Abstract: The present invention discloses a method for preparing a perfluoroalkyl sulfinate ester. The method includes reacting an ?-carbonyldiazo compound and a sodium perfluoroalkyl sulfinate, in an organic solvent, in the presence of anhydrous copper acetate as an optimal catalyst and tert-butyl hydroperoxide (TBHP) as a green oxidant, to obtain the perfluoroalkyl sulfinate ester. Compared to the prior art, the present method has the advantages of a wide range of reaction substrates, a short reaction time, a high reaction yield, and mild reaction conditions. The reaction does not require pre-activation of sodium perfluoroalkyl sulfinate, which can participate in the reaction directly, making reaction operations simple. The present method uses TBHP as a green oxidant and produces tert-butanol and water after reaction. Moreover, the present method avoids using a bromide or a chloride as a reaction material, and thus avoids formation of a large amount of a halide salt.

Abstract: Disclosed is a method for preparing ?-carbonyl sulfones. The method comprises: by taking an ?-carbonyl diazo compound and sodium arylsulfinate as reaction substrates, cheap silver nitrate as an optimal catalyst, 1,10-phenanthroline as a ligand, and potassium persulfate as an oxidant, carrying out coupling reaction in a mixed solvent of acetonitrile and water to obtain a ?-carbonyl sulfones compound. Compared with the prior art, the method has the following advantages: a wide range of reaction substrates, short reaction time, a relatively high reaction yield, a mild reaction condition, etc. In the present invention, non-toxic and harmless reagents are used as reaction raw materials, so that it has no harm to the environment and satisfies the requirements of contemporary green chemistry development. Post-reaction treatment is relatively simple, and is convenient for separation and purification. In addition, the reaction can achieve gram-scale synthesis, and lays a foundation for actual applications.

Abstract: The invention provides a method for producing a dichloro addition product of an aliphatic olefin by photocatalysis under visible light. The method includes reacting an aliphatic olefin as a substrate with hydrochloric acid as a chlorine source in an organic solvent under visible light irradiation in the presence of copper chloride with visible light absorption ability as a catalyst, to obtain the dichloro addition product of the aliphatic olefin, wherein the reaction is carried out under an oxygen-containing atmosphere, the aliphatic olefin comprises a carbon-carbon double bond and a C9-C15 aliphatic chain connected to the carbon-carbon double bond by a covalent bond. In the invention, visible light is used to provide the energy and a transition metal chloride with visible light absorption ability is used to undergo light-induced electron transfer from chloride with a reaction substrate, thereby initiating an addition reaction to obtain a dichloro addition product.

Abstract: A method for preparing 1,2,4-triazole includes using a fluoroborate aryl diazonium salt, a diazoester derivative and an organic nitrile as reaction substrates, a transition metal salt as a catalyst, and an inorganic base as an additive in a cyclization reaction. The method has the following characteristics: the reaction is economical; the substrate is universal; the post-functionalization is easy; the reaction conditions are mild; the reaction can be performed in air; the catalyst amount used is less; and the post-treatment is simple. Meanwhile, the raw materials, such as the reactants and the catalyst used, are inexpensive and easily available; the reaction composition is reasonable; no ligand is needed; there are less reaction steps; and only one step of reaction is required to obtain a high yield, meeting the requirements and directions of contemporary green chemistry and medicinal chemistry, being suitable for screening highly active 1,2,4-triazole drugs.

Abstract: The present invention discloses a method for preparing a perfluoroalkyl sulfinate ester. The method includes reacting an ?-carbonyldiazo compound and a sodium perfluoroalkyl sulfinate, in an organic solvent, in the presence of anhydrous copper acetate as an optimal catalyst and tert-butyl hydroperoxide (TBHP) as a green oxidant, to obtain the perfluoroalkyl sulfinate ester. Compared to the prior art, the present method has the advantages of a wide range of reaction substrates, a short reaction time, a high reaction yield, and mild reaction conditions. The reaction does not require pre-activation of sodium perfluoroalkyl sulfinate, which can participate in the reaction directly, making reaction operations simple. The present method uses TBHP as a green oxidant and produces tert-butanol and water after reaction. Moreover, the present method avoids using a bromide or a chloride as a reaction material, and thus avoids formation of a large amount of a halide salt.

Abstract: A method for preparing 1,2,4-triazole includes using a fluoroborate aryl diazonium salt, a diazoester derivative and an organic nitrile as reaction substrates, a transition metal salt as a catalyst, and an inorganic base as an additive in a cyclization reaction. The method has the following characteristics: the reaction is economical; the substrate is universal; the post-functionalization is easy; the reaction conditions are mild; the reaction can be performed in air; the catalyst amount used is less; and the post-treatment is simple. Meanwhile, the raw materials, such as the reactants and the catalyst used, are inexpensive and easily available; the reaction composition is reasonable; no ligand is needed; there are less reaction steps; and only one step of reaction is required to obtain a high yield, meeting the requirements and directions of contemporary green chemistry and medicinal chemistry, being suitable for screening highly active 1,2,4-triazole drugs.

Abstract: Embodiments of the present invention disclose a wireless access point, including: a first radio frequency module, a second radio frequency module, and a processor. A frequency band of the first radio frequency module is the same as that of the second radio frequency module; the first radio frequency module and the second radio frequency module work on different channels; a first transmit power upper limit of the first radio frequency module is greater than a second transmit power upper limit of the second radio frequency module; and the processor is configured to schedule a terminal whose signal strength is greater than a threshold to associate with the wireless access point by using the second radio frequency module. The complexity of hardware design for integrating two radio frequency modules of a same frequency band into one AP may be reduced.

Abstract: A contention adjustment method for use in an apparatus and a system in a wireless local area network. The method includes acquiring an air interface occupancy time ratio of a terminal that is in a service operating state, and adjusting an uplink data sending threshold of the terminal according to the air interface occupancy time ratio of the terminal, where the air interface occupancy time ratio of the terminal is a ratio of an air interface occupancy time of the terminal to an air interface time, and the air interface occupancy time of the terminal is a ratio of a volume of data sent by the terminal to an air interface data sending rate of the terminal in the air interface time. The present disclosure may avoid that a terminal with a stronger demand excessively preempts a terminal with a weaker demand.

Abstract: Embodiments of the present invention disclose a wireless access point, including: a first radio frequency module, a second radio frequency module, and a processor. A frequency band of the first radio frequency module is the same as that of the second radio frequency module; the first radio frequency module and the second radio frequency module work on different channels; a first transmit power upper limit of the first radio frequency module is greater than a second transmit power upper limit of the second radio frequency module; and the processor is configured to schedule a terminal whose signal strength is greater than a threshold to associate with the wireless access point by using the second radio frequency module. The complexity of hardware design for integrating two radio frequency modules of a same frequency band into one AP may be reduced.

Abstract: A contention adjustment method for use in an apparatus and a system in a wireless local area network. The method includes acquiring an air interface occupancy time ratio of a terminal that is in a service operating state, and adjusting an uplink data sending threshold of the terminal according to the air interface occupancy time ratio of the terminal, where the air interface occupancy time ratio of the terminal is a ratio of an air interface occupancy time of the terminal to an air interface time, and the air interface occupancy time of the terminal is a ratio of a volume of data sent by the terminal to an air interface data sending rate of the terminal in the air interface time. The present disclosure may avoid that a terminal with a stronger demand excessively preempts a terminal with a weaker demand.