Abstract: The present disclosure belongs to the technical fields of nanoscience and fluorescence sensing, and specifically relates to a preparation method of a paper-based sensor for detecting an ammonia gas, and a use of the paper-based sensor. In the present disclosure, Zn(PA)(BPE) is first prepared, and a porous structure on a surface of the Zn(PA)(BPE) is used to adsorb an ammonia gas to improve a reaction sensitivity of the ammonia gas; then a Zn(PA)@CNQD ratiometric fluorescent substance is prepared from Zn(PA)(BPE) and CNQD through embedding, and finally dissolved in ultrapure water (UPW) to obtain a solution; and the solution is added dropwise on a filter paper, and the filter paper is purged with nitrogen, such that the solution is loaded on the filter paper to obtain a ratiometric fluorescent paper-based sensor.

Abstract: A method for preparing an antibacterial and fresh-keeping fruit-packaging material through three-dimensional (3D) printing includes the following steps: dissolving gum arabic and pullulan separately in deionized water to obtain a gum arabic solution and a pullulan solution; subjecting a probiotic to cultivation, centrifugation, and resuspension to obtain a bacterial suspension; mixing the bacterial suspension, the gum arabic solution, and the pullulan solution to obtain a core layer solution; mixing polyvinyl chloride, a modifier, and a plasticizer to obtain a shell layer solution; injecting the shell layer solution and the core layer solution into two syringes, respectively; conducting coaxial 3D printing to finally obtain a coaxial 3D printing product with a core-shell structure; and conducting uniaxial 3D printing with the shell layer solution alone to form an outer layer on the coaxial 3D printing product to obtain the antibacterial and fresh-keeping fruit-packaging material with inner and outer layers.

Abstract: The present invention belongs to the field of organophosphorus pesticide (OP) detection, and relates to a method for detecting an OP by a microfluidic chip based on a fluorescent sensing film. A porous fluorescent sensing film and the microfluidic chip are first constructed. The fluorescent sensing film is fabricated through layer-by-layer self-assembly of a platinum nanoparticle@oxalate-metal-organic framework (MOF) composite and a porous two-dimensional (2D) nanosheet, and has the functions of specifically detecting OPs and blocking macromolecular interferents. The microfluidic chip includes a sample channel, injection channels, reaction tanks, microfluidic channels, a detection tank, and an optical fiber channel, such that sample pretreatment and detection processes are integrated in the chip.

Abstract: The present application provides an ultrasonic wake-up system. The system includes an ultrasonic imaging device, an ultrasound stimulation device, and an ultrasound stimulation effect evaluation device, and acquires an ultrasonic image of a target object through the ultrasonic imaging device, transmits an ultrasound to the target object based on the ultrasonic image through the ultrasound stimulation device, and adjusts the transmitted ultrasound required through the ultrasound stimulation effect evaluation device. Therefore, peripheral nerves are accurately stimulated, an uplink reticular wake-up system is activated, so as to wake up patients with disorders of consciousness.

Abstract: The present disclosure belongs to the technical fields of nanoscience and fluorescence sensing, and specifically relates to a preparation method of a paper-based sensor for detecting an ammonia gas, and a use of the paper-based sensor. In the present disclosure, Zn(PA)(BPE) is first prepared, and a porous structure on a surface of the Zn(PA)(BPE) is used to adsorb an ammonia gas to improve a reaction sensitivity of the ammonia gas; then a Zn(PA)@CNQD ratiometric fluorescent substance is prepared from Zn(PA)(BPE) and CNQD through embedding, and finally dissolved in ultrapure water (UPW) to obtain a solution; and the solution is added dropwise on a filter paper, and the filter paper is purged with nitrogen, such that the solution is loaded on the filter paper to obtain a ratiometric fluorescent paper-based sensor.

Abstract: The method involves growing a boule of co-doped LYSO:Ce,Ca scintillation crystal containing Ce3+ ions and Ce4+ ions in a ratio of about 1:1, wherein the grown boule is substantially free of Li+ ions and Mg2+ ions. This is achieved by providing a specialized crystal growing device having an inner iridium crucible and loading it with specific oxides and a carbonate salt in specific amounts. The loaded iridium crucible is then subjected to a vacuum and then pressurized with a specific gas mixture consisting mostly of Ar admixed with a small amount of CO. The loaded and pressurized iridium crucible is then heated to yield a melt, into which a seed crystal is placed to grow (by way of the Czochrolaski pull method) an unfinished crystalline boule. This unfinished boule is then annealed in the same special pressurized atmosphere to yield the final boule of co-doped LYSO:Ce,Ca scintillation crystal.

Abstract: Disclosed are a grain boundary and surface-doped rare earth manganese-zirconium composite compound as well as a preparation method and use thereof. A rare earth manganese oxide with a special structure is formed at grain boundary and surface of a rare earth zirconium-based oxide by a grain boundary doping method so as to increase oxygen defects at the grain boundary and the surface, thereby increasing the amount of active oxygen, improving the catalytic activity of the rare earth manganese-zirconium composite compound, inhibiting high-temperature sintering of the rare earth manganese-zirconium composite compound, and improving the NO catalytic oxidation capability. When the rare earth manganese-zirconium composite compound is applied to a catalyst, the consumption of noble metal can be greatly reduced.

Abstract: In the present disclosure, a temperature-sensitive inner layer solution, a deformation intermediate layer solution, and a rigid outer layer solution are first prepared and spray-coated layer by layer on a surface of a fruit or vegetable, such that three preservative film layers are produced successively and can be used for the preservation of the fruit or vegetable.

Abstract: Disclosed are a grain boundary and surface-doped rare earth zirconium-based ceramic material and a preparation method and application thereof, and part of doped elements are positioned at the grain boundary and surface of the rare earth zirconium-based ceramic material by a step-by-step doping method. The sintering activity of the rare earth zirconium-based ceramic material can be changed by adjusting the type and content of doping elements at the grain boundary and the surface, thereby enabling the control of the grain size and the grain boundary number and characteristics of the rare earth zirconium-based ceramic material, and finally optimizing the properties, such as electrical and mechanical properties, of the material. The doping method has the advantages of simple process, low cost and high universality, and can meet the requirements of different rare earth zirconium-based ceramics on doping elements, and thus is suitable for large-scale application.

Abstract: Disclosed are a grain boundary- and surface-doped lithium-lanthanum-zirconium composite oxide solid electrolyte, a preparation method therefor, and an application thereof. Part of doping elements are step-doped at the grain boundary and the surface of the lithium-lanthanum-zirconium composite oxide solid electrolyte to improve the distribution state of the doping elements at the grain boundaries, reduce the number of grain boundaries, lower the grain boundary resistance of the lithium-lanthanum-zirconium composite oxide, thereby obtaining high ionic conductivity. The doping method has the advantages of being simple and convenient in process, low in cost and high in universality, can meet the requirements of different solid electrolytes on doping elements, and is suitable for large-scale application.

Abstract: Disclosed are a grain boundary and surface-loaded noble metal catalyst, a preparation method and an application thereof. The noble metal is dispersed at the grain boundary and surface of alumina and/or a rare earth manganese-zirconium composite oxide to form a multiphase interface, which achieves the following beneficial technical effects: firstly, the multiphase interface has a larger steric hindrance and a stronger anchoring effect, which can inhibit the migration, agglomeration, and growth of the noble metal at high temperatures, increase the high-temperature stability and catalytic performance of the noble metal, and reduce the usage of the noble metal; secondly, the multiphase interface exhibits a synergistic catalytic effect, which can reduce the activation energy of lattice oxygen and increase the quantity of active oxygen, thereby enhancing the NO oxidation and low-temperature catalytic activity.

Abstract: The present invention belongs to the field of organophosphorus pesticide (OP) detection, and relates to a method for detecting an OP by a microfluidic chip based on a fluorescent sensing film. A porous fluorescent sensing film and the microfluidic chip are first constructed. The fluorescent sensing film is fabricated through layer-by-layer self-assembly of a platinum nanoparticle@oxalate-metal-organic framework (MOF) composite and a porous two-dimensional (2D) nanosheet, and has the functions of specifically detecting OPs and blocking macromolecular interferents. The microfluidic chip includes a sample channel, injection channels, reaction tanks, microfluidic channels, a detection tank, and an optical fiber channel, such that sample pretreatment and detection processes are integrated in the chip.

Abstract: The present invention discloses a rare-earth-manganese/cerium-zirconium-based composite compound, a method for preparing the same, and a use thereof. The composite compound is of a core-shell structure with a general formula expressed as: A REcBaOb-(1-A)CexZr(1-x-y)MyO2-z, wherein 0.1?A?0.3, preferably 0.1?A?0.2; a shell layer has a main component of rare-earth manganese oxide with a general formula of REcMnaOb, wherein RE is a rare-earth element or a combination of more than one rare-earth elements, and B is Mn or a combination of Mn and a transition metal element, 1?a?8, 2?b?18, and 0.25?c?4; and a core has a main component of cerium-zirconium composite oxide with a general formula of CexZr(1-x-y)MyO2-z, wherein M is one or more non-cerium rare-earth elements, 0.1?x?0.9, 0?y?0.3, and 0.01?z?0.3. The composite compound enhances an oxygen storage capacity of a cerium-zirconium material through an interface effect, thereby increasing a conversion rate of a nitrogen oxide.

Abstract: In the present disclosure, a temperature-sensitive inner layer solution, a deformation intermediate layer solution, and a rigid outer layer solution are first prepared and spray-coated layer by layer on a surface of a fruit or vegetable, such that three preservative film layers are produced successively and can be used for the preservation of the fruit or vegetable.

Abstract: A method for highly-sensitive and rapid detection of a pesticide residue based on an imprinted metal-organic framework (MOF) probe is provided. A molecularly imprinted MOF enzyme-mimic probe is used as a colorimetric probe to catalyze the oxidation of a substrate, thereby enabling a color change of a system; a low-cost filter paper is used as a substrate for supporting the colorimetric probe, including a quality control zone, a standard zone, and a detection zone; in the quality control zone, the optimal colorimetric analysis parameters can be selected according to the temperature, humidity, and light, etc. of an environment to be tested; the standard zone is a standard colorimetric zone obtained through the dropwise addition of standards with different concentrations and is provided to establish a colorimetric analysis mathematical model; and the detection zone is provided for the detection of an actual sample.

Abstract: The present invention relates to the technical field of identification on adulterated meat, and in particular, to a method for identifying raw meat and high-quality fake meat based on a gradual linear array change of a component. The present invention spatially characterizes changing rules of featured components in the meat with the utilization of sensitivities of the visible/near-infrared spectral signals to changes of the components in the meat and the advantage that spectral scanning can acquire optical signals of the samples spatially and consecutively, further constructs the identification model according to differences in components and spectra of a region of interest in the hyperspectral image by taking a derivative for characterizing rates of change of the featured components.

Abstract: The present invention belongs to the technical field of food processing, and in particular, relates to an adaptive quantitative sub-packaging method for fried rice with multiple side dishes in a central kitchen and an apparatus therefor. The present invention mainly includes self-construction of a key side dish recognition model, self-evaluation of the key side dish recognition model, adaptive quantification of batch fried rice, and the apparatus matched with the three-step operation.