Abstract: Described herein are settable spacer fluids and methods of making and using such fluids. The settable spacer fluids generally contain a polymerizable raw material and activator in aqueous medium, where the spacer fluid is configured to have density sufficient to displace fluids within a well and to solidify after a duration sufficient to allow use of the spacer fluid to aid in well development and placement of the spacer fluid at a target location prior to significant transformation. The spacer fluid solidifies over time, but can be used with final compressive strength as low as 50 psi.

Abstract: Methods of cementing a subterranean well using a geopolymer composition are provided herein. In one aspect, the geopolymer composition can be a pumpable mixture comprising an aluminosilicate source, an activator, a carrier fluid, and a fluid loss composition comprising at least two materials selected from the group consisting of a water soluble polymer, a polymer particle dispersion, a particulate additive, and a dispersant. The geopolymer composition is placed in the subterranean well and allowed to harden into a solid geopolymer. Other methods herein include preparing a dry geopolymer slurry precursor comprising an aluminosilicate source, a metal silicate, an activator, a fluid loss control agent, and a fluid loss control agent enhancer; mixing the dry geopolymer slurry precursor with water to form a pumpable geopolymer precursor; pumping the geopolymer precursor into a subterranean well; and hardening the geopolymer precursor into a solid geopolymer within the subterranean well.

Abstract: A bipolar battery having at least two electrochemical cells electrically arranged in series includes a housing, an electrolyte, a bipolar electrode, an anode, a cathode, and first and second microporous separators. The bipolar electrode comprises a first anode material and a first cathode material. The first cathode and anode materials are disposed on opposite faces of a current collector. The anode comprises a second anode material comprising: a zinc compound, a zinc oxide compound, and a binder, and the cathode comprises a second cathode material comprising: a manganese oxide, a conductive carbon, and a copper compound. The first cathode material faces the second anode material, and the first anode material faces the second cathode material. The first microporous separator is disposed between the first cathode material and the second anode material, and the second microporous separator is disposed between the first anode material and the second cathode material.

Abstract: A primary or rechargeable battery comprising a battery housing; a cathode comprising a cathode electroactive material a conductive carbon, and a binder; an anode comprising an anode electroactive material; an electrolyte; and a conductive interlayer; and wherein the cathode, the anode, the electrolyte, and the conductive interlayer are disposed within the battery housing. The cathode electroactive material comprises manganese dioxide, any polymorphs thereof, or combinations thereof. The cathode is configured to access 20-100% of 1st electron capacity of the cathode electroactive material. The conductive interlayer contacts the cathode. The conductive interlayer comprises (i) a binder and (ii) a conductive carbon, a metal hydroxide, a metal oxide, or combinations thereof.

Abstract: A system and method for forming a metallic ion intercalated layered structure can include a housing, an electrolyte disposed in the housing, a counter-electrode disposed in the housing, and a working electrode disposed in the housing. The working electrode comprises a metallic support; and an electrode paste. The electrode paste can include an active material and a binder. The system can be used to form a layered structure having metallic ions from the metallic support intercalated into the layered structure based on cycling the working electrode.

Abstract: A battery includes a cathode compartment, a catholyte solution disposed within the cathode compartment, an anode compartment, an anolyte solution disposed within the anode compartment, a separator disposed between the cathode compartment and the anode compartment, and a flow system configured to provide fluid circulation in the cathode compartment and the anode compartment. The catholyte solution and the anolyte solution have different compositions.

Abstract: A wellbore fluid comprising an aqueous base fluid and a plurality of nanoparticles suspended in the aqueous base fluid. The nanoparticles are present in the wellbore fluid in an amount effective to have an effect of increasing the density by at least 0.2 lb/gal.

Abstract: A battery includes a cathode compartment, a catholyte solution disposed within the cathode compartment, an anode compartment, an anolyte solution disposed within the anode compartment, a separator disposed between the cathode compartment and the anode compartment, and a flow system configured to provide fluid circulation in the cathode compartment and the anode compartment. The catholyte solution and the anolyte solution have different compositions.

Abstract: A membraneless battery comprising a cathode comprising a cathode electroactive material; an anode comprising an anode electroactive material; a catholyte in contact with the cathode, wherein the catholyte is not in contact with the anode; an anolyte in contact with the anode, wherein the anolyte is not in contact with the cathode; and one or more buffer interlayers disposed between the anolyte and the catholyte. The catholyte has a pH of less than 4, and the anolyte has a pH of greater than 10. The one or more buffer interlayers regulate a pH in the battery. The anode electroactive material comprises a Zn electroactive material. At least one of the one or more buffer interlayers comprises a weak acid and its conjugate base; and/or at least one of the one or more buffer interlayers comprises a weak base and its conjugate acid.

Abstract: A method of recycling a direct emulsion wellbore fluid may include disrupting a direct emulsion comprising an aqueous external phase and an oleaginous internal phase, wherein the direct emulsion is stabilized by a surfactant composition; and separating the aqueous phase and the oleaginous phase.

Abstract: Aspects of the disclosure include a power system comprising a power-supply device having an output, the power-supply device being configured to provide output power to the output of the power-supply device, and control circuitry configured to receive voltage information indicative of a voltage of a battery, determine that the voltage of the battery is above a first voltage threshold, activate a shutdown signal responsive to determining that the voltage of the battery is above the first voltage threshold, determine that the voltage of the battery is below a second voltage threshold, the second voltage threshold being less than the first voltage threshold, control the power-supply device to disable the output power to the output of the power-supply device responsive to determining that the voltage of the battery is below the second voltage threshold and that the shutdown signal is activated, and control the power-supply device to provide the output power to the output of the power-supply device responsive to de

Abstract: A primary or rechargeable battery comprising a battery housing; a cathode comprising a cathode electroactive material a conductive carbon, and a binder; an anode comprising an anode electroactive material; an electrolyte; and a conductive interlayer; and wherein the cathode, the anode, the electrolyte, and the conductive interlayer are disposed within the battery housing. The cathode electroactive material comprises manganese dioxide, any polymorphs thereof, or combinations thereof. The cathode is configured to access 20-100% of 1st electron capacity of the cathode electroactive material. The conductive interlayer contacts the cathode. The conductive interlayer comprises (i) a binder and (ii) a conductive carbon, a metal hydroxide, a metal oxide, or combinations thereof.

Abstract: A wellbore fluid comprising a first aqueous base fluid and a plurality of silica nanoparticles suspended in the first aqueous base fluid. The nanoparticles are present in the fluid in an amount to have an effect of decreasing a crystallization temperature by at least 4 to 55° F. as compared to a second aqueous base fluid without the silica nanoparticles.

Abstract: A wellbore fluid comprising an aqueous base fluid and a plurality of nanoparticles suspended in the aqueous base fluid. The nanoparticles are present in the wellbore fluid in an amount effective to have an effect of increasing the density by at least 0.2 lb/gal.

Abstract: A battery comprises a housing, an electrolyte disposed in the housing, a cathode disposed in the housing, an anode disposed in the housing and comprising an anode material comprising: zinc or zinc oxide, an electrocoagulant material selected from the group consisting of: aluminum, iron, titanium, calcium, zirconium, a hydroxide thereof, a salt thereof, an oxide thereof, and a combination thereof, and a binder.

Abstract: A battery includes a housing, an electrolyte disposed in the housing, an anode disposed in the housing, and an electrode disposed in the housing and comprising an electrode material comprising manganese dioxide, and a conductive carbon coated with a metallic layer. The use of the conductive carbon coated with the metallic layer can help to control the effects of other ions such as zincate on the manganese dioxide during discharge or cycling of the battery.

Abstract: A system and method for forming a metallic ion intercalated layered structure can include a housing, an electrolyte disposed in the housing, a counter-electrode disposed in the housing, and a working electrode disposed in the housing. The working electrode comprises a metallic support; and an electrode paste. The electrode paste can include an active material and a binder. The system can be used to form a layered structure having metallic ions from the metallic support intercalated into the layered structure based on cycling the working electrode.

Abstract: A wellbore fluid comprising a first aqueous base fluid and a plurality of silica nanoparticles suspended in the first aqueous base fluid. The nanoparticles are present in the fluid in an amount to have an effect of decreasing a crystallization temperature by at least 4 to 55° F. as compared to a second aqueous base fluid without the silica nanoparticles.

Abstract: A zinc electrode comprises an anode material, the anode material comprising: an electroactive material comprising at least one of zinc or a compound comprising zinc, a stabilizer additive comprising at least one of: bismuth, copper, indium, a compound comprising bismuth, a compound comprising copper, a compound comprising indium, or any combination thereof, a conductive additive, and a binder.

Abstract: A method of forming a layered manganese dioxide for use in a cathode of a battery comprises disposing a cathode into a housing of an electrochemical cell, disposing an anode into the housing, disposing a polymeric separator between the anode and the cathode such that the anode and the cathode are electrically separated, adding an alkaline electrolyte to the housing, cycling the electrochemical cell into the 2nd electron capacity of the manganese dioxide, and forming a layered manganese dioxide having a layered manganese dioxide structure with the one or more additives incorporated into the layered manganese dioxide structure. The cathode comprising a cathode material comprising: a manganese dioxide compound, one or more additives selected from the group consisting of bismuth, copper, tin, lead, silver, cobalt, nickel, magnesium, aluminum, potassium, lithium, calcium, gold, antimony, iron, zinc, and combinations thereof, and a conductive carbon.