Abstract: A rubber composition having improved antiozonation performance comprising a substituted hydroxyl-phenyl-p-(hydroxy)phenylenediamine. Such a composition is particularly suitable for rubber articles. The improved rubber composition possesses a long lasting antiozonation performance, slowing migration through the rubber article and reducing effluence of the antiozonant. Such rubber articles may include rubber pneumatic tires, solid tires, non-pneumatic tires, belts, hoses, cables, automotive mounts, bushings and general mechanic products that are exposed to continuous and intermittent dynamic operation conditions and require protection from ozonation.

Abstract: A rubber composition is disclosed and more particularly, a rubber composition having low uncured viscosity for better green rubber handling and high cured cohesiveness desired cured article properties, methods for making them and articles made from such rubber compositions. Particularly the invention uses 3-hydroxydiphenylamime or 4-hydroxydiphenylamine or their combinations in a rubber composition yielding a rubber composition having a low uncured viscosity for rubber processing and a high cured cohesion and rigidity for the cured rubber product. Such a composition is particularly suitable for rubber applications including tires.

Abstract: A rubber composition is disclosed and more particularly, a rubber composition having low uncured viscosity for better green rubber handling and high cured cohesiveness desired cured article properties, methods for making them and articles made from such rubber compositions. Particularly the invention uses 3-hydroxydiphenylamine or 4-hydroxydiphenylamine or their combinations in a rubber composition yielding a rubber composition having a low uncured viscosity for rubber processing and a high cured cohesion and rigidity for the cured rubber product. Such a composition is particularly suitable for rubber applications including tires.

Abstract: Tire treads, especially tire treads for aircraft or for heavy vehicles, formed from a material that is based upon a cross-linkable rubber composition, the cross-linkable rubber composition comprising, per 100 parts by weight of rubber, between 40 phr and 100 phr of a polyisoprene rubber, between 0 and 60 phr of a highly unsaturated diene rubber and between 1 phr and 25 phr of a polyterpene resin having a glass transition temperature of between 50° C. and 120° C. The rubber composition further includes between 0.1 phr and 10 phr of a poly-thiosulfate anti-reversion agent having the formula: MO3S—S—X—S—SO3M wherein X is an alkylene radical or a radical comprising two or more alkylene units, pairs of which units being linked through an oxygen or a sulfur atom, through a group —SO2—, —NH—, —NH2+—, —N(C1-16alkyl)- or —COO—, or through an arylene or cycloalkylene radical and M is a metal.

Abstract: A sidewall support and/or a bead apex that is manufactured from a rubber composition that is based upon a cross-linkable rubber composition comprising a rubber component selected from the group consisting of a polybutadiene and at least one of a natural rubber and a polyisoprene. Such rubber compositions may further include a carbon black and also include a sulfur curing agent and a peroxide curing agent.

Abstract: Rubber compositions and rubber articles manufactured from such rubber compositions that include the well-known antioxidant poly-2,2,4-trimethyl-1,2-dihydroquinoline (TMQ) having the formula (C12H15N)n where n=2˜4 as well as a methylene acceptor/donor system reinforcing resin. Such embodiments include a tire component comprising a rubber composition that is based upon a cross-linkable elastomer composition, the cross-linkable rubber composition comprising, per 100 parts by weight of rubber (phr), a highly unsaturated diene elastomer, reinforcing filler, between 0.5 phr and 10 phr of TMQ and the methylene acceptor/methylene donor.

Abstract: Tire treads, especially tire treads for aircraft or for heavy vehicles, formed from a material that is based upon a cross-linkable rubber composition, the cross-linkable rubber composition comprising, per 100 parts by weight of rubber, between 40 phr and 100 phr of a polyisoprene rubber, between 0 and 60 phr of a highly unsaturated diene rubber and between 1 phr and 25 phr of a polyterpene resin having a glass transition temperature of between 50° C. and 120° C. The rubber composition further includes between 0.1 phr and 10 phr of a poly-thiosulfate anti-reversion agent having the formula: MO3—S—S—X—S—SO3M wherein X is an alkylene radical or a radical comprising two or more alkylene units, pairs of which units being linked through an oxygen or a sulfur atom, through a group —SO2—, —NH—, —NH2+—, —N(C1-16alkyl)- or —COO—, or through an arylene or cycloalkylene radical. and M is a metal.

Abstract: Tire components comprising rubber compositions based upon cross-linkable elastomer composition, the cross-linkable elastomer compositions including, per 100 parts by weight of rubber (phr), a highly unsaturated diene elastomer, a reinforcing filler and a methylene acceptor of the form wherein R is selected from H, an alkyl moiety, a cycloalkyl moiety, an aryl moiety, an amine moiety or combinations thereof. The rubber compositions include a methylene donor in an amount that provides little or no change in the rigidity of the cured rubber composition. Since the methylene acceptor may be described as having antidegradant properties, then resulting rubber composition has improved resistance to degradation.

Abstract: Rubber compositions and rubber articles manufactured from such rubber compositions that include the well-known antioxidant poly-2,2,4-trimethyl-1,2-dihydroquinoline (TMQ) having the formula (C12H15N) where n=2˜4 as well as a methylene acceptor/donor system reinforcing resin. Such embodiments include a tire component comprising a rubber composition that is based upon a cross-linkable elastomer composition, the cross-linkable rubber composition comprising, per 100 parts by weight of rubber (phr), a highly unsaturated diene elastomer, reinforcing filler, between 0.5 phr and 10 phr of TMQ and the methylene acceptor/methylene donor.

Abstract: A tire component comprising a rubber composition having a highly unsaturated diene elastomer and a reinforcing filler with a methylene acceptor selected from 3-hydroxydiphenyl-amine, 4-hydroxydiphenyl-amine or combinations thereof. Such rubber compositions further include a methylene donor, wherein a ratio of the methylene acceptor to the methylene donor may be greater than 10:1 or in other embodiments greater than 10:1 but no more than 50:1 or between 15:1 and 30:1. A method for manufacturing a tire component includes mixing together components of a rubber composition into a non-productive mix, the components including a highly unsaturated diene elastomer, a reinforcing filler and a methylene acceptor selected from 3-hydroxydiphenyl-amine, 4-hydroxydiphenyl-amine or combinations thereof; and mixing a methylene donor and a vulcanizing agent into the non-productive mix to convert the non-productive mix to a productive mix.

Abstract: A tire component comprising a rubber composition having a highly unsaturated diene elastomer and a reinforcing filler with a first methylene acceptor selected from 3-hydroxydiphenylamine, 4-hydroxydiphenylamine or combinations thereof; a second methylene acceptor selected from a Novolac resin, diphenylolmethane, diphenylolethane diphenylolpropane, diphenylolbutane, a naphthol, a cresol or combinations thereof and a methylene donor.

Abstract: Tire components made of rubber compositions that comprises, per 100 parts by weight of rubber (phr) 100 phr or an essentially unsaturated diene rubber, between 30 phr and 150 phr of a reinforcing filler and between 2 phr and 50 phr of a high-styrene content styrene-butadiene copolymer additive, the styrene-butadiene copolymer additive having a styrene content of between 50 wt. % and 90 wt. %. Alternatively, the styrene content of the styrene-butadiene copolymer additive may be between 55 wt. % and 80 wt. %. Because the rigidity of the resulting cured rubber composition is high, particular embodiments may include components around the bead area of a tire and tire treads, including winter tire treads.

Abstract: Tire components comprising rubber compositions based upon cross-linkable elastomer composition, the cross-linkable elastomer compositions including, per 100 parts by weight of rubber (phr), a highly unsaturated diene elastomer, a reinforcing filler and a methylene acceptor of the form wherein R is selected from H, an alkyl moiety, a cycloalkyl moiety, an aryl moiety, an amine moiety or combinations thereof. The rubber compositions include a methylene donor in an amount that provides little or no change in the rigidity of the cured rubber composition. Since the methylene acceptor may be described as having antidegradant properties, then resulting rubber composition has improved resistance to degradation.

Abstract: Methods for producing a rubber composition for a tire component that include preparing a methylene acceptor block by mixing a first highly unsaturated diene elastomer with a methylene acceptor. This mixture is then cooled and may then be used or may be stored for later use in producing a rubber composition. Such methods may further include mixing a non- productive mix, the non-productive mix comprising a second highly unsaturated diene elastomer, a reinforcing filler and the methylene acceptor block. The methylene acceptor block itself comprises no or essentially no reinforcing filler. To prepare for the addition of the vulcanization agent, such methods, include cooling the non-productive mix and then mixing a vulcanizing agent and a methylene donor into the cooled non-productive mix to produce a productive mix.

Abstract: A tire component comprising a rubber composition having a highly unsaturated diene elastomer and a reinforcing filler with a methylene acceptor selected from 3-hydroxydiphenyl- amine, 4-hydroxydipheyl- amine or combinations thereof. Such rubber compositions further include a methylene donor, wherein a ratio of the methylene acceptor to the methylene donor may be greater than 10:1 or in other embodiments greater than 10:1 but no more than 50:1 or between 15:1 and 30:1. A method for manufacturing a tire component includes mixing together components of a rubber composition into a non-productive mix, the components including a highly unsaturated diene elastomer, a reinforcing filler and a methylene acceptor selected from 3-hydroxydiphenylamine, 4-hydroxydipheyl-amine or combinations thereof; and mixing a methylene donor and a vulcanizing agent into the non-productive mix to convert the non-productive mix to a productive mix.

Abstract: A tire component comprising a rubber composition having a highly unsaturated diene elastomer and a reinforcing filler with a first methylene acceptor selected from 3-hydroxydiphenylamine, 4-hydroxydiphenylamine or combinations thereof; a second methylene acceptor selected from a Novolac resin, diphenylolmethane, diphenylolethane diphenylolpropane, diphenylolbutare, a naphthol, a cresol or combinations thereof and a methylene donor.

Abstract: A rubber composition comprising a metal salt of a carboxylic acid used as a curing agent, a highly unsaturated dieene rubber, a filler and a sulfur vulcanization system of between 0.5 phr and 8 phr of sulfur and at least one vulcanization accelerator. Particular embodiments may further include between 1 phr and 6 phr of a metal salt of a carboxylic acid that increases a tear index of the cured elastomer composition by at least 50 percent as compared to a similar cured elastomer composition, such similar cured elastomer composition being different in composition only in that it (1) lacks the metal salt of a carboxylic acid and (2) has an increased amount of the sulfur vulcanization system at about the same sulfur to accelerator ratio to maintain a 10% modulus of elongation at 23 0C to within 15% of the modulus of the cured rubber composition.

Abstract: Tire treads, especially tire treads for aircraft or for heavy vehicles, formed from a material that is based upon a cross-linkable rubber composition, the cross-linkable rubber composition comprising, per 100 parts by weight of rubber, between 40 phr and J 00 phr of a polyisoprene rubber, between 0 and 60 phr of a highly unsaturated diene rubber and between 1 phr and 25 phr of a polylerpene resin having a glass transition temperature of between 50° C. and 120° C. The rubber composition further includes between 0.1 phr and 10 phr of a poly-thiosulfate anti-reversion agent having the formula: MO3S—S—X—S—SO3M wherein X is an alkylene radical or a radical comprising two or more alkylene units, pairs of which units being linked through an oxygen or a sulfur atom, through a group SO2—, —NH—, —NH2+—, —NlC1-16alkyl)- or —COO—, or through an arylene or cycloalkylene radical and M is a metal.

Abstract: Using a target loading value and target intrinsic properties desired for a rubber formulation, two or more fillers are combined to create a blend having the desired intrinsic properties—i. e. a blend can be created emulating the desired intrinsic properties of a single filler system. In another exemplary aspect, knowing the individual loadings of fillers along with the target values desired for the loading of the blend and its intrinsic properties, individual intrinsic properties for at least one unknown filler that will be used to create the blend can be calculated. The unknown filler can then be identified by comparing the calculated intrinsic properties with the intrinsic properties of known fillers. The method allows e.g.) a manufacturer to blend a variety of suitable fillers while maintaining a more limited inventory of fillers than would otherwise be required for multiple rubber formulations.

Abstract: A cushion gum for bonding a tire tread to a tire carcass, the cushion gum comprising an essentially unsaturated diene elastomer, between (0.5) and (25) phr of a metal salt of a carboxylic acid and a peroxide curing system. The essentially unsaturated diene elastomer may be, in some embodiments, a highly unsaturated diene elastomer such as, for example, natural rubber.