Abstract: The present invention relates to a biodegradable polyester and use thereof, including components: A) acid components containing following repeating units: 50 to 58 mol % of terephthalic acid A1; 30 to 40 mol % of sebacic acid A2; and 2 to 20 mol % of an aliphatic dibasic acid A3 with a carbon chain length of 6 or less; B) butanediol. In the present invention, in the case of a high content of the terephthalic acid, the biodegradable polyester prepared by introducing an aliphatic dibasic acid unit having a carbon chain length of 6 or less can satisfy the degradation performance and rigidity and improve the tenacity of the material simultaneously.

Abstract: The present invention discloses a poly(terephthalate-co-sebacate) resin composition, comprising the following components: a. poly(terephthalate-co-sebacate); and b. an alkane, which is at least one selected from the group consisting of hexadecane, heptadecane, octadecane, nonadecane and eicosane; wherein a weight content of the alkane is 5 ppm-1000 ppm based on a total weight of the poly(terephthalate-co-sebacate) resin composition. The present invention controls the content of alkane in the composition within a range of 5 ppm-1000 ppm by adding an alkane, which not only enables the poly(terephthalate-co-sebacate) resin to have obviously improved blow molding properties, a film thickness range of less than 0.3 ?m, and a relative deviation of film thickness of less than 2.

Abstract: The present invention relates to a polylactic acid 3D printing material and a preparation method thereof, which belong to the technical field of polymer materials. The polylactic acid 3D printing material of the present invention comprises the following preparation raw materials in parts by weight: (a) 40-95 parts of crystalline or semi-crystalline polylactic acid, (b) 5-60 parts of noncrystalline polylactic acid, and (c) 0-1.0 parts of a processing aid. In the polylactic acid 3D printing material, a weight of dextral polylactic acid represents 0.5%-8% of a total weight of the polylactic acid. According to the present invention, a polylactic acid 3D printing material with a good aging resistance property can be obtained, by selecting and using two kinds of polylactic acids with different optical purities as raw materials, rationally distributing the proportional relationship between the two, and defining the content of dextral polylactic acid.

Abstract: The present invention discloses a PBS resin composition and a preparation method thereof. The composition comprises: a. PBS resin; b. element titanium; c. element phosphorus, wherein a weight ratio range of titanium to phosphorus is 0.6-10:1, preferably 0.7-4:1, and more preferably 1.25-1.5:1. A weight content of the element titanium is 20-200 ppm, and a weight content of the element phosphorus is 15-70 ppm. By adding a titanium-containing compound and a phosphorus-containing compound and controlling the range of the weight ratio of the element titanium to the element phosphorus in the PBS resin composition to be 0.6-10:1, the present invention obtains a PBS resin composition. After treating in a 95° C.-distilled water bath for 12 hours and drying at 90° C. for 3 hours, a change of the melt flow index of the PBS resin composition is less than 50.0 g/10 min, and the PBS resin composition possesses an obviously improved hydrolysis property.

Abstract: The present invention discloses a melt impregnation device and a melt impregnation method. Through an impregnation chamber with a corrugated shape, when a resin melt-distributing runner is connected with a peak position of the impregnation chamber, a chamber vertical height of the peak position of the impregnation chamber is larger than a chamber vertical height of a trough position of the impregnation chamber, and when the resin melt-distributing runner is connected with the trough position of the impregnation chamber, the chamber vertical height of the trough position of the impregnation chamber is larger than the chamber vertical height of the peak position of the impregnation chamber. The present invention can balance an impregnating effect of a continuous fiber band, can carry a broken fiber hairiness which is generated during the impregnation out of an impregnation area, avoids a broken yarn, and enhances a production stability and a production efficiency.

Abstract: The present invention discloses a polylactic acid composite and use thereof. The polylactic acid composite includes the following components: (A) 89 to 98 parts by weight of polylactic acid; (B) 1 to 4 parts by weight of talcum powder; and (C) 1 to 7 parts by weight of a plasticizer. In the component (A), the polylactic acid has a polydispersity index P satisfying the following relationship: 1.55?P?2.02. In the component (B), the talcum powder has a particle size D(50) satisfying: 1 ?m?D(50)?2.6 ?m. In the component (C), the plasticizer has a relative molecular weight M satisfying: 180?M?670. Through research, the present invention has unexpectedly discovered that by using the polylactic acid having the polydispersity index P satisfying the relationship 1.55?P?2.

Abstract: An alternating pressure melt impregnation device and a melt impregnation method, including having a resin melt squirted from each resin melt runner on an upper die and a lower die of a melt injection area, and thus the squirted resin melt is enable to be squirted directly on an upper surface and a lower surface of a continuous fiber bundle which is entering into an impregnation chamber. Impregnation and infiltration for both surfaces of the continuous fiber bundle are primarily completed by a squirted pressure. The resin melt inside the impregnation chamber flows to a decompression chambers at both sides of the impregnation chamber. When the resin melt flows to a throttle plate, a re-impregnation for the continuous fiber bundle is realized. Then the pressure is decreased and a section of the resin melt is enlarged and a radial flow is generated due to the Barus effect.

Abstract: A semiaromatic copolyamide resin and a polyamide molding composition consisting of the same are provided, consisting of following repeat units: (A) 26-80 mol % of units derived from para-amino benzoic acid; (B) 4-70 mol % of units derived from 11-aminoundecanoic acid or undecanolactam, and 0-70 mol % of units derived from another amino acids having 6 to 36 carbon atoms or units consisting of a lactam having 6-36 carbon atoms; (C) 0-37 mol % of units derived from a diamine unit having 4 to 36 carbon atoms; and (D) 0-37 mol % of units derived from a diacid unit having 6 to 36 carbon atoms; wherein, (A)+(B)+(C)+(D)=100 mol %; and molar contents of the units derived from para-amino benzoic acid and those derived from 11-aminoundecanoic acid or undecanolactam are not equal to 50 mol % simultaneously.

Abstract: The present invention discloses a PBAT resin composition comprising: (a) Poly (butyleneadipate-co-terephthalate); (b) a cyclic esterified product having a structure represented by the formula (I) Wherein the content by weight of the cyclic esterified product is from 10 ppm to 2000 ppm, based on the total weight of the PBAT resin composition. In the present invention, the service life of the PBAT resin composition can be greatly extended by adding cyclic esterified product in the PBAT resin composition and controlling the content of the cyclic esterified product in the composition in the range of 10 ppm to 2000 ppm. And after boiled for 240 hours in 95% ethanol at 40° C., the film produced from blowing or the articles produced from injection have less surface precipitates, with excellent surface appearance properties.

Abstract: A biodegradable polyester composition based on a total weight of the biodegradable polyester composition, including a weight content of a cyclic ester compound having a structure shown as formula (I), which is 100 ppm-950 ppm; and based on the total weight of the biodegradable polyester composition, a weight content of cyclopentanone is 0.5 ppm-85 ppm is provided. The cyclic ester compound and cyclopentanone is added into the composition and controlling the content of the cyclic ester compound and the content of cyclopentanone in a certain range in the composition to realize an anti-thermal oxidative aging property of the biodegradable polyester composition. In addition, a film is prepared by blow molding or a part is prepared by injection molding after being digested with 95% ethanol at 40° C. for 240 hours.

Abstract: The present invention discloses a biodegradable polyester composition, wherein based on a total weight of the biodegradable polyester composition, a weight content of glycidyl methacrylate is 0.05 ppm-10 ppm. In the present invention, by adding a trace amount of glycidyl methacrylate into a chosen formula of the biodegradable polyester composition and controlling the weight content of glycidyl methacrylate which finally remains in the biodegradable polyester composition as 0.05 ppm-10 ppm, a compatibility between aliphatic-aromatic polyester and polylactic acid in the biodegradable polyester composition can be greatly enhanced, which enables the biodegradable polyester composition to have excellent surface property of film material, and no fisheye occurs on the film material because of a fluctuation of processing technique.

Abstract: The present invention discloses a biodegradable polyester composition, wherein based on a total weight of the biodegradable polyester composition, a weight content of styrene is 0.1 ppm-30 ppm. When the weight content of styrene which is added into a chosen formula of the biodegradable polyester composition based on the total weight of the biodegradable polyester composition is controlled as 0.1 ppm-30 ppm, the present invention may guarantee the biodegradable polyester composition with excellent transmittance and haze effect, and meanwhile may guarantee the biodegradable polyester composition with suitable UV resistance function, without reducing a degradation rate of the biodegradable polyester composition.

Abstract: A biodegradable polyester composition based on a total weight of the biodegradable polyester composition, including a weight content of a cyclic ester compound having a structure shown as formula (I) which is 100 ppm-950 ppm; and based on the total weight of the biodegradable polyester composition, a weight content of tetrahydrofuran is 3 ppm-200 ppm is provided. The cyclic ester compound and tetrahydrofuran is added into the composition and controlling the content of the cyclic ester compound and the content of tetrahydrofuran in a certain range in the composition to realize an anti-thermal oxidative aging property of the biodegradable polyester composition. In addition, a film is prepared by blow molding or a part is prepared by injection molding after being digested with 95% ethanol at 40° C. for 240 hours.

Abstract: The present invention discloses a PBS resin composition and a preparation method thereof. The composition comprises: a. PBS resin; b. element titanium; c. element phosphorus, wherein a weight ratio range of titanium to phosphorus is 0.6-10:1, preferably 0.7-4:1, and more preferably 1.25-1.5:1. A weight content of the element titanium is 20-200 ppm, and a weight content of the element phosphorus is 15-70 ppm. By adding a titanium-containing compound and a phosphorus-containing compound and controlling the range of the weight ratio of the element titanium to the element phosphorus in the PBS resin composition to be 0.6-10:1, the present invention obtains a PBS resin composition. After treating in a 95° C.-distilled water bath for 12 hours and drying at 90° C. for 3 hours, a change of the melt flow index of the PBS resin composition is less than 50.0 g/10 min, and the PBS resin composition possesses an obviously improved hydrolysis property.

Abstract: A biodegradable polyester composition based on a total weight of the biodegradable polyester composition, including a weight content of tetrahydrofuran, which is 3 ppm-200 ppm; and based on the total weight of the biodegradable polyester composition, a weight content of cyclopentanone is 0.5 ppm-85 ppm is provided. The tetrahydrofuran and cyclopentanone is added into the composition and controlling the content of tetrahydrofuran and the content of cyclopentanone in a certain range in the composition to realize printing performance. Moreover, when a velocity of film blowing is 176 Kg/h, a range of a film thickness is less than 0.2 ?m and a relative deviation of the film thickness is less than 1%.

Abstract: The present invention discloses a poly(terephthalate-co-sebacate) resin composition, comprising the following components: a. poly(terephthalate-co-sebacate); and b. an alkane, which is at least one selected from the group consisting of hexadecane, heptadecane, octadecane, nonadecane and eicosane; wherein a weight content of the alkane is 5 ppm-1000 ppm based on a total weight of the poly(terephthalate-co-sebacate) resin composition. The present invention controls the content of alkane in the composition within a range of 5 ppm-1000 ppm by adding an alkane, which not only enables the poly(terephthalate-co-sebacate) resin to have obviously improved blow molding properties, a film thickness range of less than 0.3 ?m, and a relative deviation of film thickness of less than 2.

Abstract: An alternating pressure melt impregnation device and a melt impregnation method, including having a resin melt squirted from each resin melt runner on an upper die and a lower die of a melt injection area, and thus the squirted resin melt is enable to be squirted directly on an upper surface and a lower surface of a continuous fiber bundle which is entering into an impregnation chamber. Impregnation and infiltration for both surfaces of the continuous fiber bundle are primarily completed by a squirted pressure. The resin melt inside the impregnation chamber flows to a decompression chambers at both sides of the impregnation chamber. When the resin melt flows to a throttle plate, a re-impregnation for the continuous fiber bundle is realized. Then the pressure is decreased and a section of the resin melt is enlarged and a radial flow is generated due to the Barus effect.

Abstract: The present invention discloses a melt impregnation device and a melt impregnation method. Through an impregnation chamber with a corrugated shape, when a resin melt-distributing runner is connected with a peak position of the impregnation chamber, a chamber vertical height of the peak position of the impregnation chamber is larger than a chamber vertical height of a trough position of the impregnation chamber, and when the resin melt-distributing runner is connected with the trough position of the impregnation chamber, the chamber vertical height of the trough position of the impregnation chamber is larger than the chamber vertical height of the peak position of the impregnation chamber. The present invention can balance an impregnating effect of a continuous fiber band, can carry a broken fiber hairiness which is generated during the impregnation out of an impregnation area, avoids a broken yarn, and enhances a production stability and a production efficiency.

Abstract: The present invention discloses a semiaromatic copolyamide resin and a polyamide molding composition consisting of the same, consisting of following repeat units: (A) 26-80 mol % of units derived from para-amino benzoic acid; (B) 4-70 mol % of units derived from 11-aminoundecanoic acid or undecanolactam, and 0-70 mol % of units derived from another amino acids having 6 to 36 carbon atoms or units consisting of a lactam having 6-36 carbon atoms; (C) 0-37 mol % of units derived from a diamine unit having 4 to 36 carbon atoms; and (D) 0-37 mol % of units derived from a diacid unit having 6 to 36 carbon atoms; wherein, (A)+(B)+(C)+(D)=100 mol %; and molar contents of the units derived from para-amino benzoic acid and those derived from 11-aminoundecanoic acid or undecanolactam are not equal to 50 mol % simultaneously.

Abstract: The present invention discloses a semiaromatic polyamide resin, a preparation method thereof, and a polyamide molding composition consisting of the same, which consists of following components: (A) 20 to 95 wt % of a PA10T homopolymer derived from 1,10-decanediamine and terephthalic acid; and (B) 5 to 80 wt % of a PA6T homopolymer derived from 1,6-hexanediamine and terephthalic acid. Particularly, (A)+(B)=100 wt %. In the present invention, by adding a certain amount of the PA10T homopolymer into the PA6T homopolymer, a melting point of the PA6T homopolymer can be significantly decreased to be below a decomposition temperature thereof, and thereby a processability of the PA6T homopolymer is improved. The prepared semiaromatic polyamide resin has a decreased melting point, and may be processed normally. The polyamide molding composition consisting of the semiaromatic polyamide resin has a good processability, and has excellent surface properties.