts thereof.Type: GrantFiled: October 21, 1993Date of Patent: April 25, 1995Assignee: Wella AktiengesellschaftInventors: Thomas Clausen, Wolfgang R. Balzer, Helmut Keller
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Patent number: 5382702Abstract: Process for producing 5-alkoxy-2,4-dinitroalkylbenzenes of the general formula (I) ##STR1## R.sup.1 =C.sub.1 to C.sub.4 alkyl; R=C.sub.1 to C.sub.6 alkyl group, C.sub.2 to C.sub.4 hydroxyalkyl, C.sub.3 to C.sub.4 dihydroxyalkyl,in which a 3-fluoroalkylbenzene is nitrated and the obtained 2,4-dinitro-5-fluoroalkylbenzene is then reacted with a suitable alcohol at -5.degree. C. to +25.degree. C. with the addition of sodium hydroxide or potassium hydroxide.Type: GrantFiled: November 19, 1993Date of Patent: January 17, 1995Assignee: Wella AktiengesellschaftInventors: Wolfgang R. Balzer, Thomas Clausen, Alexa Weinges
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Patent number: 5380340Abstract: The composition for oxidative dyeing of hair contains at least one coupler and 0.010 to 3.0 percent by weight of at least one developer selected from the group consisting of aminopyrazole derivatives of the formula (I): ##STR1## wherein R is selected from the group consisting of hydrogen and alkyl groups having one to four carbon atoms; n=2 or 3; and physiologically tolerated, water-soluble salts thereof. The developer and coupler substances are present in the composition in a total amount of from 0.1 to 5.0 percent. New pyrazole derivative compounds are also part of the invention.Type: GrantFiled: March 4, 1993Date of Patent: January 10, 1995Assignee: Wella AktiengesellschaftInventors: Hans Neunhoeffer, Stefan Gerstung, Thomas Clausen, Wolfgang R. Balzer
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Patent number: 5303722Abstract: The apparatus for bleaching hair has a light comb with a comb back, a plurality of comb teeth extending from the comb back, a device for guiding light from a light source through the comb back into the comb teeth, and a device for radiating the light from the comb teeth and parallel to the comb back, this radiating device receiving the light from the light guiding device.Type: GrantFiled: January 8, 1993Date of Patent: April 19, 1994Assignee: Wella AktiengesellschaftInventors: Robin E. Godfrey, Thomas Clausen, Wolfgang R. Balzer
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Patent number: 5279313Abstract: A preparation for use in a hair bleaching composition consists of 30 to 65% by weight of a persulfate granulate having granule diameters from 0.1 to 0.6 cm and at least one other granulated substance including 15 to 45% by weight of granulated alkaline reacting alkali metal salts. The other granulated substance also has particle diameters from about 0.1 to 0.6 cm. It can also contain 0.1 to 3% by weight of a chelating agent, 0.1 to 15% by weight of an anionic, cationic or nonionic surfactant and a water-soluble thickener. The two component composition contains an aqueous solution which is 4 to 18% by weight hydrogen peroxide and the preparation containing the granulated persulfate. Prior to application on the hair the hydrogen peroxide solution is mixed with the preparation.Type: GrantFiled: December 12, 1991Date of Patent: January 18, 1994Assignee: Wella AktiengesellschaftInventors: Thomas Clausen, Wolfgang R. Balzer
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Patent number: 5246019Abstract: The process for bleaching hair using light includes first, applying a sufficient quantity of a composition containing at least one optical photosensitizer and a compound capable of providing a hydrogen radical to strands of the hair to be bleached and allowing the composition to act for up to 60 minutes on those strands; then, irradiating them with light of a wavelength or wavelengths selected from visible and ultraviolet wavelength ranges capable of activating the at least one optical photosensitizer and having an intensity sufficient for bleaching them, and subsequently rinsing and drying the bleached hair. This process does not require excess hydrogen peroxide and is thus particularly gentle to the hair.Type: GrantFiled: June 24, 1991Date of Patent: September 21, 1993Assignee: Wella AktiengesellschaftInventors: Robin E. Godfrey, Thomas Clausen, Wolfgang R. Balzer
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Patent number: 5224965Abstract: The composition for the oxidative dyeing of hair contains at least one coupler substance of the formula ##STR1## where R is a straight-chain or branched C.sub.1 - to C.sub.4 -alkyl group and X is fluorine or bromine, and new 5-halogen-2,4-diaminoalkylbenzenes.The coupler substances of formula (I) are obtainable by simple chemical reactions, easily soluble in water and have a good shelf stability particularly as constituents of the hair dye composition described here.In addition to the multitude of color shades, the dye results which can be achieved with the hair dye composition according to the invention are distinguished particularly by the intensity of color of the red tones and good uniformity of color of the blue tones.Type: GrantFiled: April 7, 1992Date of Patent: July 6, 1993Assignee: Wella AktiengesellschaftInventors: Thomas Clausen, Alexa Weinges, Wolfgang R. Balzer